Polyurethane resin for tire and preparation method thereof
A technology of polyurethane resin and resin, applied in the field of polyurethane resin for tires and its preparation, can solve the problem of high production cost
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Embodiment 1
[0055] The polyoxyethylene-oxypropylene trihydric alcohol of 221.7kg (number-average molecular weight is 6000), the styrene graft copolymerized polyoxyethylene-oxypropylene trihydric alcohol of 55.4kg (number-average molecular weight is 6000), 1.39kg ethylene glycol, The ethylene glycol solution of the triethylenediamine of 0.22kg, the solution that 0.89kg of 70wt% bis (dimethylaminoethyl) ether and 30wt% dipropylene glycol is made into, 2.77kg water and 0.28kg organosilicon homogeneous foam After the agent was reacted at 50°C for 2.5h, the temperature was lowered to 40°C and mixed for 1.5h to obtain the polyurethane resin component A.
[0056] With the diphenylmethane diisocyanate of 45.4kg, the carbodiimide modified diphenylmethane diisocyanate of 15.1kg, the polyethylene adipate butylene glycol ester diol of 0.76kg (the number average molecular weight is 1000) React with 0.0015kg of phosphoric acid at 65°C for 3 hours to obtain component B1 of polyurethane resin.
[0057] ...
Embodiment 2
[0060] The polyoxyethylene-oxypropylene trihydric alcohol of 221.7kg (number-average molecular weight is 6000), the styrene graft copolymerized polyoxyethylene-oxypropylene trihydric alcohol of 55.4kg (number-average molecular weight is 6000), 1.39kg ethylene glycol, The ethylene glycol solution of the triethylenediamine of 0.22kg, the solution that 0.89kg of 70wt% bis (dimethylaminoethyl) ether and 30wt% dipropylene glycol is made into, 2.77kg water and 0.28kg organosilicon homogeneous foam After the agent was reacted at 50°C for 2.5h, the temperature was lowered to 40°C and mixed for 1.5h to obtain the polyurethane resin component A.
[0061] With the diphenylmethane diisocyanate of 7.46kg, the carbodiimide modified diphenylmethane diisocyanate of 2.48kg, the polyethylene adipate butylene glycol ester diol of 0.12kg (the number average molecular weight is 1000) React with 0.00032kg of phosphoric acid at 65°C for 3 hours to obtain component B1 of polyurethane resin.
[0062] R...
Embodiment 3
[0065] The polyoxyethylene-oxypropylene trihydric alcohol of 101.0kg (number-average molecular weight is 10000), the acrylonitrile graft copolymerized polyoxyethylene-oxypropylene trihydric alcohol of 101.0kg (number-average molecular weight is 10000), 2.02kg ethylene glycol, The ethylene glycol solution of the triethylenediamine of 1.01kg, the solution that the bis(dimethylaminoethyl) ether of 1.01kg 70wt% and 30wt% dipropylene glycol is made into, 3.03kg water and 4.04kg organosilicon bubble evenly After the agent was reacted at 60°C for 1.5h, the temperature was lowered to 45°C and mixed for 1.0h to obtain the polyurethane resin component A.
[0066] With the diphenylmethane diisocyanate of 48.3g, the carbodiimide modified diphenylmethane diisocyanate of 12.1kg, the polyethylene adipate butanediol ester diol of 12.1kg (the number average molecular weight is 2000) React with 0.002kg of phosphoric acid at 75°C for 2 hours to obtain component B1 of polyurethane resin.
[0067...
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