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Preparation method of high permeability fast water injection well scale remover

A technology for water injection wells and descaling agents, which is applied in the direction of chemical instruments and methods, drilling compositions, etc., can solve the problems of low construction labor intensity, short construction time, and low corrosion, and achieve low construction labor intensity. Short time, good treatment effect

Inactive Publication Date: 2017-06-16
周益铭
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The technical problem mainly solved by the present invention: aiming at the problem that the current chemical descaling agent has a long descaling cycle, low descaling efficiency, strong corrosion to pipelines, good effect on inorganic scales, but difficult to remove organic scales, a method of using The descaling agent is prepared by adding the acidic complexing agent to the osmotic softener. In the present invention, the catalyst is prepared by using phosphotungstic acid first, and then the acidic complexing agent is prepared by using the catalyst and glucosamine hydrochloride through processes such as reaction and pH adjustment. For standby, use polyoxyethylene fatty acid ester, octadecyl dimethyl betaine and other substances to prepare composite osmotic lubricant, and mix it with acidic complexing agent, organic acid and other substances to obtain high-permeability rapid water injection well Descaling agent, the descaling agent prepared by the present invention can increase the rate of dissolution, loosening and shedding of dirt, and the prepared metal complexing agent is added to the descaling agent, which can penetrate into the bonding surface of scale and metal, and undergo metathesis with dirt , reduce the adhesion between the dirt and the metal contact surface and make the old scale fall off, not only has a good treatment effect on the inorganic scale, but also can remove the organic scale, the construction labor intensity is low, the construction time is short, and the corrosion is small

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0021] Weigh 100g of ethyl silicate, 50g of butanol, 40g of deionized water and 32g of phosphotungstic acid into a three-necked flask, put them in a water bath, heat to reflux, pour them into a glass beaker after reflux for 3 hours, and put them in a water bath In the pot, heat up to 60°C, keep stirring for 3 hours, put it in an oven, dry at 100°C for 6 hours, put it into a grinder after drying, and pass through a 100-mesh sieve to obtain catalyst powder; Add 6g of glucosamine hydrochloride and 250mL of deionized water to the four-necked flask of the tube, thermometer and water separator in sequence, adjust the pH value to 7.0 with a mass fraction of 20% sodium hydroxide solution, and then add 2.5g of the above-mentioned Catalyst powder, stir evenly, put it into a water bath, heat up to 35°C, heat and stir for 5 hours, and use 20% sodium hydroxide solution to keep the pH of the reaction solution at 7.0 during the reaction; filter to obtain Filtrate, adjust the pH of the filtra...

example 2

[0024]Weigh 150g of ethyl silicate, 80g of butanol, 45g of deionized water and 33g of phosphotungstic acid into a three-necked flask, put them in a water bath, heat to reflux, pour them into a glass beaker after reflux for 4 hours, and put them in a water bath In the pot, heat up to 65°C, keep stirring for 4 hours, put it in an oven, dry at 105°C for 7 hours, put it into a grinder after drying, and pass through a 110-mesh sieve to obtain catalyst powder; Add 7g of glucosamine hydrochloride and 275mL of deionized water to the four-necked flask of the tube, thermometer and water separator in sequence, adjust the pH value to 7.0 with a 20% mass fraction of sodium hydroxide solution, and then add 2.7g of the above-mentioned Put the catalyst powder into a water bath after stirring evenly, raise the temperature to 37°C, and keep stirring for 5.5 hours. During the reaction, use 20% sodium hydroxide solution to keep the pH value of the reaction solution at 7.0; filter after the above r...

example 3

[0027] Weigh 200g of ethyl silicate, 100g of butanol, 50g of deionized water and 35g of phosphotungstic acid into a three-necked flask, put them in a water bath, heat to reflux, pour them into a glass beaker after reflux for 5 hours, and put them in a water bath In the pot, heat up to 70°C, keep warm and stir for 5 hours, put it in an oven, dry at 110°C for 8 hours, put it into a grinder after drying, and pass it through a 120-mesh sieve to obtain catalyst powder; Add 8g of glucosamine hydrochloride and 300mL of deionized water to the four-necked flask of the tube, thermometer and water separator in sequence, adjust the pH value to 7.0 with a 20% mass fraction of sodium hydroxide solution, and then add 3.0g of the above-mentioned Catalyst powder, stir evenly, put it into a water bath, heat up to 40°C, heat and stir for 6 hours, and use 20% sodium hydroxide solution to keep the pH of the reaction solution at 7.0 during the reaction; filter to obtain Filtrate, adjust the pH of t...

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Abstract

Belonging to the technical field of scale removers, the invention discloses a preparation method of a high permeability fast water injection well scale remover. The method includes: firstly utilizing phosphotungstic acid to prepare a catalyst, then reacting the catalyst with glucosamine hydrochloride, adjusting pH and performing other processes to obtain an acidic complexing agent for standby use, using polyoxyethylene aliphatate, octodecyl betaine and other substances to prepare a composite permeation lubricant, and mixing the composite permeation lubricant with the acidic complexing agent, organic acid and other substances, thus obtaining the high permeability fast water injection well scale remover. The scale remover prepared by the method provided by the invention can enhance the dirt dissolution, loosening and falling rate, after the prepared metal complexing agent is added into the scale remover, the scale remover can permeate into a bonding surface of limescale and metal to undergo double decomposition with dirt, the dirt adhesion to the metal contact surface can be reduced so as to make the oil dirt fall off. The scale remover has good treatment effect on inorganic dirt, but also can remove organic dirt, and has the advantages of low construction labor intensity, short construction time, and small corrosion.

Description

technical field [0001] The invention discloses a preparation method of a high-permeability rapid water injection well descaling agent, which belongs to the technical field of descaling agents. Background technique [0002] In the process of oilfield water injection development, water injection wells are usually used to inject water into the oil reservoir to maintain or restore the pressure of the oil layer, so that the oil reservoir has a strong driving force, so as to increase the production speed and recovery rate of the oil reservoir. However, during the use of water injection wells, due to corrosion, precipitation, gelling, carbon deposition, bacterial reproduction, etc., it is easy to cause scaling on the inner wall of the pipe string. The deposition of scale will cause local electrochemical corrosion of the pipe string and reduce the flow cross section Area, increase hydraulic resistance and transport energy, block oil well channels, thereby reducing oil well productio...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/524C09K8/528
CPCC09K8/524C09K8/528
Inventor 周益铭徐越
Owner 周益铭
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