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Highly corrosion-resistant, wear-resistant and anti-fouling coating for flue gas turbine blades and its preparation process

A flue gas turbine and anti-scaling coating technology, which is applied in the direction of metal material coating technology, coating, melt spraying, etc., can solve the problems of spraying composite coatings, achieve good corrosion resistance, improve stability, and improve The effect of service life

Active Publication Date: 2019-06-28
725TH RES INST OF CHINA SHIPBUILDING INDAL CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, there is no invention patent for spraying composite coatings on the surface of flue gas turbine blade materials to solve the above problems

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] After the blade is clamped by the tooling, first fix the blade with sandblasting tooling, use 16 mesh and 24 mesh mixed brown corundum with a ratio of 3:1 for sandblasting, the pressure is 0.7MPa, the spray angle is 90°, and the sandblasting distance is 0.15m ; The material composition of the cermet coating is NiCr 25%, Cr 3 C 2 75% mixed powder, the preparation process is air pressure 0.8MPa, propane pressure 0.7MPa, powder feeding speed 20g / min, spraying distance 200mm, spraying angle 90°, spraying speed 500mm / s, step distance 3mm, substrate temperature less than 150 ℃; then the composition of the material used for spraying the ceramic coating is Al 2 o 3 87%, TiO 213%, the preparation process is spraying voltage 50V, current 700A, main gas pressure 0.6MPa, main gas flow 60L / min, auxiliary gas pressure 0.5MPa, auxiliary gas flow 6L / min, carrier gas flow 5L / min, powder feeding speed 40g / min, the spraying distance is 100mm, the spraying angle is 90°, the spraying s...

Embodiment 2

[0030] After the blade is clamped by the tooling, first fix the blade with sandblasting tooling, use 16 mesh and 24 mesh mixed brown corundum with a ratio of 3:1 for sandblasting, the pressure is 0.7MPa, the spray angle is 90°, and the sandblasting distance is 0.15m ; The material composition of the cermet coating is NiCr40%, Cr 3 C 2 60% mixed powder, the preparation process is air pressure 0.7MPa, propane pressure 0.55MPa, powder feeding speed 20g / min, spraying distance 200mm, spraying angle 90°, spraying speed 500mm / s, step distance 3mm, substrate temperature less than 150 ℃; then the composition of the material used for spraying the ceramic coating is Al 2 o 3 92%, TiO 2 8%, the preparation process is spraying voltage 55V, current 650A, main gas pressure 0.6MPa, main gas flow 60L / min, auxiliary gas pressure 0.5MPa, auxiliary gas flow 6L / min, carrier gas flow 5L / min, powder feeding speed 40g / min, the spraying distance is 100mm, the spraying angle is 90°, the spraying s...

Embodiment 3

[0032] A high-corrosion-resistant, wear-resistant, and anti-scaling coating for flue gas turbine blades is composed of a 0.1mm-thick chromium carbide cermet coating on the inner layer and a 0.1mm-thick alumina-titanium oxide ceramic coating on the outer layer. The chemical composition and mass percentage content of the chromium carbide cermet coating are: NiCr alloy 25%, Cr 3 C 2 Ceramic 75%; the chemical composition and mass percentage content of alumina titanium oxide ceramic coating are: Al 2 o 3 60%, TiO 2 40%.

[0033] The preparation process of the high-corrosion-resistant, wear-resistant and anti-fouling coating for the flue gas turbine blade is characterized in that it comprises the following steps:

[0034] (1) Surface cleaning: first use acetone and then use absolute ethanol to manually clean the blade surface to remove oil and ensure the cleanliness of the flue gas turbine blade surface;

[0035] (2) Shielding protection: Use blade spraying tooling to shield ...

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Abstract

The invention relates to a highly corrosion-resistant and wear-resistant anti-scale coating for a flue gas turbine blade and a preparation process thereof. The coating is composed of a chromium carbide-based metal ceramic coating and an outer aluminum oxide and titanium oxide ceramic coating. The preparation process comprises the following steps: firstly, cleaning the blade, shielding and protecting the blade, then carrying out sand blasting coarsening, and preparing the chromium carbide-based metal ceramic coating on the surface of the blade by utilizing a supersonic flame spraying process, wherein the thickness is 0.1-0.3mm, the fuel is propane and air, the surface temperature of the blade in the spraying process is less than 200 DEG C, and repeated spraying is adopted to prevent the coating from overheating; and finally, preparing the aluminum oxide and titanium oxide ceramic coating on the surface of the chromium carbide-based metal ceramic coating by adopting a high-speed plasma spraying process, wherein the thickness is 0.1-0.2mm. According to the coating and the preparation process thereof, coating compositions are combined and optimally designed, the method is simple, the prepared highly corrosion-resistant and wear-resistant anti-scale coating can solve the problems of corrosion, erosion, scale formation and the like on the surface of the flue gas turbine blade, and the service life of the blade can be prolonged.

Description

technical field [0001] The invention relates to a coating, in particular to a highly corrosion-resistant, wear-resistant and anti-fouling coating for flue gas turbine blades and a preparation process thereof. Background technique [0002] The flue gas turbine blades in the petroleum catalytic cracking system are forged with GH864 superalloy, the rotor speed can reach 6300r / min, and the working temperature is as high as 750°C. SO in a flue gas turbine x , NO x , CO, CO 2 、H 2 O and other flue gas corrosion, catalyst particle erosion and catalyst fouling on the surface of the blade, the surface of the blade is prone to corrosion, wear, and fouling, resulting in a decrease in the strength of the blade and a significant reduction in life, and even affects the flue gas in severe cases. The normal operation of the turbine equipment causes a lot of economic losses. Therefore, blades need to have comprehensive properties such as high temperature resistance, erosion resistance, ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23C4/06C23C4/11C23C4/129C23C4/134C23C4/02
CPCC23C4/02C23C4/06
Inventor 许康威武笑宇石绪忠张振千王松江田耕夏金法付春龙
Owner 725TH RES INST OF CHINA SHIPBUILDING INDAL CORP