A kind of organically modified CDS-doped silicon nanotube composite material and its preparation method and application
A technology of composite materials and silicon nanotubes, which is applied in the direction of climate sustainability, final product manufacturing, sustainable manufacturing/processing, etc., can solve the problems that the back passivation layer material cannot be sensed, so as to improve the efficiency of light energy utilization and strong The effect of sensory ability
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Embodiment 1
[0021] Preparation of organically modified CdS-doped silicon nanotube composites:
[0022] (1) Add 2.5 mol of silicon nanotubes and 7.5 mol of deionized water into a three-necked flask, ultrasonically disperse for 1 hour, add 0.5 mol of CdS to the three-necked flask, react hydrothermally at 120-125°C for 5 hours, and filter the obtained product , washed, and dried at 60°C to obtain CdS-doped silicon nanotubes;
[0023] (2) Add 1 mol of polyvinyl alcohol laurate and 0.3 mol of methacryloxysilane to 10 mol of ethanol, stir thoroughly for 0.5 hours, then add 1 mol of CdS-doped silicon nanotubes prepared in step (1), and finally add 0.05molNa 2 SO 4 , stirred and reacted for 3 hours under normal temperature and 200r / min rotating speed conditions, and the organically modified CdS-doped silicon nanotube composite material was prepared.
[0024] Preparation of organically modified CdS-doped silicon nanotube composite back passivation layer cadmium telluride thin film solar cells: ...
Embodiment 2
[0029] Preparation of organically modified CdS-doped silicon nanotube composites:
[0030] (1) Add 4.5 mol of silicon nanotubes and 12.5 mol of deionized water into a three-necked flask, ultrasonically disperse for 2 hours, add 0.5 mol of CdS to the three-necked flask, conduct a hydrothermal reaction at 120-125°C for 8 hours, and filter the resulting product , washed, and dried at 60°C to obtain CdS-doped silicon nanotubes;
[0031] (2) Add 1 mol of polyvinyl alcohol laurate and 0.6 mol of methacryloxysilane to 15 mol of ethanol, stir thoroughly for 0.5 hours, then add 3 mol of CdS-doped silicon nanotubes prepared in step (1), and finally add 0.1molNa 2 SO 4 , stirred and reacted for 5 hours under normal temperature and 200r / min rotating speed conditions, and the organically modified CdS-doped silicon nanotube composite material was prepared.
[0032] Preparation of organically modified CdS-doped silicon nanotube composite back passivation layer cadmium telluride thin film ...
Embodiment 3
[0037] Preparation of organically modified CdS-doped silicon nanotube composites:
[0038] (1) Add 3.5 mol of silicon nanotubes and 10 mol of deionized water into a three-necked flask, ultrasonically disperse for 2 hours, add 0.5 mol of CdS to the three-necked flask, conduct a hydrothermal reaction at 120-125°C for 7 hours, and filter the resulting product, washing and drying at 60°C to obtain CdS-doped silicon nanotubes;
[0039](2) Add 1 mol of polyvinyl alcohol laurate and 0.4 mol of methacryloxysilane to 12 mol of ethanol, stir thoroughly for 0.5 hours, then add 2 mol of CdS-doped silicon nanotubes prepared in step (1), and finally add 0.08molNa 2 SO 4 , stirred and reacted for 4 hours under normal temperature and 200r / min rotating speed conditions, and prepared organically modified CdS-doped silicon nanotube composite material.
[0040] Preparation of organically modified CdS-doped silicon nanotube composite back passivation layer cadmium telluride thin film solar cell...
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