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Solid-phase denitrification coupling carrier for simultaneous denitrification and carbon removal

A nitrification coupling and carrier technology, applied in the field of solid phase nitrification, can solve the problems of complex dosing equipment, increase of effluent organic matter content and chroma, and slow release of solid carbon source, so as to increase the enriched microbial biomass and reduce effluent organic matter Content, denitrification performance enhancement effect

Inactive Publication Date: 2017-07-25
ZHEJIANG OCEAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the relatively low carbon and nitrogen in agricultural runoff, it is difficult to achieve a good denitrification effect only by using internal carbon sources, so it is necessary to add external carbon sources
Traditional carbon sources mainly include liquid low-molecular carbon sources such as methanol, ethanol, and glucose. Although good application results have been achieved, some problems have also been found during the application process, such as: complicated operation and management, difficult control of dosage, and The equipment is complicated, and the liquid carbon source is easy to lose, which is easy to cause secondary pollution, etc.; the solid carbon source is released slowly, runs stably, and is not easy to cause secondary pollution, and can be used as a biofilm carrier. It is called "solid phase nitrification" technology
In recent years, many researchers have used solid carbon sources as a substitute for liquid carbon sources in the denitrification process. These solid carbon sources include artificially synthesized polymers (PLA, PCL, etc.), biosynthesized polymers ( PHAs, etc.) and some natural materials, but the cost of artificially synthesized polymers and biosynthetic polymers is relatively high, which is not conducive to industrial applications. Although natural materials are cheap and easy to obtain, they have the disadvantages of increasing organic content and chroma in effluent when used alone

Method used

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  • Solid-phase denitrification coupling carrier for simultaneous denitrification and carbon removal

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1-7

[0029] Embodiment 1-7: adopt the same agricultural runoff water quality to configure influent (wherein organic matter concentration 20.74mg / L, nitrate nitrogen 6.22mg / L, ammonia nitrogen 7.11mg / L, nitrite nitrogen 5.84mg / L), influent pH and temperature 7.0~8.0 and 25±2°C respectively, and set the hydraulic retention time to 6h.

[0030] The determination of ammonia nitrogen is determined by Nessler's reagent colorimetry after distillation; the determination of nitrate nitrogen is determined by phenol disulfonic acid ultraviolet spectrophotometry; the determination of nitrite nitrogen is determined by diazo coupling spectrophotometry; the concentration of organic matter is determined by dichromic acid Determination of potassium method. The above-mentioned determination method refers to the second editorial office of China Standard Press. Water affairs management-a complete book of laws, standards and norms: water source environment volume [M]. Beijing: China Standard Press, 200...

Embodiment 1

[0032] The experiment uses a continuous flow bioreactor, made of plexiglass, with an effective volume of 4L. Select the suspended filler as the PBS carrier, and the density ρ of the suspended filler is 0.96g / cm 3 , the specific surface area is about 500m 2 / m 3 . Choose corncobs as biodegradable carriers, wash and dry the corncobs, and cut the corncobs into 1cm 3 Size, divided into mesh bags (7cm×9cm), each bag is 5g. Take 50.0g of corncobs and 50g of PBS carriers, and fill them in the following way: suspending the filler before filling, that is, filling the PBS carrier in the area near the water inlet of the reactor, and filling the area of ​​the reactor near the water outlet with corncobs. The concentration of three-state nitrogen (nitrate nitrogen, ammonia nitrogen, and nitrite nitrogen) and organic matter (total organic carbon) in the influent and effluent water was regularly measured, and the removal rates of nitrate nitrogen, ammonia nitrogen, nitrite nitrogen, and o...

Embodiment 2

[0036] The experiment uses a continuous flow bioreactor, made of plexiglass, with an effective volume of 4L. Select the suspended filler as the PBS carrier, and the density ρ of the suspended filler is 0.96g / cm 3 , the specific surface area is about 500m 2 / m 3 . Choose corncobs as biodegradable carriers, wash and dry the corncobs, and cut the corncobs into 1cm 3Size, divided into mesh bags (7cm×9cm), each bag is 5g. Take 50.0g of corn cob and 50g of PBS carrier, the filling method is: the biodegradable carrier is placed in front, that is, the corn cob is filled in the area near the water inlet of the reactor, and the PBS carrier is filled in the area of ​​the reactor near the water outlet. The concentrations of three-state nitrogen (nitrate nitrogen, ammonia nitrogen, and nitrite nitrogen) and organic matter (total organic carbon) in the influent and effluent water were regularly measured, and the removal rates of nitrate nitrogen, ammonia nitrogen, nitrite nitrogen, and ...

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Abstract

The invention belongs to the technical field of solid-phase denitrification, and particularly relates to a solid-phase denitrification coupling carrier for simultaneous denitrification and carbon removal. The solid-phase denitrification coupling carrier is prepared from biodegradable carriers and suspension filling materials through being coupled. The biodegradable carriers and the suspension filling materials are coupled; the specific surface area of the biodegradable carriers and the suspension filling materials is great; a biological membrane can be better attached; microbes can be enriched; microbes enriched on two kinds of carriers have different emphasis on the contaminant removal; the biodegradable carriers have a good effect on the denitrification; the suspension filling materials have good effects on removing organic matters. By using the coupling carriers, agricultural wastes can be recovered and utilized; the denitrification performance is enhanced; the quantity of the enriched microbes is increased; in addition, the goals of synchronously removing organic matters and reducing the outlet water organic matter content are achieved; the generation of secondary pollution is avoided.

Description

technical field [0001] The invention belongs to the technical field of solid phase nitrification, and in particular relates to a solid phase nitrification coupling carrier for synchronous denitrification and carbon removal. Background technique [0002] For problems such as eutrophication caused by nitrogen pollution in agricultural runoff, biological denitrification technology has received greater attention. However, due to the low carbon and nitrogen ratios in agricultural runoff, it is difficult to achieve a good denitrification effect only by using internal carbon sources, so it is necessary to add external carbon sources. Traditional carbon sources mainly include liquid low-molecular carbon sources such as methanol, ethanol, and glucose. Although good application results have been achieved, some problems have also been found during the application process, such as: complicated operation and management, difficult control of dosage, and The equipment is complex, and the ...

Claims

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Application Information

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IPC IPC(8): C02F3/28C02F3/34C02F101/16C02F101/30
CPCC02F3/2806C02F3/34C02F2101/16C02F2101/163C02F2101/166C02F2101/30C02F2203/006
Inventor 卢忆
Owner ZHEJIANG OCEAN UNIV
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