System and method for deeply treating brown alga chemical engineering waste calcium water through double-membrane technology

A technology of advanced treatment and double-membrane method, applied in chemical instruments and methods, water/sewage treatment, flotation water/sewage treatment, etc., can solve the impact of treatment process, increase treatment cost, equipment cost and large-scale floor area and other problems, to achieve the effect of simplifying the process steps, simplifying the pretreatment process, and facilitating the scale-up of the process

Inactive Publication Date: 2017-07-25
CHINA UNIV OF PETROLEUM (EAST CHINA)
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the pretreatment steps of this invention are complicated, the equipment cost and floor space are too large, and the addition of various chemical reagents not only increases the treatment cost but also affects the subsequent treatment process
The Chinese invention patent CN102745841A published in 2012, "A New Recycling Process for Brown Algae Chemical Waste Calcium Water", describes a technology that combines chemical precipitation, electrodialysis and ion exchange to treat waste calcium water; the electrodialysis process in this invention can The consumption is too high, the cost of regeneration is high, and a large amount of regeneration waste liquid is produced, the cost of treating actual sewage is too high, and it has no practical value
However, the above-mentioned technologies still require the use of a large amount of chemicals, and at the same time, after the waste calcium water is treated and reused, a large amount of high-salt wastewater will still be produced, and the later wastewater treatment is more difficult.
[0005] At present, there is no report on the method of using ceramic membrane modules to treat brown algae chemical waste calcium water

Method used

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  • System and method for deeply treating brown alga chemical engineering waste calcium water through double-membrane technology
  • System and method for deeply treating brown alga chemical engineering waste calcium water through double-membrane technology

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Embodiment 1

[0024] The method for advanced treatment of brown algae chemical waste calcium water by double-membrane method comprises the following steps:

[0025] (1) A system for advanced treatment of brown algae chemical waste calcium water using a double-membrane method; the ceramic membrane module 2 is a flat ceramic membrane module with a hydrophilic surface, and the average pore size of the ceramic membrane is 100nm; the reverse osmosis membrane module 4 is a hollow reverse osmosis membrane module. Permeable membrane components;

[0026] (2) The brown algae chemical waste calcium water is input into the coagulation-air flotation treatment tank 1 through the brown algae chemical waste calcium water pipeline 8 to remove the alginate and then input into the ceramic membrane module 2, and the filtrate is obtained by separating under the condition of an operating pressure of 0.2 MPa 1 and concentrated water, the filtrate 1 is passed into the activated carbon tank 3 for filtration and the...

Embodiment 2

[0030] The method for advanced treatment of brown algae chemical waste calcium water by double-membrane method comprises the following steps:

[0031] (1) A system for advanced treatment of waste calcium water from brown algae chemical industry using a double-membrane method; the ceramic membrane module 2 is a tubular ceramic membrane module with a hydrophilic surface, and the average pore diameter of the ceramic membrane is 10nm; the reverse osmosis membrane module 4 is a tubular ceramic membrane module. type reverse osmosis membrane module;

[0032] (2) The brown algae chemical waste calcium water is input into the coagulation-air flotation treatment tank 1 through the brown algae chemical waste calcium water pipeline 8 to remove the alginate, and then input into the ceramic membrane module 2, and the filtrate is obtained by separating under the condition of an operating pressure of 0.1 MPa 1 and concentrated water, the filtrate 1 is passed into the activated carbon tank 3 f...

Embodiment 3

[0034] The method for advanced treatment of brown algae chemical waste calcium water by double-membrane method comprises the following steps:

[0035] (1) A system for advanced treatment of waste calcium water from brown algae chemical industry using a double-membrane method; the ceramic membrane module 2 is a tubular ceramic membrane module with a hydrophilic surface, and the average pore size of the ceramic membrane is 200nm; the reverse osmosis membrane module 4 is a flat plate reverse osmosis membrane components;

[0036] (2) The brown algae chemical waste calcium water is input into the coagulation-air flotation treatment tank 1 through the brown algae chemical waste calcium water pipeline 8 to remove the alginate, and then input into the ceramic membrane module 2, and the filtrate is obtained by separating under the condition of an operating pressure of 0.4MPa 1 and concentrated water, the filtrate 1 is passed into the activated carbon tank 3 for filtration and then pass...

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Abstract

The invention discloses a system and a method for deeply treating brown alga chemical engineering waste calcium water through a double-membrane technology. The system for deeply treating brown alga chemical engineering waste calcium water through the double-membrane technology is characterized in that a brown alga chemical engineering waste calcium water pipeline 8 is sequentially connected with a coagulation-air flotation treatment tank 1, a ceramic membrane module 2, an activated carbon tank 3 and a reverse osmosis membrane module 4, and the reverse osmosis membrane module 4 is connected with a production water pipe 9; and the ceramic membrane module 2 is connected with a settlement tank 6 through a pipeline, and the settlement tank 6 is connected with an oxidation reactor 7 and the coagulation-air flotation treatment tank 1 through a pipeline. The ceramic membrane module is used to pre-treat the waste calcium water, so the process treatment step is simplified; and the ceramic membrane module occupies a small area and has a high sewage treatment efficiency. The pretreatment using a ceramic ultrafiltration membrane system significantly reduces the pollution of a reverse osmosis membrane, reduces the cost of the pretreatment process and realizes easy technology amplification.

Description

technical field [0001] The invention relates to the field of sewage treatment of seaweed industrial production, in particular to the treatment of waste calcium water produced in the production process of sodium alginate products. Background technique [0002] Seaweed processing products mainly include red algae gelatinous products and brown algae chemical products. my country's annual production capacity of alginate products is about 35,000 tons, accounting for 60% of the world's total production capacity. It is a pillar product in my country's seaweed processing industry and has been widely used in printing and dyeing, medicine, food, daily necessities and other fields. The production of 1 ton of alginate will consume 1,000 tons of fresh water, and the waste calcium water produced will account for more than 70% of all wastewater. The reuse of the above-mentioned sewage after treatment will effectively reduce the production cost of enterprises, save fresh water resources, a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/04
CPCC02F9/00C02F1/44C02F1/441C02F1/52C02F1/24C02F1/283
Inventor 牛青山袁涛王婧雯远冰冰
Owner CHINA UNIV OF PETROLEUM (EAST CHINA)
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