Formaldehyde elimination agent and preparation method thereof
A technology of formaldehyde eliminating agent and dispersing agent, which is applied in separation methods, chemical instruments and methods, and other chemical processes, can solve problems such as insufficient reaction and low formaldehyde removal rate, and achieve improved elimination effect, wide application range, and wide application easy effect
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[0056] 1. Preparation of silver-loaded nano anatase titanium dioxide:
[0057] B1, the anatase type titanium dioxide is immersed in the silver ammonia solution that is made of 2% silver nitrate solution and 2% ethylenediamine, and evaporated to dryness in a water bath;
[0058] B2, the product obtained in the above steps is calcined for 2 hours and reduced with hydrogen to obtain a silver-loaded nano anatase titanium dioxide finished product with a particle size of 15-30nm and a silver content of preferably 0.1-0.5%wt.
[0059] The chemical material used is commercially available anatase titanium dioxide, and the preferred model is Evonik P25.
[0060] 2. The preparation of polypeptide molecules refers to the patent CN1865279B "Preparation Method for Solid-Phase Polypeptide Synthesis of Thymopentin", which uses CTC resin as the starting material, Fmoc-protected amino acid as the monomer, and TBTU / HOBt as the condensation agent. Amino acids or derivatives, Boc-Arg-OH is used f...
Embodiment 1
[0064] Preparation of Alfa-cyclodextrin-grafted oligopeptides:
[0065] A1, using CTC resin as raw material, L-arginine, L-alanine, and L-glutamic acid with a molar ratio of 2:1:1 protected by Fmoc as monomers, and TBTU / HOBt as a condensation agent, After the peptide chain is made, add a peptide cutting reagent to cut the peptide, and then add ether to precipitate to make a crude product; separate and purify the above crude product through a C18 column to obtain a polypeptide molecule;
[0066] A2. Dissolve 4% Alfa-cyclodextrin in deionized water; add 0.05% coupling agent DDC and 15% polypeptide molecules in turn, stir and react at 25°C for 2 hours to complete polycondensation, filter and dry to obtain Alfa- Cyclodextrin-grafted oligopeptides.
[0067] A kind of preparation of formaldehyde eliminating agent:
[0068] S1. Mix 15% Alfa-cyclodextrin-grafted oligopeptide with 0.1% dispersant-alkyl dimethyl betaine, add it into deionized water, and stir for 20 minutes to prepare ...
Embodiment 2
[0072] The preparation method of the Alfa-cyclodextrin grafted oligopeptide and the preparation method of the formaldehyde scavenger in this embodiment are the same as in Example 1, and will not be repeated here; wherein:
[0073] The amino acid monomer in step A1 is L-arginine, L-methionine, L-lysine with a molar ratio of 2:1:1;
[0074] In step A2, the Alfa-cyclodextrin is 4%, the coupling agent DDC is 0.05%, the polypeptide molecule is 15%, the reaction temperature is 25°C, and the reaction time is 2 hours;
[0075] In step S1, the oligopeptide grafted with Alfa-cyclodextrin is 15%, the dispersant is 0.1% alkyl dimethyl betaine, and the stirring time is 20 minutes;
[0076] In the step S2, the stock solution of camphor fendourea is 0.1%, AEO3 is 0.3%, and the stirring time is 20 minutes;
[0077] In step S3, the silver-loaded nano anatase titanium dioxide is 1%, and the stirring time is 20 minutes.
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