A method for excess sludge treatment and resource recovery and a method for improving the yield of vfas

A technology of excess sludge and resource recovery, applied in the field of organic solid waste recycling, can solve the problem of long anaerobic fermentation of sludge and denitrification and phosphorus removal, increasing subsequent treatment steps of fermentation broth, unfavorable process operation and management, etc. problems, to achieve the effect of simplifying the process flow, reducing the subsequent processing process, and improving the yield

Active Publication Date: 2020-02-14
JIANGNAN UNIV
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, there are also some problems in this method: on the one hand, a large amount of ammonia nitrogen is produced due to the gradual consumption of protein substances during the fermentation process, and the concentration of ammonia nitrogen can reach more than 1000 mg / L. The efficiency of anaerobic fermentation is low; on the other hand, the nitrogen and phosphorus content of the fermentation liquid is high, far exceeding the discharge limit of the sewage plant, and it cannot be directly put into the sewage plant as a carbon source. The fermentation liquid often needs to be denitrified and dephosphorized. can be used as an external carbon source
However, due to the need for solid-liquid separation and chemical denitrification and phosphorus removal of the sludge after fermentation, the subsequent treatment steps of the fermentation broth are increased, which is not conducive to the operation and management of the entire process. operation, the total cycle of sludge anaerobic fermentation and nitrogen and phosphorus removal is relatively long, the efficiency is low, and the energy consumption is too large

Method used

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  • A method for excess sludge treatment and resource recovery and a method for improving the yield of vfas
  • A method for excess sludge treatment and resource recovery and a method for improving the yield of vfas
  • A method for excess sludge treatment and resource recovery and a method for improving the yield of vfas

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Experimental program
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Effect test

Embodiment 1

[0029] (1) The first stage (UASB liquid fermentation without adding nitrogen and phosphorus removal device): use deionized water to adjust the total solid concentration (TS) of the remaining sludge (Wuxi Shuofang Sewage Plant, Jiangsu) to 75g / L, and use The NaOH solution adjusts its pH to 12, and after sealing, it is placed under the condition of 90-105° C. and stirred slowly for 12 hours for pretreatment. The pretreatment hydrolyzate is centrifuged, separated liquid (organic load is 8kg COD / m 3 / d) Continuously feed into a 5L UASB reactor (inoculation seed sludge occupies 20% of the volume) for fermentation. During fermentation, the temperature in the reactor is controlled at 35±2°C, the pH is controlled at 9-10, and the yields of ammonia nitrogen, total phosphorus, and TVFA are as follows: figure 2 , 3 Shown in the first stage of . The concentrations of ammonia nitrogen and total phosphorus were 991.60±3.23mg / L and 532.16±1.59mg / L respectively during smooth operation, an...

Embodiment 2

[0032] UASB liquid fermentation with nitrogen and phosphorus removal device added:

[0033] Use deionized water to adjust the total solids concentration (TS) of the remaining sludge (Wuxi Shuofang Sewage Plant, Jiangsu) to 75g / L, and adjust its pH to 12 with NaOH solution, seal it and place it at 95°C for 12 hours with slow stirring preprocessing. The pretreatment hydrolyzate is centrifuged, separated liquid (organic load is 8kg COD / m 3 / d) Continuously feed into a 5L UASB reactor (inoculation seed sludge occupies 20% of the volume) for fermentation. During the fermentation, the temperature in the reactor is controlled at 35±2° C., and the pH is controlled at 9-10. Among them, the fermented liquid of UASB enters the nitrogen and phosphorus removal device with a reflux ratio of 0.8 and an HRT of 2.0h, and the nitrogen and phosphorus removal device maintains Mg 2+ Dosing concentration is 1000±5.0mg / L, temperature and pH are the same as UASB. During smooth operation, the ammo...

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Abstract

The invention discloses a method for regulating the acidogenic effect of liquid state fermentation of sludge and removing nitrogen and phosphorus on line, which belongs to the field of turning organic solid wastes into sources. The method couples and synchronizes a denitrifying and dephosphorizing device and an upflow anaerobic sludge fluidized bed (UASB) to achieve the objective of removing nitrogen and phosphorus and increasing the yield of volatile fatty acid (VFA). The denitrifying and dephosphorizing device, which is of an upflow type, receives fermented liquid coming from the UASB after the liquid state fermentation of sludge, dissolved magnesium salt is added according to a produced struvite proportion, the denitrified and dephosphorized liquid flows back into the UASB, and produced struvite precipitate is removed from the bottom of a reactor. Compared with ammonia nitrogen and total phosphorus in the fermented liquid of a UASB not synchronized with a denitrifying and dephosphorizing device, ammonia nitrogen and total phosphorus in the fermented liquid of the method disclosed by the invention are respectively decreased by 78.09 plus or minus 0.30 percent and 94.61 plus or minus 0.51 percent, and meanwhile, 1.52 plus or minus 0.04g of struvite / g of PO4<3-> is recovered. Moreover, the proportions of acetic acid and propionic acid are increased to 66.76 plus or minus 0.23 percent and 16.54 plus or minus 0.17 percent, and the directional acidogenesis of acetic acid and propionic acid is enhanced.

Description

technical field [0001] The invention relates to a method for excess sludge treatment and resource recovery and a method for increasing the yield of VFAs, belonging to the field of organic solid waste recycling. Background technique [0002] The anaerobic fermentation of municipal surplus sludge to produce volatile fatty acids (VFAs), as a way of sludge resource utilization, has attracted increasing attention in sewage treatment plants. Sludge liquid fermentation is an efficient acid production method, which has the advantages of high fermentation intensity, high VFAs production and low operating energy consumption. However, there are also some problems in this method: on the one hand, a large amount of ammonia nitrogen is produced due to the gradual consumption of protein substances during the fermentation process, and the concentration of ammonia nitrogen can reach more than 1000 mg / L. The efficiency of anaerobic fermentation is low; on the other hand, the nitrogen and pho...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F9/14C01B25/45C02F101/10C02F101/16
CPCC01B25/451C02F1/5236C02F3/2846C02F2101/105C02F2101/16
Inventor 刘和李祎飞马惠君刘宏波符波
Owner JIANGNAN UNIV
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