A kind of composite photocatalyst and preparation method thereof
A catalyst and composite light technology, applied in chemical instruments and methods, physical/chemical process catalysts, metal/metal oxide/metal hydroxide catalysts, etc., can solve the problems of inability to achieve large-scale production and waste, and achieve a wide range of The effect of application prospect and industrialization prospect, easy operation and stable structure
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Embodiment 1
[0021] Disperse cadmium nitrate and thioacetamide into 40ml mixed solution at a mass ratio of 0.4:1, the volume ratio of triethylenediamine and deionized water in the mixed solution is 2:1, heat to 80°C for 16h, and then centrifuge , and vacuum dried at 60°C for 6h to obtain CdS nanocrystals.
[0022] CdS nanocrystals are mixed with 15ml ethylene glycol, 0.3g sodium molybdate, and 0.5g bismuth nitrate and added to 25ml deionized water, and the mixed solution is transferred to a 50ml polytetrafluoroethylene-lined stainless steel reactor, heated to React at 180°C for 24 hours to prepare bismuth molybdate and cadmium sulfide composite photocatalyst.
[0023] Such as figure 1 As shown in the photo of the TEM spectrum of the produced bismuth molybdate and cadmium sulfide, the hydrogen production performance can reach 2490 micromoles after 2 hours.
Embodiment 2
[0025] Disperse 20g of cadmium chloride and 15g of sodium sulfide into a 2L mixed solution, the volume ratio of diethylenetriamine and deionized water in the mixed solution is 1:1, then heat the mixed solution to 180°C for 48 h, then centrifuge, Vacuum drying to obtain CdS nanocrystals.
[0026] CdS nanocrystals were mixed with 0.5L Tween, 30g ammonium molybdate, and 15g bismuth chloride into 5L deionized water, and the mixed solution was heated to 200°C for hydrothermal reaction for 36 hours to prepare bismuth molybdate and cadmium sulfide composite photocatalyst.
[0027] Its photocatalytic degradation efficiency of methylene blue dye wastewater reaches 98%.
Embodiment 3
[0029] Disperse 1Kg of cadmium acetate and 1Kg of sublimed sulfur into a 30L mixed solution, the volume ratio of hexamethylenetetramine and deionized water in the mixed solution is 4:1, then heat the mixed solution to 110°C for 30 h, then centrifuge , dried in vacuum to obtain CdS nanocrystals.
[0030] Mix CdS nanocrystals with 1L disodium lauryl sulfosuccinate monoester, 900g molybdenum trioxide, 1.5Kg bismuth subnitrate and add to 7L deionized water, heat the mixed solution to 220°C for 24 hours to produce molybdic acid Bismuth and cadmium sulfide composite photocatalyst.
[0031] Its photocatalytic degradation of heavy metal Cr 3+ Ions are 96% efficient.
[0032] The invention discloses a composite photocatalyst of bismuth molybdate and cadmium sulfide, which can decompose water by using visible light in sunlight to generate hydrogen. Owing to what utilize is visible light to go to produce hydrogen, the ratio that visible light accounts for in sunlight is 49%, and this ...
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