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A kind of composite photocatalyst and preparation method thereof

A catalyst and composite light technology, applied in chemical instruments and methods, physical/chemical process catalysts, metal/metal oxide/metal hydroxide catalysts, etc., can solve the problems of inability to achieve large-scale production and waste, and achieve a wide range of The effect of application prospect and industrialization prospect, easy operation and stable structure

Active Publication Date: 2020-01-17
HUAIBEI NORMAL UNIVERSITY
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the prior art, some patents use ultraviolet light to decompose water and produce hydrogen. Hydrogen is indeed an ideal energy source. Under the action of a catalyst, water is decomposed to produce hydrogen and oxygen. After the hydrogen is burned, water is produced, without any pollution to the environment. Moreover, the energy generated is very considerable, and hydrogen can be used to replace traditional energy sources; there are also technical papers that disclose hydrogen production by using ultraviolet light to produce hydrogen, but the proportion of ultraviolet light in sunlight is only 2%, and the rest 98% are all wasted. Although sunlight is infinite, such a small proportion cannot be mass-produced.

Method used

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  • A kind of composite photocatalyst and preparation method thereof

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Effect test

Embodiment 1

[0021] Disperse cadmium nitrate and thioacetamide into 40ml mixed solution at a mass ratio of 0.4:1, the volume ratio of triethylenediamine and deionized water in the mixed solution is 2:1, heat to 80°C for 16h, and then centrifuge , and vacuum dried at 60°C for 6h to obtain CdS nanocrystals.

[0022] CdS nanocrystals are mixed with 15ml ethylene glycol, 0.3g sodium molybdate, and 0.5g bismuth nitrate and added to 25ml deionized water, and the mixed solution is transferred to a 50ml polytetrafluoroethylene-lined stainless steel reactor, heated to React at 180°C for 24 hours to prepare bismuth molybdate and cadmium sulfide composite photocatalyst.

[0023] Such as figure 1 As shown in the photo of the TEM spectrum of the produced bismuth molybdate and cadmium sulfide, the hydrogen production performance can reach 2490 micromoles after 2 hours.

Embodiment 2

[0025] Disperse 20g of cadmium chloride and 15g of sodium sulfide into a 2L mixed solution, the volume ratio of diethylenetriamine and deionized water in the mixed solution is 1:1, then heat the mixed solution to 180°C for 48 h, then centrifuge, Vacuum drying to obtain CdS nanocrystals.

[0026] CdS nanocrystals were mixed with 0.5L Tween, 30g ammonium molybdate, and 15g bismuth chloride into 5L deionized water, and the mixed solution was heated to 200°C for hydrothermal reaction for 36 hours to prepare bismuth molybdate and cadmium sulfide composite photocatalyst.

[0027] Its photocatalytic degradation efficiency of methylene blue dye wastewater reaches 98%.

Embodiment 3

[0029] Disperse 1Kg of cadmium acetate and 1Kg of sublimed sulfur into a 30L mixed solution, the volume ratio of hexamethylenetetramine and deionized water in the mixed solution is 4:1, then heat the mixed solution to 110°C for 30 h, then centrifuge , dried in vacuum to obtain CdS nanocrystals.

[0030] Mix CdS nanocrystals with 1L disodium lauryl sulfosuccinate monoester, 900g molybdenum trioxide, 1.5Kg bismuth subnitrate and add to 7L deionized water, heat the mixed solution to 220°C for 24 hours to produce molybdic acid Bismuth and cadmium sulfide composite photocatalyst.

[0031] Its photocatalytic degradation of heavy metal Cr 3+ Ions are 96% efficient.

[0032] The invention discloses a composite photocatalyst of bismuth molybdate and cadmium sulfide, which can decompose water by using visible light in sunlight to generate hydrogen. Owing to what utilize is visible light to go to produce hydrogen, the ratio that visible light accounts for in sunlight is 49%, and this ...

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Abstract

The invention discloses a composite photocatalyst, which refers to a composite photocatalyst of bismuth molybdate and cadmium sulfide. The composite photocatalyst can enable water to continuously generate hydrogen under visible light irradiation of sunlight, and its preparation method is disclosed. The bismuth molybdate and cadmium sulfide composite photocatalyst prepared by the present invention has a large-area contact interface, which is conducive to carrier separation. The structure of the bismuth molybdate and cadmium sulfide is stable and the band gap is matched, which improves the photocatalytic activity and stabilizes the catalytic effect. It has excellent properties of photolysis of water to produce hydrogen, photodegradation of organic pollutants, heavy metal ions and reduction of carbon dioxide; the synthesis method has common raw materials, simple preparation operation process, easy to realize process parameters, low cost, easy operation, high yield and long cycle life. , has broad application prospects and industrialization prospects in the fields of photolysis of water to produce hydrogen, photodegradation of organic pollutants, reduction of heavy metal ions and carbon dioxide.

Description

technical field [0001] The invention relates to a composite photocatalyst and a preparation method thereof, belonging to the technical field of nanometer material preparation, in particular to a composite nanometer material and a preparation method thereof. Background technique [0002] In recent years, the energy crisis has intensified, oil has become increasingly depleted, and oil prices have risen, resulting in slow global economic growth. Countries have implemented various policies to solve the energy crisis, and some countries have launched wars to seize crude oil, the Iranian Revolution, the Persian Gulf War, and Iraq All wars are for the control of oil, and the ultimate goal is to solve the energy crisis. In order to solve the energy crisis in the world, many new energy sources and new methods have also been developed, such as photolysis hydrogen production, wind power generation, tidal power generation, geothermal power generation, etc., but most of the methods have ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J27/051
CPCB01J23/31B01J27/04B01J27/051B01J35/19B01J35/39
Inventor 代凯李真吕佳丽王中辽霍瑶胡太平张金锋李强
Owner HUAIBEI NORMAL UNIVERSITY
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