Manufacturing method for novel flexible thermoelectric element
A technology of thermoelectric elements and manufacturing methods, which is applied in the manufacture/processing of thermoelectric devices, thermoelectric device components, thermoelectric device node lead-out materials, etc., which can solve the problems that cannot be made into flexible thermoelectric devices on a large scale, and achieve energy density High, simple manufacturing process, compact circuit structure
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[0019] Example 1:
[0020] Preparation of carbon-filled poly-3,4-ethylenedioxythiophene: P-type thermoelectric material dispersion slurry of polysulfonated styrene and tungsten carbide-filled poly-3,4-ethylenedioxythiophene / polydiallyl two The N-type thermoelectric material dispersion slurry of methyl ammonium chloride is used to print P-type thermoelectric material slurry and N-type thermoelectric material slurry on both sides of the flexible polyimide substrate by screen printing. After drying, the N-type thermoelectric material slurry is obtained. For the circuit layer of P-type thermoelectric material, drill a row of through holes at both ends of the flexible insulating substrate. The through holes are gold-plated, and the circuit layers on both sides are connected through the gold-plated through holes at both ends to form an alternating series circuit structure of NPNP... Obtain flexible thermoelectric elements, the front and cross sections are as figure 1 with figure 2 Sho...
Example Embodiment
[0022] Example 2:
[0023] Prepare Bi 0.5 Sb 1.5 Te 3 P-type thermoelectric material dispersion slurry filled with polyvinylidene fluoride and Bi 2 Te 2.7 Se 0.3 N-type thermoelectric material dispersion paste filled with polyvinylidene fluoride, P-type thermoelectric material paste and N-type thermoelectric material paste are printed by screen printing on both sides of the flexible polyethylene terephthalate substrate, and dried After obtaining the circuit layers of N-type and P-type thermoelectric materials, drill a row of through holes at both ends of the flexible insulating substrate. The through holes are plated with silver, and the circuit layers on both sides are connected to form NPNP through the through holes plated at both ends. …The alternating series circuit structure obtains flexible thermoelectric elements.
[0024] Dangru Figure 4 When current is applied to the series circuit shown, one side of the flexible substrate can be cooled, and the other side can dissipate ...
Example Embodiment
[0025] Example 3:
[0026] The P-type thermoelectric material dispersion slurry filled with carbon nanotubes filled with polyaniline and the N-type thermoelectric material dispersion slurry filled with polyvinylidene fluoride filled with tungsten carbide were prepared, and screen printing was used on both sides of the flexible polybutylene terephthalate substrate. Print P-type thermoelectric material slurry and N-type thermoelectric material slurry, and obtain the circuit layer of N-type and P-type thermoelectric material respectively after drying. Drill a row of through holes at both ends of the flexible insulating substrate. Copper-plated, the circuit layers on both sides are connected to an alternate series circuit structure of NPNP... through copper-plated through holes at both ends to obtain a flexible thermoelectric element.
[0027] When there is a temperature difference between the two ends of the flexible insulating substrate, a potential difference is generated in the alt...
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