Ordered mesoporous composite catalyst and preparation method and application thereof
A composite catalyst and catalyst technology, applied in the direction of catalyst activation/preparation, preparation of organic compounds, chemical instruments and methods, etc., can solve the problems of low selectivity of low-carbon alcohols, limited catalyst activity, high water content of products, etc. The effect of mass resistance
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Embodiment 1
[0037] An ordered mesoporous composite catalyst, the preparation steps are as follows:
[0038] ①At 40°C, dissolve 1.0g triblock copolymer F127 in 8.0g ethanol, add 0.9g dilute hydrochloric acid (0.2M), stir, add 3.2g zirconium oxychloride and 0.8g ethanol solution of phenolic resin , continue stirring. The solution was spread on a film and left to evaporate the solvent, and then polymerized and crosslinked at 100°C for 24 hours. Afterwards, the material was ground into powder and calcined at 500 °C for 5 h under nitrogen atmosphere to obtain the ordered mesoporous carrier C-ZrO 2 ;
[0039] 2. Get the carrier 44.3g that step 1. obtains and impregnate in be dissolved with 9.5g copper nitrate (Cu(NO 3 ) 2 ·3H 2 O), 12.4g cobalt nitrate (Co(NO 3 ) 2 ·6H 2 O), 0.3g ruthenium chloride (RuCl 2 ·3H 2 O) and 1.3g potassium acetate (CH 3 COOK) mixed solution 30ml, soaked at room temperature for 14h, then dried in air at 110°C for 12h, and then calcined at 450°C for 5h to pr...
Embodiment 2
[0042] An ordered mesoporous composite catalyst, the preparation steps are as follows:
[0043] ① Dissolve 1.2g triblock copolymer P123 in 10.0g ethanol at 42°C, add 1.1g0.2mol / l dilute hydrochloric acid, stir, add 3.4g zirconium oxychloride and 0.9g ethanol solution of phenolic resin , continue stirring. Spread the solution on a film and let it stand to evaporate the solvent, then polymerize and cross-link at 105°C for 28h. Grind the material into powder, and calcined at 550 °C for 4 h under nitrogen atmosphere to obtain the ordered mesoporous carrier C-ZrO 2 ;
[0044] 2. Get the carrier 43.8g that step 1. obtains and impregnate in be dissolved with 9.5g copper nitrate (Cu(NO 3 ) 2 ·3H 2 O), 15.3g iron nitrate (Fe(NO 3 ) 3 9H 2 O), 0.5g ruthenium chloride (RuCl 2 ·3H 2 O) and 2.6g potassium acetate (CH 3 COOK) in 40ml of mixed solution, immersed at room temperature for 16h, dried in air at 110°C for 14h, and then calcined at 480°C for 5h to obtain catalyst B;
[...
Embodiment 3
[0047] An ordered mesoporous composite catalyst, the preparation steps are as follows:
[0048] ① Dissolve 1.0g triblock copolymer F127 in 10.0g ethanol at 40°C, add 0.9g0.2mol / l dilute hydrochloric acid, stir, add 2.8g zirconium oxychloride and 0.8g ethanol solution of phenolic resin , continue stirring. Spread the solution on a film and let it stand to evaporate the solvent, then polymerize and cross-link at 105°C for 24h. Grind the material into powder, and calcined at 600 °C for 3 h under nitrogen atmosphere to obtain the ordered mesoporous carrier C-ZrO 2 ;
[0049] 2. Get the carrier 49g that step 1. obtains and impregnate in be dissolved with 9.5g copper nitrate (Cu(NO 3 ) 2 ·3H 2 O), 12.4g nickel nitrate (Ni(NO 3 ) 2 ·6H 2 O), 0.7g palladium chloride (PdCl 2 ) and 1.3g potassium acetate (CH 3 COOK) in 30ml of mixed solution, immersed at room temperature for 14h, dried in air at 110°C for 12h, and then calcined at 450°C for 5h to obtain catalyst C;
[0050] T...
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