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Ellagic acid prepared through liquid-state fermentation of granatanine and preparation method thereof

A technology of liquid fermentation and ellagic acid, which is applied in the fields of cosmetics, health care products, and pharmaceuticals. It can solve the problems of high-concentration strong acid consumption, uneven fermentation, troublesome loading and discharging, etc., and achieves increased utilization times, mild fermentation conditions, The effect of improving utilization efficiency

Active Publication Date: 2017-12-01
ZAOZHUANG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the preparation process of gallic acid (ester) is cumbersome and complicated, and the enzyme also needs to be refined and purified, and there are unknown quinones in the synthetic product, and the ratio of it to ellagic acid is 1: 2.4, which brings certain difficulties to the separation and purification of the product. Difficulties, at present, this method is rarely used for the production of ellagic acid
[0008] The third is the process of preparing ellagic acid by acid hydrolysis (patent number: 200510002081.X). This method has higher yield and purity, but it needs to consume high-concentration strong acid and complete it under long-term heating conditions. The equipment has high requirements on anti-corrosion ability and serious environmental pollution
This method uses a fermenter for solid-state fermentation, which is cumbersome for loading and discharging, and the fermentation is uneven in the upper and lower parts; moreover, the method only uses a single strain of fermentation, and the efficiency needs to be improved. These aspects have certain restrictions on large-scale industrial production.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] (1) Preparation of pomegranate peel tannin extract

[0024] Grind the dried pomegranate peel to 40 mesh, use 62% ethanol solution at 72°C to reflux extract three times, add ethanol solution for the first time which is 12 times the mass of pomegranate peel powder, extract for 2 hours, and centrifuge to separate the filtrate and filter residue; For the second time, add 10 times of ethanol solution to the filter residue, extract for 1.5 h, and centrifuge; for the third time, add 8 times of ethanol solution to the filter residue, extract for 1 h, and centrifuge; combine the filtrates from three times, recover ethanol by distillation, and obtain pomegranate The concentrated aqueous solution of leather tannin extraction can be directly used in fermentation production. The tannin content in the extracted concentrated aqueous solution is determined to be 1% to 1.5%.

[0025] (2) Cultivation and co-immobilization of fermentation strains

[0026] After Aspergillus niger, Penici...

Embodiment 2

[0032] (1) Preparation of pomegranate peel tannin extract

[0033] Grind the dried pomegranate peel to 40 mesh, use: 65% ethanol solution at 73°C for reflux extraction three times, add ethanol solution for the first time which is 14 times the mass of pomegranate peel powder, extract for 2 h, and centrifuge the filtrate and filter residue Add 9 times of ethanol solution to the filter residue for the second time, extract for 1.5 h, and centrifuge; add 7 times of ethanol solution to the filter residue for the third time, extract for 1 h, and centrifuge; combine the filtrates for three times, recover ethanol through distillation, and obtain The concentrated aqueous solution of pomegranate peel tannin extraction can be directly used in fermentation production. The tannin content in the extracted concentrated aqueous solution is determined to be 1% to 1.5%.

[0034] (2) Cultivation and co-immobilization of fermentation strains

[0035] Aspergillus niger, Penicillium and Escherichi...

Embodiment 3

[0041] (1) Preparation of pomegranate peel tannin extract

[0042] Grind the dried pomegranate peel to 40 mesh, use 70% volume fraction of ethanol solution to reflux extract at 75 ℃ for three times, add ethanol solution for the first time which is 15 times the mass of pomegranate peel powder, extract for 2 h, and centrifuge to separate the filtrate and filter residue; Add 8 times of ethanol solution to the filter residue for the second time, extract for 1.5 h, and centrifuge; add 6 times of ethanol solution to the filter residue for the third time, extract for 1 h, and centrifuge; combine the filtrates from three times, recover ethanol by distillation, and obtain pomegranate The concentrated aqueous solution of leather tannin extraction can be directly used in fermentation production. The tannin content in the extracted concentrated aqueous solution is determined to be 1% to 1.5%.

[0043] (2) Cultivation and co-immobilization of fermentation strains

[0044] After Aspergill...

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Abstract

An ellagic acid prepared through liquid-state fermentation of granatanine and a preparation method thereof belong to the technical fields of cosmetics, drugs and healthcare products. According to the ellagic acid prepared through liquid-state fermentation of granatanine and the preparation method thereof, granatanine extract aqueous solution is taken as substrate for liquid-stage fermentation in a fermentation tank; Asperigillus niger, Pencicillin G and Escherichia. Coli are mixed proportionally and immobilized beads are prepared through sodium carboxymethylcellulose, sodium alginate and diatomite to achieve repeated application and further to improve the utilization rate of strains; mixed fermentation of the three bacteria can achieve complementary effects to increase conversion efficiency of ellagic acid. The preparation method of the ellagic acid prepared through liquid-state fermentation of the granatanine is mild in fermentation conditions, capable of greatly reducing consumption of chemical substances, small in environmental pollution and more applicable to large-scale production.

Description

technical field [0001] The invention relates to preparation of ellagic acid by liquid-state fermentation of pomegranate peel tannin and a preparation method thereof, belonging to the technical fields of cosmetics, medicines, health care products and the like. Background technique [0002] Ellagic acid, formula C 14 h 6 o 8 , which is a dimeric derivative of gallic acid, is a polyphenolic dilactone. Pure ellagic acid is a yellow needle-like crystal, slightly soluble in water, alcohol, soluble in hot methanol, alkali and pyridine. Its molecular structure is as follows: [0003] Ellagic acid is a natural polyphenolic compound widely present in various nuts and fruits, especially in pomegranate peel. However, there are less free forms and more in condensed forms (such as ellagitannins, glycosides, etc.). my country has a large pomegranate planting area and abundant pomegranate peel resources. Except for a small part that is used as Chinese medicinal materials, most of th...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C12P39/00C12P17/18C12N11/12C12N11/10C12N11/14C12R1/685C12R1/80C12R1/19
CPCC12N11/10C12N11/12C12N11/14C12P17/181C12P39/00
Inventor 张立华吕慧张沛
Owner ZAOZHUANG UNIV