Antistatic treating agent and preparation method thereof

A technology of antistatic treatment agent and conductive agent, which is applied in the field of antistatic treatment agent and its preparation, to achieve the effects of not being easy to agglomerate, improving antistatic ability, and broadening the application field

Inactive Publication Date: 2017-12-22
江苏多森新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Synthetic leather is composed of organic polymer compounds, which is not easy to conduct electricity,

Method used

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  • Antistatic treating agent and preparation method thereof
  • Antistatic treating agent and preparation method thereof

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preparation example Construction

[0026] The embodiment of the present invention also provides a preparation method of an antistatic treatment agent, which mainly includes the following steps:

[0027] First, the graphite oxide is ultrasonically treated. Since a large number of oxygen-containing functional groups (such as hydroxyl and carboxyl) are inserted between the graphite oxide layers, the graphite oxide after ultrasonic treatment is easily peeled off, so that the graphite oxide is exfoliated into graphene oxide. Therefore, graphite oxide has the same chemical composition as graphene oxide, but the thickness of graphene oxide is smaller than that of graphite oxide. Therefore, graphene oxide has better electrical conductivity than graphite oxide. Of course, graphene oxide can also be purchased directly.

[0028] Then, the graphene oxide and the polymer polyol are added into the reaction kettle for stirring and mixing, and the stirring and mixing is carried out at 45-55°C. During this period, hydrophilic...

Embodiment 1

[0032] Raw material and quality used in this embodiment are as follows:

[0033] Polybutylene adipate neopentyl glycol ester diol (number average molecular weight 1000) 15g; polyadipate-1,4 butanediol ester diol (number average molecular weight 1000) 5g; triphenylmethane triisocyanate 5g ; Graphite oxide 0.1 g.

[0034] The preparation method of the antistatic treatment agent of the present embodiment is as follows:

[0035] Mix all the above-mentioned raw materials, keep the progress of the reaction at 50°C after mixing, judge the degree of progress of the reaction according to the change of the reaction solution, and finally obtain the antistatic treatment agent.

Embodiment 2

[0037] Raw material and quality used in this embodiment are as follows:

[0038] Polyethylene adipate diol (number-average molecular weight 3000) 10g; Polypropylene adipate diol (number-average molecular weight 1000) 5g; Polybutylene adipate diol hexanediol (number-average Molecular weight 2000) 13g; Triphenylmethane triisocyanate 8g; PPDI 14g; Graphite oxide 1g; Glycerol 0.3g; Pentanediol 0.5g; Deionized water 50g.

[0039] The preparation method of the antistatic treatment agent of the present embodiment is as follows:

[0040]Polyethylene adipate diol, polytrimethylene adipate diol, polybutylene adipate hexanediol diol, sodium sulfonate group-containing diol, carboxyl-containing polyester , Glycerin, Pentylene Glycol, and Graphite Oxide were put into the reaction kettle together, and stirred evenly at 45°C. Then slowly add the mixture of triphenylmethane triisocyanate and PPDI (the dropping rate is not limited), keep the temperature at 60°C for reaction, and after 3 hour...

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Abstract

The invention provides an antistatic treating agent and a preparation method thereof, and relates to the technical field of material preparation. Raw materials of the antistatic treating agent comprise the following components in parts by weight: 20-30 parts of polymer polyol, 5-22 parts of polyisocyanate and 0.1-1 part of a conductive agent, wherein various commonly used diols are mainly adopted as the polymer polyol, the polyisocyanate includes one or both of diisocyanate and triisocyanate, and the conductive agent comprises graphite oxide and/or graphene oxide. Isocyanate groups on the polyisocyanate can react with hydroxyl groups on the graphite oxide or graphene oxide, and the isocyanate groups can also react with hydroxyl groups of the polymer polyol simultaneously. Therefore, the graphite oxide is linked into a molecular chain of polyurethane by taking the polyisocyanate as a bridge, thereby fundamentally solving the problems of aggregation and sedimentation of the graphite oxide in polyurethane resin, and enhancing the antistatic capability of a surface of polyurethane synthetic leather.

Description

technical field [0001] The invention relates to the technical field of material preparation, in particular to an antistatic treatment agent and a preparation method thereof. Background technique [0002] With the continuous optimization of polyurethane raw materials and related formulation processes, polyurethane synthetic leather has penetrated into all aspects of people's lives. Polyurethane treatment agent can endow polyurethane synthetic leather with more excellent properties, especially to improve the surface mechanical properties of synthetic leather, such as wear resistance and scratch resistance. Synthetic leather is composed of organic polymer compounds, which is not easy to conduct electricity, but it will inevitably generate friction with the body during use, and it is very easy to generate static electricity. If static electricity cannot be derived from the surface of synthetic leather in time, excessive static electricity accumulation can easily lead to some ac...

Claims

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Application Information

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IPC IPC(8): C08G18/76C08G18/73C08G18/72C08G18/66C08G18/48C08G18/42C08G18/38C08G18/34C08G18/32D06M15/568D06M15/572
CPCC08G18/4202C08G18/3203C08G18/3206C08G18/348C08G18/3855C08G18/4018C08G18/42C08G18/4238C08G18/4854C08G18/6607C08G18/6611C08G18/6625C08G18/664C08G18/6644C08G18/6659C08G18/6674C08G18/6692C08G18/724C08G18/73C08G18/7614C08G18/7664C08G18/7671C08G18/7678D06M15/568D06M15/572
Inventor 何子健
Owner 江苏多森新材料科技有限公司
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