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Novel cationic dye flocculant as well as preparation method and application thereof

A cationic dye and flocculant technology, applied in chemical instruments and methods, flocculation/sedimentation water/sewage treatment, water pollutants, etc. Problems such as poor capture ability, to achieve the effect of solving the problem of complex heavy metal ions, high-efficiency capture of cationic dyes, and low processing costs

Active Publication Date: 2018-02-16
东营睿港管道工程有限责任公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the chemical structure of polyacrylamide is relatively simple, and there are problems such as poor ability to capture dye molecules, slow sedimentation speed, and inability to deal with complexed heavy metal ions.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] It is a new cationic dye flocculant prepared by the following steps:

[0029] Step 1 Synthesis of polymer backbone polymethylolacrylamide (PHAM)

[0030] Take 2 parts of azobisisobutyronitrile initiator, 200 parts of methylolacrylamide (HAM), and 200 parts of methanol, and carry out polymerization reaction at 75°C for 7 hours under the protection of nitrogen to obtain a degree of polymerization (DP) of 56 Polymethylolacrylamide (PHAM);

[0031] Step 2 Synthesis of anionic polymer side chain precursor polymer PtBMA-COOH and functional polymer side chain precursor polymer PNVF-COOH

[0032] Synthesis of anionic polymer side chain precursor polymer PtBMA-COOH: Take 2 parts of azobiscyanovaleric acid initiator, 100 parts of tert-butyl methacrylate (tBMA), 200 parts of toluene, in nitrogen Free radical polymerization was carried out at 75°C for 9 hours under protection to obtain PtBMA-COOH with a degree of polymerization (DP) of 50 anionic polymer side chain precursor poly...

Embodiment 2

[0042] It is a new cationic dye flocculant prepared by the following steps:

[0043] Step 1 Synthesis of polymer backbone polymethylolacrylamide (PHAM)

[0044] Take 2 parts of ethyl 2-bromoisobutyrate initiator, 3 parts of CuBr and 3 parts of 4,4-linked 2-picoline (BPy), 100 parts of methylolacrylamide (HAM), 50 Parts of methanol were polymerized at 55°C for 10 hours under the protection of nitrogen to obtain polymethylol acrylamide (PHAM) with a degree of polymerization (DP) of 140;

[0045] Step 2 Synthesis of anionic polymer side chain precursor polymer PtBMA-COOH and functional polymer side chain precursor polymer PNVF-COOH

[0046] Synthesis of anionic polymer side chain precursor polymer PtBMA-COOH: take 2 parts of azobiscyanovaleric acid initiator, 200 parts of tert-butyl methacrylate (tBMA), 100 parts of toluene, in nitrogen Free radical polymerization was carried out at 55°C under protection for 12 hours to obtain an anionic polymer side chain precursor polymer PtB...

Embodiment 3

[0056] It is a new cationic dye flocculant prepared by the following steps:

[0057] Step 1 Synthesis of polymer backbone polymethylolacrylamide (PHAM)

[0058] Take 1 part of ethyl 2-bromoisobutyrate initiator, 1 part of CuBr and 1 part of 4,4-linked 2-picoline (BPy), 100 parts of hydroxymethylacrylamide (HAM), 200 Parts of methanol were polymerized at 70°C for 8 hours under the protection of nitrogen to obtain polymethylolacrylamide (PHAM) with a degree of polymerization (DP) of 175;

[0059] Step 2 Synthesis of anionic polymer side chain precursor polymer PtBMA-COOH and functional polymer side chain precursor polymer PNVF-COOH

[0060] Synthesis of anionic polymer side chain precursor polymer PtBMA-COOH: take 1 part of azobiscyanovaleric acid initiator, 300 parts of tert-butyl methacrylate (tBMA), 200 parts of toluene, in nitrogen Free radical polymerization was carried out at 70°C under protection for 15 hours to obtain an anionic polymer side chain precursor polymer PtB...

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Abstract

The invention relates to a novel cationic dye flocculant as well as a preparation method and application thereof. The novel cationic dye flocculant is characterized by being prepared from polymer mainchain polyhydroxymethyl acrylamide, anionic polymer side chain precursor polymer terminated carboxyl-containing poly(tert-butyl methacrylate), functional polymer side chain precursor polymer terminated carboxyl-containing poly-N-vinyl amino formamide, dimethyl formamide, a catalyst, i.e., N-hydroxysuccinimide, [3-[(ethylimidocarbonyl)amino]propyl] trimethylammonium iodide, cyclohexanediamine tetraacetic acid dianhydride and potassium hydroxide; the novel cationic dye flocculant is used for treating dye waste water and artistic coating waste water which are discharged in a synthesis process ora dyeing and finishing process of dyes. The novel cationic dye flocculant is high in trapping capability and rapid in settling velocity, is capable of trapping cationic dye molecules and complex heavy metal ions within a few seconds, and can rapidly grow into large sedimentation particles, thus achieving the aim of separating the dyes; effluent is basically colorless; simple and convenient operation, low treatment cost and high adaptability are achieved.

Description

technical field [0001] The invention belongs to the field of water treatment technology and polymer functional materials, and specifically relates to a novel cationic dye flocculant and its preparation method and application, which is mainly used in dye wastewater and art paint wastewater discharged during dye synthesis or dyeing and finishing processes application, to achieve simultaneous removal of cationic dye molecules and complexed heavy metal ions in dye wastewater. Background technique [0002] In recent years, my country's annual sewage discharge has reached more than 39 billion tons, of which industrial sewage accounts for 51%, while dye wastewater accounts for 35% of the total industrial wastewater discharge, and it is increasing at a rate of 1% year by year. Dye wastewater mainly comes from dye synthesis and dye use enterprises, and is composed of dyes and auxiliaries discharged during the synthesis or dyeing and finishing process. With the rapid development of t...

Claims

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Application Information

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IPC IPC(8): C02F1/52C02F1/54C02F1/56C08G81/02C02F101/30C02F103/30
CPCC02F1/5236C02F1/54C02F1/56C02F2101/308C02F2103/30C08G81/021
Inventor 刘锋彭琦陈燕舞洪丹张浥琨郭志杰唐秋实霍应鹏
Owner 东营睿港管道工程有限责任公司
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