Novel cationic dye flocculant as well as preparation method and application thereof
A cationic dye and flocculant technology, applied in chemical instruments and methods, flocculation/sedimentation water/sewage treatment, water pollutants, etc. Problems such as poor capture ability, to achieve the effect of solving the problem of complex heavy metal ions, high-efficiency capture of cationic dyes, and low processing costs
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Embodiment 1
[0028] It is a new cationic dye flocculant prepared by the following steps:
[0029] Step 1 Synthesis of polymer backbone polymethylolacrylamide (PHAM)
[0030] Take 2 parts of azobisisobutyronitrile initiator, 200 parts of methylolacrylamide (HAM), and 200 parts of methanol, and carry out polymerization reaction at 75°C for 7 hours under the protection of nitrogen to obtain a degree of polymerization (DP) of 56 Polymethylolacrylamide (PHAM);
[0031] Step 2 Synthesis of anionic polymer side chain precursor polymer PtBMA-COOH and functional polymer side chain precursor polymer PNVF-COOH
[0032] Synthesis of anionic polymer side chain precursor polymer PtBMA-COOH: Take 2 parts of azobiscyanovaleric acid initiator, 100 parts of tert-butyl methacrylate (tBMA), 200 parts of toluene, in nitrogen Free radical polymerization was carried out at 75°C for 9 hours under protection to obtain PtBMA-COOH with a degree of polymerization (DP) of 50 anionic polymer side chain precursor poly...
Embodiment 2
[0042] It is a new cationic dye flocculant prepared by the following steps:
[0043] Step 1 Synthesis of polymer backbone polymethylolacrylamide (PHAM)
[0044] Take 2 parts of ethyl 2-bromoisobutyrate initiator, 3 parts of CuBr and 3 parts of 4,4-linked 2-picoline (BPy), 100 parts of methylolacrylamide (HAM), 50 Parts of methanol were polymerized at 55°C for 10 hours under the protection of nitrogen to obtain polymethylol acrylamide (PHAM) with a degree of polymerization (DP) of 140;
[0045] Step 2 Synthesis of anionic polymer side chain precursor polymer PtBMA-COOH and functional polymer side chain precursor polymer PNVF-COOH
[0046] Synthesis of anionic polymer side chain precursor polymer PtBMA-COOH: take 2 parts of azobiscyanovaleric acid initiator, 200 parts of tert-butyl methacrylate (tBMA), 100 parts of toluene, in nitrogen Free radical polymerization was carried out at 55°C under protection for 12 hours to obtain an anionic polymer side chain precursor polymer PtB...
Embodiment 3
[0056] It is a new cationic dye flocculant prepared by the following steps:
[0057] Step 1 Synthesis of polymer backbone polymethylolacrylamide (PHAM)
[0058] Take 1 part of ethyl 2-bromoisobutyrate initiator, 1 part of CuBr and 1 part of 4,4-linked 2-picoline (BPy), 100 parts of hydroxymethylacrylamide (HAM), 200 Parts of methanol were polymerized at 70°C for 8 hours under the protection of nitrogen to obtain polymethylolacrylamide (PHAM) with a degree of polymerization (DP) of 175;
[0059] Step 2 Synthesis of anionic polymer side chain precursor polymer PtBMA-COOH and functional polymer side chain precursor polymer PNVF-COOH
[0060] Synthesis of anionic polymer side chain precursor polymer PtBMA-COOH: take 1 part of azobiscyanovaleric acid initiator, 300 parts of tert-butyl methacrylate (tBMA), 200 parts of toluene, in nitrogen Free radical polymerization was carried out at 70°C under protection for 15 hours to obtain an anionic polymer side chain precursor polymer PtB...
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