Zinc oxide composite floating agent and preparation method and application thereof

A flotation agent, zinc oxide technology, applied in flotation, solid separation and other directions, can solve the problems of low recovery index, reduced collection efficiency, low zinc oxide ore grade, etc., to achieve recovery rate and grade improvement, simple process flow , the effect of saving pharmaceutical costs

Active Publication Date: 2018-04-27
KUNMING UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the grade of zinc oxide ore in our country is low, and the recovery index is not ideal. A large amount of zinc oxide ore is abandoned or piled up for a long time. The main difficulties in the recovery of zinc oxide ore are as follows. It hinders the contact between the agent and the mineral, thereby reducing the collection efficiency; second, the flotation conditions of different minerals in the ore are different, and the interference between the agents at each stage is serious; third, the surface of the zinc oxide mineral is often oxidized Iron pollution, loss of original flotation performance
[0004] At present, there are generally amine and xanthate collectors for zinc oxide flotation reagents, but the effect of simply using amine or xanthate collectors is not ideal, and the index is low...

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] Embodiment 1: The composition and mass percent of this zinc oxide composite flotation agent are octadecylamine acetate 30g, dodecylamine 15g, primary amine 15g, methyl isobutyl carbinol 30g, copper sulfate 7g, emulsifier 3g;

[0020] The specific operation of the preparation method is as follows: Weigh octadecylamine acetate, dodecylamine, primary amine and copper sulfate solids in a container, then add methyl isobutyl carbinol and emulsifier p-octylphenol polyoxyethylene ether to the container , and stirred evenly at 30°C to obtain a mixed solution, and then emulsified the mixed solution, the emulsification equipment is a high-speed shear emulsifier, the emulsification time is 30min, the emulsification temperature is 25°C, after the emulsification is completed, a zinc oxide composite emulsifier is obtained Choose medicine.

[0021] A zinc oxide ore in Guangxi was treated with the zinc oxide composite flotation agent prepared in this example. The gangue of this ore is m...

Embodiment 2

[0022] Embodiment 2: the composition and mass percent of this zinc oxide composite flotation agent are octadecylamine acetate 40g, dodecylamine 20g, primary amine 20g, methyl isobutyl carbinol 40g, copper sulfate 15g, emulsifier 5g;

[0023] The specific operation of its preparation method is as follows: weigh octadecylamine acetate, dodecylamine, primary amine and copper sulfate solid in a container, then add methyl isobutyl carbinol and emulsifier p-octylphenol polyoxyethylene to the container Ether, and stirred at 35°C to obtain a mixed solution, and then the mixed solution was emulsified, the equipment for emulsification was a high-speed shear emulsifier, the emulsification time was 25min, the emulsification temperature was 30°C, and the emulsification was completed to obtain a zinc oxide compound Flotation agent.

[0024] A certain zinc oxide ore in Sichuan was treated with the zinc oxide composite flotation agent prepared in this example. The gangue of this ore is mainly...

Embodiment 3

[0025] Embodiment 3: the composition and mass percent of this zinc oxide composite flotation agent are octadecylamine acetate 35g, dodecylamine 17g, primary amine 17g, methyl isobutyl carbinol 35g, copper sulfate 12g, emulsifier 4g;

[0026] The specific operation of its preparation method is as follows: weigh octadecylamine acetate, dodecylamine, primary amine and copper sulfate solid in a container, then add methyl isobutyl carbinol and emulsifier p-octylphenol polyoxyethylene to the container Ether, and stirred at 40°C to obtain a mixed solution, and then emulsified the mixed solution, the emulsification equipment is a high-speed shear emulsifier, the emulsification time is 10min, the emulsification temperature is 35°C, after the emulsification is completed, the zinc oxide composite Flotation agent.

[0027] Use the zinc oxide composite flotation agent prepared in this example to treat a zinc oxide ore in Henan. The gangue of this mine is mainly minerals such as dolomite an...

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PUM

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Abstract

The invention discloses a zinc oxide composite floating agent and a preparation method and application thereof. The floating agent is prepared from the following components of, by mass, 30-40 parts ofoctadecylamine acetate, 15-20 parts of dodecylamine, 15-20 parts of primary amine, 30-40 parts of methyl isobutyl carbinol, 7-15 parts of copper sulfate and 3-5 parts of an emulgator. The preparationmethod comprises the steps that the octadecylamine acetate, the dodecylamine, the primary amine and the solid copper sulfate are put into a container, then, the methyl isobutyl carbinol and the emulgator are added into the container, stirring is uniformly conducted at the temperature of 30-40 DEG C to obtain a mixed solution, the mixed solution is subjected to emulsification treatment, and the zinc oxide composite floating agent is obtained. When the composite floating agent is used for processing low-grade high-slime zinc oxide ore, raw ore does not need to be subjected to desliming treatment, and floating is directly conducted. The technical process is simple, and the zinc oxide composite floating agent is free of environment pollution and environmental friendly and has broad application prospects.

Description

technical field [0001] The invention relates to a composite flotation agent of zinc oxide, a preparation method and application thereof, and belongs to the technical field of ore dressing flotation agents. Background technique [0002] Zinc is mainly used in the galvanizing industry. A large part of the zinc produced in the world is used in the galvanizing industry, and the rest is mainly used in die-casting alloys, brass, and rolled products. At present, high-purity zinc-silver batteries have the advantages of small size and high energy, and are used as instrument power supplies for aircraft and spacecraft. The organic compounds of zinc diaryl zinc dithiophosphate and dialkyl zinc dithiophosphate can be used to prepare internal combustion engine oil to improve anti-wear, anti-oxidation and anti-corrosion performance; as a granular compound mainly containing zinc element Nitrogen fertilizer urea zinc, its main function is to make the roots of crops more and stronger, the st...

Claims

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Application Information

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IPC IPC(8): B03D1/018B03D101/02B03D103/04
CPCB03D1/018B03D2201/02B03D2203/04
Inventor 谢贤宋强童雄张胜东范培强康博文
Owner KUNMING UNIV OF SCI & TECH
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