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High pure white carbon black produced by utilizing industrial silicon byproduct silica fume and production method of high pure white carbon black

A silicon by-product micro-production method technology, applied in chemical instruments and methods, silicates, silicon compounds, etc., can solve the problems of poor content controllability, a large amount of acidic wastewater, poor application reliability, etc., and achieves low cost and high. Economic value, effect of stable quality

Inactive Publication Date: 2018-05-11
CHANGJI JISHENG NEW BUILDING MATERIALS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The advantage of this method is that high-purity water glass products of different moduli can be prepared according to needs, and high-purity white carbon black can be produced with relatively low cost; the disadvantage is that a large amount of acid waste water will be produced when pickling refined quartz sand, and there are serious problems. Environmental hazards
[0004] In addition, the existing precipitation technology generally uses sulfuric acid as the acidifying agent without further treatment for removing heavy metals. Heavy metals are generally detected in the high-purity white carbon black produced by it and the content controllability is poor. It is widely used in the food and pharmaceutical industries. Poor application reliability

Method used

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  • High pure white carbon black produced by utilizing industrial silicon byproduct silica fume and production method of high pure white carbon black
  • High pure white carbon black produced by utilizing industrial silicon byproduct silica fume and production method of high pure white carbon black

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Experimental program
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Effect test

Embodiment 1

[0061] First, the micro-silica powder is continuously preheated to 600°C, and then continuously added to a roaster at 950°C for dynamic roasting for 20 minutes to remove organic volatiles such as coal tar and sintered to obtain porous spherical, gray-white particles of roasted micro-silica powder; the roasted micro-silica powder Add 24.75Kg of silicon powder, 33.5Kg of liquid sodium hydroxide with a mass fraction of 30wt%, and 65Kg of water into a 200L reactor, mix and stir evenly, and directly feed superheated steam with a pressure of 3.0MPa and a temperature of 450°C to heat the mixture to 175°C And hold the pressure for 180 minutes to react to generate water glass mother liquor. When the temperature is lowered to 70°C by heat exchange, it is filtered by a filter press to obtain colorless, odorless, transparent high-purity water glass. After analysis and detection, SiO in high-purity water glass 2 The content is 17.10wt%, Na 2 The O content is 5.69wt%, and the modulus is 3....

Embodiment 2

[0065] First, the micro-silicon powder is continuously preheated to 650°C, and then continuously added to a roaster at 880°C for dynamic roasting for 28 minutes to remove organic volatiles such as coal tar and sintered to obtain porous spherical, gray-white particles of roasted micro-silicon powder; the roasted micro-silicon powder Add 41.3Kg of silicon powder, 48Kg of liquid sodium hydroxide with a mass fraction of 30%, and 110Kg of water into a 300L reactor, mix and stir evenly, and directly feed superheated steam with a pressure of 3.0MPa and a temperature of 450°C to heat the mixture to 190°C and React for 240 minutes to generate water glass mother liquor. After the mother liquor is cooled to 75°C by heat exchange, filter it with a filter press to obtain colorless, odorless and transparent high-purity water glass. After analysis and detection, SiO in high-purity water glass 2 The content is 19.15%wt, Na 2 The O content is 5.82wt%, and the modulus is 3.4; after analysis by...

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Abstract

The invention discloses high pure white carbon black produced by utilizing industrial silicon byproduct silica fume and a production method of the high pure white carbon black. The method comprises the concrete steps of roasting the silica fume to remove organic impurities such as coal tar, reacting with caustic soda liquid to obtain a water glass mother liquor, and filtering to obtain high-pure water glass; adding a sulfuric acid impurity removal agent into sulfuric acid, reacting for precipitating metal and heavy metal in the sulfuric acid, and filtering to obtain refined sulfuric acid; adding water into the high-pure water glass so as to prepare into an alkaline base solution, enabling the water glass and the sulfuric acid to parallelly flow into the base solution, and reacting to obtain suspension slurry; filtering, washing, pulping and drying the suspension slurry to obtain the high pure white carbon black. According to the high pure white carbon black produced by utilizing industrial silicon byproduct silica fume and the production method thereof provided by the invention, the high pure white carbon black is produced by adopting the industrial solid waste silica fume as a silicon source, so that the solid waste is recycled, and the process is simple and reasonable and low-cost, and has better economic and social benefits.

Description

technical field [0001] The invention belongs to the technical field of white carbon black production, and more specifically relates to a high-purity white carbon black produced by utilizing industrial silicon by-product micro-silica powder and a production method thereof. Background technique [0002] High-purity silica is generally used in special fields such as medicine, food, cosmetics, coatings, high-temperature vulcanized silicone rubber, etc., and has high utilization value. The production of high-purity white carbon black generally adopts the gas phase method, but the equipment investment of the gas phase method is high, and the production capacity of a single set of equipment is low. The raw material used is silicon tetrachloride or silane, and the production cost is too high and the acidity is strong. Some applications still needs further processing. [0003] In recent years, some enterprises have adopted the precipitation method to produce high-purity white carbon...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B33/193C01B33/32B09B3/00
CPCC01B33/193C01B33/32C01P2006/12C01P2006/80B09B3/40
Inventor 徐伟陈建材朱尔明
Owner CHANGJI JISHENG NEW BUILDING MATERIALS CO LTD
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