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Lithium ion battery electrolyte injection method

A lithium-ion battery and liquid injection technology, which is applied to battery pack parts, circuits, electrical components, etc., can solve problems such as affecting production efficiency, insufficient liquid absorption, slow liquid absorption, etc., to achieve high production liquid injection efficiency and improve infiltration. performance, and the effect of reducing production costs

Inactive Publication Date: 2018-05-18
SHANDONG GOLDENCELL ELECTRONICS TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to the increase in the energy density of lithium-ion batteries, the density of materials inside the battery increases, and the problems of slow liquid absorption and insufficient liquid absorption appear. Aprotic solvents have poor wettability to positive and negative active materials with high specific surface areas, resulting in poor battery materials. The contact resistance with the electrolyte increases, and the internal resistance of the battery increases. Insufficient liquid injection will seriously affect the electrical performance of the battery. The extension of liquid injection time and standing time will seriously affect production efficiency.

Method used

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Embodiment

[0035] The 18650-2200mAh-3.6V battery cells were tested for liquid injection, and the amount of solvent and solute injected into the electrolyte was designed to be the same. Compare the actual absorption and injection time of 10 cells.

[0036] Prepare the electrolyte solvent and high-concentration electrolyte. The electrolyte solvent is DMC (dimethyl carbonate), EMC (ethyl methyl carbonate), EC (ethylene carbonate), and the mass ratio is 1:1:1; high concentration electrolysis The liquid solute is 2.0mol / L LiPF6 (lithium hexafluorophosphate) and VC (vinylene carbonate) accounting for 4% of the total electrolyte mass, PS (propylene sulfite) accounting for 3% of the total electrolyte mass and accounting for the total electrolyte mass 2% FEC (fluoroethylene carbonate) is used as an additive.

[0037] First, store 10 battery cells, electrolytic solvent and high-concentration electrolyte with added electrolyte at a constant temperature of 45±2℃ for later use. First mark the 10 uninjecte...

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Abstract

The invention relates to a lithium ion battery electrolyte injection method, and belongs to the technical field of lithium ion batteries. According to the technical scheme, the lithium ion battery electrolyte injection method comprises the following steps of putting a lithium ion battery cell into a vacuum system to be vacuumized to the vacuum degree of minus 0.1 to minus 0.08 Mpa, then injectingan electrolyte solvent into a lithium ion battery dry cell which is kept vacuum to stand, after the vacuum state is broken, inflating inert gas to be pressurized, keeping positive pressure inside thecell at 0.5-1.0 Mpa, and after depressurizing, conducting vacuumizing again to the vacuum degree of minus 0.1 to minus 0.08 Mpa; finally, injecting electrolyte added with lithium salt and additive inthe cell, conducting vacuumizing to the vacuum degree of minus 0.08 to minus 0.06 Mpa, after the vacuum state is broken, inflating inertia gas to be pressurized and keeping positive pressure inside the cell at 0.5-1.0 Mpa; after depressurizing, checking whether the electrolyte is left on the upper surface of the battery cell or not to supplement the electrolyte. The lithium ion battery electrolyteinjection method improves the wettability of the battery and the electrolyte injection efficiency of the battery.

Description

Technical field [0001] The invention relates to a lithium ion battery liquid injection method, which belongs to the technical field of lithium ion batteries. Background technique [0002] Because lithium-ion batteries have the advantages of high energy density, long cycle life, safety and environmental protection, they are widely used in energy storage and power fields. With the expansion of the application range and the maturity of lithium-ion technology, people have put forward more ideas on the performance of lithium-ion batteries. High demand, especially electric vehicle batteries require higher energy density to increase the range of electric vehicles, and the demand for high energy density lithium-ion batteries is increasing. As the energy density of lithium-ion batteries increases, the internal material density of the battery increases, and the problems of slow liquid absorption and insufficient liquid absorption appear. Aprotic solvents have poor wettability for positive...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M2/36H01M50/60H01M50/609
CPCH01M50/60Y02E60/10
Inventor 张敬捧王勇李涛
Owner SHANDONG GOLDENCELL ELECTRONICS TECH