Automobile extrusion type SCR denitration catalyst with good low temperature activity and preparation method of automobile extrusion type SCR denitration catalyst
A SCR catalyst, extrusion technology, used in chemical instruments and methods, heterogeneous catalyst chemical elements, physical/chemical process catalysts, etc.
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Embodiment 1
[0021] (1) Preparation of the catalyst precursor, ammonium metavanadate and oxalic acid were dissolved in deionized water at a molar ratio of 1:1, stirred with a mechanical stirrer, and dissolved completely at room temperature to prepare a catalyst precursor solution, the concentration 20%;
[0022] (2) Weigh 100 parts of titanium tungsten powder, 3 parts of manganese dioxide, 2 parts of hydroxypropyl methylcellulose, 1 part of polyethylene oxide, 2 parts of oleic acid, and 1 part of glass fiber, and add them to the kneader, Knead for 10-50 minutes to mix the raw materials evenly, then slowly add 2 parts of ethylene glycol, 2 parts of lactic acid, 15 parts of catalyst precursor solution, 2 parts of ethanolamine, 1 part of silica sol, and 4 parts of ammonia water into the mud respectively, And add 16 parts of deionized water, knead for 20-120min, and stale for 10-30h after kneading;
[0023] (3) Put the above-mentioned stale mud material in a vacuum mud refining machine for 2-...
Embodiment 2
[0027] (1) Preparation of the catalyst precursor, ammonium metavanadate and oxalic acid were dissolved in deionized water at a molar ratio of 1:1, stirred with a mechanical stirrer, and dissolved completely at room temperature to prepare a catalyst precursor solution, the concentration 20%;
[0028] (2) Weigh 100 parts of titanium tungsten powder, 1 part of manganese dioxide, 1 part of cerium dioxide, 7 parts of hydroxypropyl methylcellulose, 5 parts of polyethylene oxide, 5 parts of oleic acid, and 7 parts of glass fiber, and add In the kneader, knead for 10-50 minutes to mix the raw materials evenly, then slowly add 10 parts of ethylene glycol, 5 parts of lactic acid, 35 parts of catalyst precursor solution, 6 parts of ethanolamine, 5 parts of silica sol, and 10 parts of ammonia water into the mud Add 1 part of deionized water to the material, knead for 20-120min, and stale for 10-30h after kneading;
[0029] (3) Put the above-mentioned stale mud material in a vacuum mud re...
Embodiment 3
[0033] (1) Preparation of the catalyst precursor, ammonium metavanadate and oxalic acid were dissolved in deionized water at a molar ratio of 1:1, stirred with a mechanical stirrer, and dissolved completely at room temperature to prepare a catalyst precursor solution, the concentration 20%;
[0034] (2) Weigh 100 parts of titanium tungsten powder, 1 part of manganese dioxide, 3 parts of hydroxypropyl methylcellulose, 2 parts of polyethylene oxide, 3 parts of oleic acid, and 2 parts of glass fiber, add them to a kneader, and knead for 10 -50min, mix the raw materials evenly, then slowly add 3 parts of ethylene glycol, 3 parts of lactic acid, 30 parts of catalyst precursor solution, 3 parts of ethanolamine, 2 parts of silica sol, and 5 parts of ammonia water into the mud respectively, and add 4 parts of ionized water, kneading for 20-120min, stale for 10-30h after kneading;
[0035] (3) Put the above-mentioned stale mud material in a vacuum mud refining machine for 2-4 times, a...
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