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Automobile extrusion type SCR denitration catalyst with good low temperature activity and preparation method of automobile extrusion type SCR denitration catalyst

A SCR catalyst, extrusion technology, used in chemical instruments and methods, heterogeneous catalyst chemical elements, physical/chemical process catalysts, etc.

Inactive Publication Date: 2018-06-08
凯龙蓝烽新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Therefore, extruded SCR catalysts for vehicles have higher requirements than those for stationary source extruded SCR catalysts. At present, domestic researchers are still in the initial stage of research on extruded SCR catalysts for vehicles.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] (1) Preparation of the catalyst precursor, ammonium metavanadate and oxalic acid were dissolved in deionized water at a molar ratio of 1:1, stirred with a mechanical stirrer, and dissolved completely at room temperature to prepare a catalyst precursor solution, the concentration 20%;

[0022] (2) Weigh 100 parts of titanium tungsten powder, 3 parts of manganese dioxide, 2 parts of hydroxypropyl methylcellulose, 1 part of polyethylene oxide, 2 parts of oleic acid, and 1 part of glass fiber, and add them to the kneader, Knead for 10-50 minutes to mix the raw materials evenly, then slowly add 2 parts of ethylene glycol, 2 parts of lactic acid, 15 parts of catalyst precursor solution, 2 parts of ethanolamine, 1 part of silica sol, and 4 parts of ammonia water into the mud respectively, And add 16 parts of deionized water, knead for 20-120min, and stale for 10-30h after kneading;

[0023] (3) Put the above-mentioned stale mud material in a vacuum mud refining machine for 2-...

Embodiment 2

[0027] (1) Preparation of the catalyst precursor, ammonium metavanadate and oxalic acid were dissolved in deionized water at a molar ratio of 1:1, stirred with a mechanical stirrer, and dissolved completely at room temperature to prepare a catalyst precursor solution, the concentration 20%;

[0028] (2) Weigh 100 parts of titanium tungsten powder, 1 part of manganese dioxide, 1 part of cerium dioxide, 7 parts of hydroxypropyl methylcellulose, 5 parts of polyethylene oxide, 5 parts of oleic acid, and 7 parts of glass fiber, and add In the kneader, knead for 10-50 minutes to mix the raw materials evenly, then slowly add 10 parts of ethylene glycol, 5 parts of lactic acid, 35 parts of catalyst precursor solution, 6 parts of ethanolamine, 5 parts of silica sol, and 10 parts of ammonia water into the mud Add 1 part of deionized water to the material, knead for 20-120min, and stale for 10-30h after kneading;

[0029] (3) Put the above-mentioned stale mud material in a vacuum mud re...

Embodiment 3

[0033] (1) Preparation of the catalyst precursor, ammonium metavanadate and oxalic acid were dissolved in deionized water at a molar ratio of 1:1, stirred with a mechanical stirrer, and dissolved completely at room temperature to prepare a catalyst precursor solution, the concentration 20%;

[0034] (2) Weigh 100 parts of titanium tungsten powder, 1 part of manganese dioxide, 3 parts of hydroxypropyl methylcellulose, 2 parts of polyethylene oxide, 3 parts of oleic acid, and 2 parts of glass fiber, add them to a kneader, and knead for 10 -50min, mix the raw materials evenly, then slowly add 3 parts of ethylene glycol, 3 parts of lactic acid, 30 parts of catalyst precursor solution, 3 parts of ethanolamine, 2 parts of silica sol, and 5 parts of ammonia water into the mud respectively, and add 4 parts of ionized water, kneading for 20-120min, stale for 10-30h after kneading;

[0035] (3) Put the above-mentioned stale mud material in a vacuum mud refining machine for 2-4 times, a...

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PUM

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Abstract

The invention provides an automobile extrusion type SCR denitration catalyst with good low temperature activity. The catalyst comprises the following components in parts by weight: 100 parts of titanium tungsten powder, 1-3 parts of active promotion aids, 2-7 parts of hydroxypropyl methyl cellulose, 1-5 parts of polyoxyethylene, 2-5 parts of oleic acid, 1-6 parts of a glass fiber, 2-10 parts of ethylene glycol, 2-5 parts of lactic acid, 15-35 parts of a catalyst precursor solution, 2-6 parts of cholamine, 1-10 parts of silica sol, 4-10 parts of ammonia water and 1-16 parts of deionized water.The automobile extrusion type SCR denitration catalyst provided by the invention has remarkable advantages, the extrusion type catalyst is an active material as a whole, has a relatively large effective mass and excellent durability, and is remarkable in low temperature activity effect due to addition of the active aids; meanwhile, to meet identical emission standards, the amount of materials of the extrusion type catalyst is smaller than that of a coating catalyst, so that the raw materials can be saved, and the production cost can be reduced.

Description

technical field [0001] The invention relates to a catalyst, in particular to an extruded SCR denitrification catalyst used for automobile tail gas treatment and a preparation method thereof. Background technique [0002] With the sustained and stable growth of the national economy, the development of my country's automobile industry is optimistic, and the sales of automobiles continue to grow every year. With the continuous increase of the total number of automobiles in the country, the problem of automobile exhaust pollution is becoming more and more serious. The nitrogen oxides contained in it and the nitrogen in the air The combination of water can form acid rain, and these nitrogen oxides can also react with hydrocarbons under light conditions to form photochemical smog, so the emission of nitrogen oxides is extremely harmful to the environment. [0003] In the 1950s, the Americans proposed the SCR denitrification technology and applied for a patent. In the 1970s, the Jap...

Claims

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Application Information

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IPC IPC(8): B01J23/34B01J23/30B01D53/94B01D53/56
CPCB01D53/9413B01D2251/2062B01J23/002B01J23/30B01J23/34B01J2523/00B01J2523/41B01J2523/47B01J2523/55B01J2523/69B01J2523/72B01J2523/3712Y02A50/20Y02T10/12
Inventor 许顺磊朱增赞孙敏赵磊冯峰刘军郭耘詹望成朱延江郭晓会
Owner 凯龙蓝烽新材料科技有限公司
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