A kind of chlorine-free low-melting-point thermoplastic gas generating agent and preparation method thereof

A gas generating agent, thermoplastic technology, used in non-explosive/non-thermal agent components, offensive equipment, explosives, etc., can solve the problems of acid mist or acid rain, ozone layer destruction, air pollution, etc., to achieve low price and good repeatability , the effect of gas cleaning

Active Publication Date: 2020-09-18
HUBEI INST OF AEROSPACE CHEMOTECHNOLOGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Ammonium perchlorate (AP) is widely used in the field of gas generating agents as a cost-effective oxidant due to its high oxygen balance, wide range of sources, and low price. Usually, the mass fraction in gas generating agents can be It reaches about 70%, but the gas generating agent containing AP will produce a large amount of HCl gas during the combustion process, which will cause air pollution and destroy the ozone layer when it is discharged into the atmosphere, and combine with moisture in the air to produce acid mist or acid rain. Serious damage to human beings and nature. With the gradual enhancement of people's awareness of environmental protection, chlorine-free gas generators have attracted more and more research interests of scientific researchers.

Method used

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Examples

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preparation example Construction

[0064] A preparation method of a chlorine-free low melting point thermoplastic gas generating agent, the steps of the method comprising:

[0065] (1) Prepare plasticizer: mix dioctyl sebacate and liquid polybutadiene, then carry out decompression heating and rotary distillation treatment to obtain plasticizer;

[0066] When the dioctyl sebacate and liquid polybutadiene are mixed, a water bath is used to control the temperature, the temperature is 20-30°C, and the two are mixed evenly by mechanical stirring, and the stirring speed is 20-100rpm , the stirring time is 30-60min;

[0067] The conditions for the decompression heating and rotary distillation treatment are as follows: the degree of vacuum is -0.1-0 MPa, the temperature is 70-90° C., the time is 30-60 minutes, and the rotation speed is 20-100 rpm.

[0068] (2) Oxidant, cooling agent, combustion regulator, plasticizer, auxiliary agent are weighed according to said ratio;

[0069] (3) Put the adhesive into a vertical mix...

Embodiment 1

[0080] (1) Preparation and composition of composite plasticizer and low melting point thermoplastic gas generating agent

[0081] Preparation of composite plasticizer: weigh according to the mass ratio of dioctyl sebacate: liquid polybutadiene (number average molecular weight 900~1100)=1:0.7, put it into a container, put the container into a water bath, and carry out Mechanical stirring, water bath temperature 25°C, rotating speed 40rpm, stirring time 40min, seal the mixed plasticizer in a rotary evaporator, use a vacuum pump to reduce the pressure of the rotary evaporator to -0.03MPa, heat the temperature to 75°C, and evaporate The rotational speed was 60 rpm, and the rotary steaming time was 35 minutes to obtain composite plasticizer A.

[0082] Preparation of low-melting thermoplastic gas generating agent: Weigh the oxidant, cooling agent, combustion regulator, adhesive, plasticizer A, and auxiliary agent according to the stated ratio; put the adhesive into a vertical mixer...

Embodiment 2

[0087] (1) Preparation and composition of composite plasticizer and low melting point thermoplastic gas generating agent

[0088] Preparation of composite plasticizer: weigh according to mass ratio dioctyl sebacate: liquid polybutadiene (number-average molecular weight 1400~1700)=0.9:1, put it into a container, put the container into a water bath, and carry out Mechanical stirring, water bath temperature 28°C, rotating speed 65rpm, stirring time 40min, seal the mixed plasticizer in a rotary evaporator, use a vacuum pump to reduce the pressure of the rotary evaporator to -0.05MPa, heat the temperature to 85°C, and evaporate The rotational speed was 60 rpm, and the rotary steaming time was 35 minutes to obtain composite plasticizer B.

[0089] The preparation of the low melting point thermoplastic gas generating agent is the same as in Example 1.

[0090] Composition (mass percentage) of low melting point thermoplastic gas generating agent: modified ammonium nitrate (72%); Dihy...

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Abstract

The invention relates to a chloride-free low-melting point thermoplastic fuel gas generator and a preparation method thereof, and belongs to the technical field of composite solid propellants. The chloride-free low-melting point thermoplastic gas generator is prepared from the following components in percentage by mass: 60 to 80 percent of an oxidant, 1 to 20 percent of a cooling agent, 1 to 3 percent of a combustion regulator, 5 to 10 percent of a low-melting point thermoplastic adhesive, 1 to 5 percent of an assistant and 1 to 10 percent of a plasticizing agent. The chloride-free low-meltingpoint thermoplastic fuel gas generator prepared by the invention contains no metal powder and has lower combustion temperature and clear gas, and the defect of atmospheric pollution caused by HCl generated in a combustion product due to the use of ammonium perchlorate in an existing gas generator is overcome; through the chloride-free low-melting point thermoplastic gas generator, melt mixing ata lower temperature (smaller than 95 DEG C) can be realized, the preparation safety of a thermoplastic propellant is greatly increased, continuity of production and repeated processing of waste products can be realized, and the production cost is reduced.

Description

technical field [0001] The invention relates to a chlorine-free low-melting thermoplastic gas generator and a preparation method thereof. The gas generator can be applied to gas generators and other gas generators, and belongs to the technical field of composite solid propellants. Background technique [0002] Ammonium perchlorate (AP) has the advantages of high oxygen balance, wide range of sources and low price. As a cost-effective oxidant, it is widely used in the field of gas generating agents. Usually, the mass fraction in gas generating agents can be It reaches about 70%, but the gas generating agent containing AP will produce a large amount of HCl gas during the combustion process, which will cause air pollution and destroy the ozone layer when it is discharged into the atmosphere, and combine with moisture in the air to produce acid mist or acid rain. It will cause serious damage to human beings and nature. With the gradual enhancement of people's awareness of enviro...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C06B31/28C06B23/00
CPCC06B23/009C06B31/28
Inventor 刘轩乔应克白文李志勇陈怡代志龙鲁国林
Owner HUBEI INST OF AEROSPACE CHEMOTECHNOLOGY
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