Modified steel slag as well as preparation method and application thereof
A steel slag and modification technology, applied in the field of environmental treatment, can solve the problems of rising, increase the difficulty of operation and treatment cost, and achieve the effects of low preparation cost, promoting Fenton-like reaction, and improving treatment efficiency and treatment effect.
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Embodiment 1
[0040] A modified steel slag is prepared by taking steel slag as a raw material and modifying it with a salicylic acid solution and a cobalt chloride solution, and specifically includes the following steps:
[0041] (1) Get 50g of salicylic acid and dissolve in 1L of methanol / acetone composite solvent (the volume ratio of methanol and acetone in the composite solvent is 1:1) to obtain a salicylic acid solution.
[0042] (2) Take 150g of steel slag (the steel slag is converter steel slag, purchased from a mineral product processing plant in Lingshou County, Hebei Province, and dry the metallurgical slag (ie converter steel slag) and break it into particles with a diameter of about 0.05mm, wherein the steel slag is mainly The composition is 46.95wt% CaO, 10.63wt% SiO 2 , 9.65wt% Fe 2 o 3 , 13.45wt% FeO, 4.86wt% MgO, 3.64wt% Al 2 o 3 , 1.85wt% P 2 o 5 , coded as SCS) and 1L of the salicylic acid solution in step (1) were mixed and shaken for 2h, filtered, washed with water,...
Embodiment 2
[0063] An application of modified steel slag in the treatment of antibiotic wastewater, specifically utilizing modified steel slag to remove sulfamethazine in water, comprising the following steps:
[0064] Get 5 parts of sulfamethazine solutions with a volume of 1L and a concentration of 50mg / L, add 0.1g, 0.2g, 0.5g, 0.7g, 1.0g of the modified steel slag prepared in Example 1, and then add 20mL each , a concentration of 30% (w / w) H 2 o 2 After mixing the solution evenly, adjust the initial pH value of the obtained mixed solution to 7 to carry out a Fenton-like reaction to complete the degradation treatment of sulfamethazine.
[0065] Fenton-like reaction is carried out 0.5h, 1h, 1.5h, 2h, 3h (and 4h after sampling from reaction system respectively, utilizes the content of sulfamethazine in the detection solution of high performance liquid chromatography, the results are shown in Figure 4 . Figure 4 It is the effect diagram of the removal of sulfamethazine in wastewater b...
Embodiment 3
[0067] An application of modified steel slag in the treatment of antibiotic wastewater, specifically utilizing modified steel slag to remove sulfamethazine in water, comprising the following steps:
[0068] Get 5 parts of volume and be 1L, concentration is the sulfamethazine solution of 50mg / L, respectively add the modified steel slag prepared in the embodiment 1 of 0.7g, then each add 40mL, concentration is 30% (w / w) H 2 o 2 After mixing the solution evenly, adjust the initial pH values of the obtained mixed solution to 5, 6, 7, 8, and 9 respectively to perform a Fenton-like reaction to complete the degradation treatment of sulfamethazine.
[0069] After the Fenton-like reaction was carried out for 0.5h, 1h, 1.5h, 2h, 3h and 4h, samples were taken from the reaction system, and the content of sulfamethazine in the solution was detected by high performance liquid chromatography. The results are shown in Figure 5 . Figure 5 It is a graph showing the effect of modified stee...
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