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Modified steel slag as well as preparation method and application thereof

A steel slag and modification technology, applied in the field of environmental treatment, can solve the problems of rising, increase the difficulty of operation and treatment cost, and achieve the effects of low preparation cost, promoting Fenton-like reaction, and improving treatment efficiency and treatment effect.

Active Publication Date: 2018-06-22
HUNAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Since the steel slag contains a relatively high content of iron, this can provide iron ions for the Fenton-like reaction, but because the steel slag also contains a large amount of alkaline components such as CaO, it will be hydrolyzed in the solution and cause the pH of the solution to rise sharply. In order to ensure the Fenton-like reaction The continuous progress of the reaction requires the continuous addition of acid solution to control the pH of the reaction system, which increases the difficulty of operation and processing costs

Method used

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  • Modified steel slag as well as preparation method and application thereof
  • Modified steel slag as well as preparation method and application thereof
  • Modified steel slag as well as preparation method and application thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0040] A modified steel slag is prepared by taking steel slag as a raw material and modifying it with a salicylic acid solution and a cobalt chloride solution, and specifically includes the following steps:

[0041] (1) Get 50g of salicylic acid and dissolve in 1L of methanol / acetone composite solvent (the volume ratio of methanol and acetone in the composite solvent is 1:1) to obtain a salicylic acid solution.

[0042] (2) Take 150g of steel slag (the steel slag is converter steel slag, purchased from a mineral product processing plant in Lingshou County, Hebei Province, and dry the metallurgical slag (ie converter steel slag) and break it into particles with a diameter of about 0.05mm, wherein the steel slag is mainly The composition is 46.95wt% CaO, 10.63wt% SiO 2 , 9.65wt% Fe 2 o 3 , 13.45wt% FeO, 4.86wt% MgO, 3.64wt% Al 2 o 3 , 1.85wt% P 2 o 5 , coded as SCS) and 1L of the salicylic acid solution in step (1) were mixed and shaken for 2h, filtered, washed with water,...

Embodiment 2

[0063] An application of modified steel slag in the treatment of antibiotic wastewater, specifically utilizing modified steel slag to remove sulfamethazine in water, comprising the following steps:

[0064] Get 5 parts of sulfamethazine solutions with a volume of 1L and a concentration of 50mg / L, add 0.1g, 0.2g, 0.5g, 0.7g, 1.0g of the modified steel slag prepared in Example 1, and then add 20mL each , a concentration of 30% (w / w) H 2 o 2 After mixing the solution evenly, adjust the initial pH value of the obtained mixed solution to 7 to carry out a Fenton-like reaction to complete the degradation treatment of sulfamethazine.

[0065] Fenton-like reaction is carried out 0.5h, 1h, 1.5h, 2h, 3h (and 4h after sampling from reaction system respectively, utilizes the content of sulfamethazine in the detection solution of high performance liquid chromatography, the results are shown in Figure 4 . Figure 4 It is the effect diagram of the removal of sulfamethazine in wastewater b...

Embodiment 3

[0067] An application of modified steel slag in the treatment of antibiotic wastewater, specifically utilizing modified steel slag to remove sulfamethazine in water, comprising the following steps:

[0068] Get 5 parts of volume and be 1L, concentration is the sulfamethazine solution of 50mg / L, respectively add the modified steel slag prepared in the embodiment 1 of 0.7g, then each add 40mL, concentration is 30% (w / w) H 2 o 2 After mixing the solution evenly, adjust the initial pH values ​​of the obtained mixed solution to 5, 6, 7, 8, and 9 respectively to perform a Fenton-like reaction to complete the degradation treatment of sulfamethazine.

[0069] After the Fenton-like reaction was carried out for 0.5h, 1h, 1.5h, 2h, 3h and 4h, samples were taken from the reaction system, and the content of sulfamethazine in the solution was detected by high performance liquid chromatography. The results are shown in Figure 5 . Figure 5 It is a graph showing the effect of modified stee...

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Abstract

The invention discloses modified steel slag as well as a preparation method and application thereof. The modified steel slag is prepared by modifying steel slag through a salicylic acid solution and acobalt ion solution. The modified steel slag disclosed by the invention has the advantages of large specific surface area, good catalytic performance, low preparation cost, environment protection andcapability of preventing a water body from being acidified and the like; the preparation method of the modified steel slag has the advantages of wide raw material source, low production cost, simplepreparation process, convenience for operation, low energy consumption, no production of toxic and harmful substances, environment friendliness and the like. The modified steel slag can be used as a catalyst of Fenton-like reaction and can be used for treating antibiotic wastewater; wastes of metallurgical slag can be reutilized and antibiotics can be effectively degraded; meanwhile, the modifiedsteel slag also has the advantages of convenience for operation, relatively low cost, high treatment efficiency, good treatment effect, small dosage of added chemical agents, environment protection and the like; an acidifying effect of traditional Fenton oxidization reaction on the water body can be reduced, the water body is prevented from being acidified and the modified steel slag has a very good application prospect.

Description

technical field [0001] The invention belongs to the field of environmental treatment, and relates to a modified steel slag and its preparation method and application. Background technique [0002] Antibiotics are a class of secondary metabolites with anti-pathogen or other activities produced by microorganisms (including bacteria, fungi, actinomycetes) or higher animals and plants in the course of life, which can interfere with the developmental functions of other living cells chemicals. In the 1930s, it was discovered that sulfonamides were effective in the treatment of hemolytic streptococcal infections and were used as clinical drugs. In 1939, the scientist Gerhard Domagk won the Nobel Prize in Medicine for his discovery of the inhibitory effect of Prontosil on Streptococcus. By 1945, more than 5,400 sulfonamides had been synthesized, among which more than 20 were commonly used in clinical practice, such as sulfacetamide, sulfapyridine, sulfathiazole, and sulfamidine. ...

Claims

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Application Information

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IPC IPC(8): B01J27/185B01J35/10B01J37/06C02F1/72
CPCC02F1/722C02F1/725B01J23/002B01J27/1853B01J37/06C02F2305/026B01J35/613B01J35/615
Inventor 程敏曾光明黄丹莲赖萃许飘万佳龚小敏秦蕾薛文静王荣忠刘希贵刘少恒
Owner HUNAN UNIV
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