Dental selective laser sintering 3D printing wax powder and preparation method thereof

A laser sintering and 3D printing technology, applied in the direction of additive processing, etc., can solve the problems of insufficient data collection accuracy and rapid prototyping processing accuracy, less wax powder, poor molding accuracy, etc., to meet the needs of laser sintering, low kinematic viscosity, good formability

Inactive Publication Date: 2018-06-22
广州市德隆化工贸易有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Since the 1980s, rapid prototyping (RP) and reverse engineering (RE) as the core of rapid prototyping and manufacturing technology is the product design and manufacturing virtual 3-dimensional, fast, this technology provides the development of prosthodontics A new way, but because of the insufficient accuracy of data collection and rapid prototyping, it is mostly used in the repair of maxillofacial defects in the field of oral restoration
Patent CN104693579A discloses a method for preparing a composite modified wax powder for laser sintering 3D printing by adding stearic acid, white carbon black, carbon black, and chopped carbon fiber to the wax powder base material ratio of double particle size gradation, Patent CN1326828A discloses a low melting point powder prepared from polyethylene for laser sintering rapid prototyping of fine casting wax models, which is used in the field of precision casting, but this type of wax powder is not suitable for use in the field of dental casting wax
[0006] Traditional dental wax has high heat sensitivity, poor molding precision, and very difficult powder preparation. It cannot be made into wax powder with a particle size that meets the sintering requirements, and is not suitable for laser sintering molding.
[0007] Laser sintering molding has unique advantages and good prospects in the field of dental medicine, but currently there are very few laser sintering molding wax powders on the market that meet the needs of the dental field and applications, so that the superiority of SLS cannot be fully displayed in this field

Method used

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  • Dental selective laser sintering 3D printing wax powder and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0042] A dental selective laser sintering 3D printing wax powder, prepared by the following method: 682# microcrystalline wax (42%), 58# fully refined wax (remainder, about 14.5%), PE wax (4%) , S wax (15%), Carabba wax (21%), color paste (3‰), put it into a 100°C reaction kettle and heat and stir. After all the substances melt, continue to heat and stir for 30min, release, cool, and then use powder Machine pulverization obtains mixed wax A. Put the mixed wax A in a low-temperature cooling device to cool to -190 ° C, mechanically pulverize it into powder, then stir in a mixer, and gradually spray sodium dodecylbenzenesulfonate (5%, the surfactant is first dissolved in an organic solvent ), through a 300-mesh sieve after vacuum drying to obtain the basic wax powder B.

[0043] Put the basic wax powder B in the double-cone mixer, and then add octadecyldimethyl quaternary ammonium nitrate (5‰), ultraviolet absorber uv-9 (5‰), antioxidant 1010 (3‰) ‰), mixed evenly and passed th...

Embodiment 2

[0046]A dental selective laser sintering 3D printing wax powder, prepared by the following method: 70# microcrystalline wax (57%), EVA (remainder, about 5%), ozokerite (18.5%), refined montan wax (19.5%) Color paste (3‰), put it into a 100°C reaction kettle and heat and stir. After all the substances are melted, continue to heat and stir for 30 minutes, release, cool, and then pulverize with a powder machine to obtain mixed wax A. Put the mixed wax A in a low-temperature cooling device to cool to -190°C, mechanically crush it into powder, then stir in a mixer, and gradually spray sodium dodecylbenzenesulfonate (6.5‰, the surfactant is first dissolved in an organic solvent ), through a 300-mesh sieve after vacuum drying to obtain the basic wax powder B.

[0047] Put the basic wax powder B in the double-cone mixer, and then add octadecyldimethyl quaternary ammonium nitrate (5‰), ultraviolet absorber uv-9 (4.5‰), antioxidant 1010 (4.5‰) ‰), mixed evenly and passed through a 300-...

Embodiment 3

[0050] A dental selective laser sintering 3D printing wax powder, prepared by the following method: 58# fully refined wax (14.5%), 682# microcrystalline wax balance (about 31.5%), EVA (4%), beeswax (10.5%), ozokerite (10%), carabba wax (29.5%), color paste (3 ‰), put it into a 100 ℃ reaction kettle and heat and stir, continue to heat and stir for 30min after all the substances are melted, release, cool, Then pulverize with a powder machine to obtain mixed wax A. Put the mixed wax A in a low-temperature cooling device to cool to -190°C, mechanically crush it into powder, then stir in a mixer, and gradually spray sodium dodecylbenzenesulfonate (8‰, the surfactant is first dissolved in an organic solvent ), through a 300-mesh sieve after vacuum drying to obtain the basic wax powder B.

[0051] Put the basic wax powder B in the double-cone mixer, and then add octadecyldimethyl quaternary ammonium nitrate (5‰), ultraviolet absorber uv-9 (5‰), antioxidant 1010 (3‰) ‰), mixed evenl...

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Abstract

The invention belongs to the technical field of special waxes and 3D printing materials, and discloses a dental selective laser sintering 3D printing wax powder and a preparation method thereof. The wax powder provided by the invention consists of basic wax powder and additives, wherein the basic wax powder comprises the following components in percentage by mass: 50-70% of petroleum wax, 0-15% ofanimal wax, 10-20% of mineral wax or mineral derived wax, 20-30% of plant wax, 0-5% of a flexibilizer, 0-10% of PE wax, 0-1% of color paste and 0-1% of a surfactant; or 40-60% of petroleum wax, 15-30% of animal wax, 0-10% of mineral wax or mineral derived wax, 0-20% of plant wax, 5-10% of a flexibilizer, 10-20% of PE wax, 0-1% of color paste and 0-1% of a surfactant. The dental selective laser sintering 3D printing wax powder provided by the invention has the advantages of good sinterability, good formability, moderate hardness, low kinematic viscosity, strong plasticity and obvious improvement in physical properties.

Description

technical field [0001] The invention belongs to the technical field of special waxes and 3D printing materials, in particular to a dental selective laser sintering 3D printing wax powder and a preparation method thereof. Background technique [0002] Since the 1980s, rapid prototyping (RP) and reverse engineering (RE) as the core of rapid prototyping and manufacturing technology is the product design and manufacturing virtual 3-dimensional, fast, this technology provides the development of prosthodontics However, due to the insufficient accuracy of data collection and rapid prototyping, it is mostly used in the repair of maxillofacial defects in the field of oral restoration. 3D is a kind of fast printing technology, but its unique technology is superior to other fast printing methods, and has been promoted and innovated by various industries. 3D printing technology is one of the core technologies for the transformation and upgrading of the manufacturing industry. The appl...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L91/06C08L23/06C08L23/08C08K5/00C08K5/42C08K5/19C08K5/134B33Y70/00
CPCB33Y70/00C08K2201/017C08L91/06C08L2201/04C08L2205/025C08L2205/035C08L23/06C08K5/00C08K5/42C08K5/19C08K5/1345C08L23/0853
Inventor 范智勇汤从海范德贤
Owner 广州市德隆化工贸易有限公司
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