Deodorant and preparation method thereof

A deodorant and metal technology, which is applied in the field of deodorant and its preparation, can solve the problems of poor removal effect of mercaptan or thioether compound, loss of deodorant effect of deodorant, high cost of manufacture and use, Achieve low production cost, low regeneration difficulty, and good broad-spectrum effects

Active Publication Date: 2018-06-29
INST OF CHEM ENG GUANGDONG ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Although the above two deodorants can achieve a certain deodorizing effect, they cannot be regenerated, and the cost of manufacture and use is high.
[0005] CN 101385864A discloses a deodorant obtained by adhering copper compounds and manganese compounds on the surface of activated carbon. The deodorant can absorb and remove methyl mercaptan, acetaldehyde, ammonia, acetic acid, etc., but due to the deodorization The activated carbon used in the deodorant is microporous carbon, and the pores on the microporous carbon are easily blocked due to the adsorption of malodorous gases, which eventually causes the deodorant to lose its deodorizing effect
[0006] The current desulfurization and deodorants are mainly for H 2 S has a good removal effect, but the removal effect on mercaptan or thioether compounds is not good
In addition, the oxidation products of sulfur-containing compounds will be deposited on the deodorant, which will easily cause the deodorant to lose its deodorizing effect and make it difficult to regenerate the deodorant

Method used

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  • Deodorant and preparation method thereof
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preparation example Construction

[0024] The preparation method of the above-mentioned deodorant comprises the following steps: dispersing the nitrate or acetate corresponding to the metal oxide in a solvent as a precursor, adding a carrier, ultrasonically dispersing, filtering, drying the solid product, and then placing Under protective atmosphere, bake at 300-600°C for 3-5 hours.

[0025] Preferably, the drying is carried out at 100-120° C., and the drying time is 10-15 hours.

Embodiment 1

[0028] A deodorant, its preparation method is as follows: prepare 0.35wt% copper nitrate solution, then add mesoporous carbon (calculate the addition of mesoporous carbon with the load of copper nitrate as 5wt%), ultrasonically disperse evenly, leave standstill After 12 hours, it was filtered, and the filter residue was dried at 110°C for 12 hours, then placed in a nitrogen atmosphere, and calcined at 500°C for 4 hours to obtain deodorant 1.

Embodiment 2

[0030] A kind of deodorant, its preparation method is as follows: prepare the cobalt nitrate solution of 0.1mol / L, then add macroporous carbon (calculate the addition amount of macroporous carbon with the loading capacity of copper nitrate as 8wt%), ultrasonic dispersion is even, adjust The pH value of the reaction liquid reached 11, and was centrifuged after standing for 12 hours. The solid product was dried at 120° C. for 10 hours, and then placed in a nitrogen atmosphere and roasted at 400° C. for 5 hours to obtain deodorant 2.

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Abstract

The invention discloses a deodorant and a preparation method thereof. The deodorant is prepared from a carrier and a metal oxide which is limited into a carrier porous channel; the carrier is at leastone of mesoporous carbon, macroporous carbon and hierarchical porous carbon; and the metal oxide is at least one of tungsten trioxide, vanadic oxide, molybdenum trioxide, niobium pentaoxide, copper oxide, cobaltosic oxide, manganese dioxide, iron oxide, cerium dioxide and dilanthanum trioxide. The preparation method comprises the following steps of dispersing nitrate or acetate, corresponding tothe metal oxide, in a solvent as a precursor, then adding the carrier, performing ultrasonic dispersion and filtering, drying a solid product, putting the solid product at a protective atmosphere, andperforming roasting for 3-5h at the temperature of 300-600 DEG C. The deodorant provided by the invention has higher removal activity to sulfur-containing compounds such as H2S, mercaptan and sulfurether, has better broad-spectrum property and is reproducible.

Description

technical field [0001] The invention relates to a deodorant and a preparation method thereof. Background technique [0002] Sewage treatment plants, garbage dumps, farms and other places generally have odor pollution problems, which have a great impact on the surrounding ecological environment, and will also cause serious harm to people's health, causing people to experience olfactory disorders, nausea, headaches, cancer, and distortion and other symptoms. With the increasing requirements of environmental protection, the problem of odor pollution has been widely concerned and highly valued by people. The research on deodorization is of great significance and has broad application prospects. [0003] The composition of the odor is complex and difficult to control. h 2 Sulfur-containing compounds such as S, mercaptan, and sulfide are the main components of odor, so desulfurization and deodorization are the focus of odor pollution control. Desulfurization and deodorization ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D53/86B01D53/48
CPCB01D53/8603B01D2257/304B01D2257/306
Inventor 张俊杰蒋婷婷王曦麦裕良
Owner INST OF CHEM ENG GUANGDONG ACAD OF SCI
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