Preparation method of low-temperature-resistant car urea solution

A vehicle urea, low temperature resistance technology, applied in the field of chemical technology, can solve the problems of limited selection range of modifiers, limited use, low crystallization point of urea solution, etc., to achieve large cost advantages, improve low temperature resistance, and reduce environmental pollution Effect

Inactive Publication Date: 2018-07-10
薛向东
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Problems solved by technology

The urea solution with this concentration has the lowest crystallization point, and it will crystallize when it is lower than -11°C. In actual use, it will be completely frozen at -20°C, which restricts its use in cold winter weather in the north, especially in the northeast.
Adding a modifier to reduce the freezing point of the urea solution for vehicles is the most convenient and low-cost method, but du

Method used

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  • Preparation method of low-temperature-resistant car urea solution

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Embodiment Construction

[0022] Peel off the outer skin of the pomelo peel and collect the white floc, wash it with deionized water for 2 to 3 times, air-dry it naturally, put it into a pulverizer and grind it, pass through a 20-mesh sieve to get the pretreated pomelo peel, take 300-500g for pretreatment Put the pomelo peel into the steam explosion tank, and feed 1.5-2.5MPa water vapor with a temperature of 210-240°C into the steam explosion tank, keep the pressure for 3-4 minutes, open the valve of the steam explosion tank instantly, release the pressure to normal pressure, and then filter To obtain the filter residue, wash the filter residue with deionized water at a temperature of 80-85°C for 2-3 times, place it in a drying oven, and dry it at 60-80°C until it reaches a constant weight, and then obtain steam explosion-treated pomelo peel, and take 100-120g of soybean protein Powder, 25-30g ammonium alginate, 200-300g steam explosion treated pomelo peel, add 5-6L deionized water, stir at 300-400r / min...

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Abstract

The invention relates to a preparation method of low-temperature-resistant car urea solution, and belongs to the technical field of a chemical process. High-temperature and high-pressure steam is used; through diffusion effect, condensed water in fiber cells fast evaporates and expands; the lignin coating effect and a cellulose crystallization structure are broken; the material porosity is obviously increased; then, the covalent bond is used for crosslinking free amino acid or amino groups of the soybean protein molecules with ammonium alginate to form a reticular space structure; under the basic condition, the soybean protein molecules swell so that the molecule structures loosen; peptide chains extend; hydrophobic groups are sufficiently exposed; through heating denaturation treatment, the materials are decomposed into pores of the materials; a viscous porous structure formed by multilayer micro fiber can be formed; the larger specific surface area and a great number of active sitescapable of being combined with metal ions are realized; the urea solution is purified; the prepared pure urea solution is mixed with ammonium acetate and ammonium chloride capable of lowering the water solution freezing point; the low-temperature-resistant performance of the urea solution is improved.

Description

technical field [0001] The invention relates to a preparation method of a low-temperature resistant vehicle urea solution, which belongs to the technical field of chemical technology. Background technique [0002] The current global energy shortage, climate warming, and environmental protection are becoming increasingly severe. In this context, the hazards of nitrogen oxides and particulate matter emitted by diesel vehicles to human health and the atmospheric environment have attracted great attention. According to reports, countries all over the world are committed to reducing these two emissions research, including improving fuel quality, implementing in-machine purification technology and out-of-machine purification technology for after-treatment of exhaust gas. As far as our country is concerned, the implementation of the national "IV" emission standard means that the emission of vehicle exhaust must adopt more advanced technology. A large number of experimental studie...

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Application Information

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IPC IPC(8): B01D53/94B01D53/56F01N3/20B01J20/24B01J20/30
CPCB01D53/9418B01D2251/2067B01J20/24B01J2220/485B01J2220/4887F01N3/2066Y02A50/20
Inventor 薛向东王文新史玉玲
Owner 薛向东
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