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A method for resource utilization of high-concentration organic wastewater

An organic wastewater, high-concentration technology, applied in chemical instruments and methods, water pollutants, natural water treatment, etc., can solve the problems of no zero discharge, low system water recovery rate, poor treatment effect, etc. The effect of reducing, difficult to biochemical degradation, fast and efficient treatment

Active Publication Date: 2021-03-26
INST OF PROCESS ENG CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, the existing treatment process usually has some technical defects: first, the recovery rate of wastewater is low, and the existing technology can achieve standard discharge, but it has not achieved zero discharge in the true sense, and the untreated part is directly treated as waste. The water recovery rate of the system is low, and it also causes secondary pollution; secondly, the existing combined treatment process is complicated, the process chain is long, and there are still some problems in the connection part of the process, resulting in high treatment cost, long treatment cycle and poor treatment effect And other issues

Method used

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  • A method for resource utilization of high-concentration organic wastewater
  • A method for resource utilization of high-concentration organic wastewater
  • A method for resource utilization of high-concentration organic wastewater

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Embodiment 1

[0073] This embodiment provides a system for resource utilization of high-concentration organic wastewater. The system includes an evaporation unit, a wet catalytic oxidation treatment unit, a steam-water separation unit, and a brine separation unit connected in sequence.

[0074] The evaporation unit includes a multi-effect evaporator and a steam boiler connected in sequence.

[0075] The liquid outlet of the steam-water separation unit is connected with the feed port of the brine separation unit, and the gas outlet of the steam-water separation unit is connected with the feed port of the evaporation unit.

[0076] The system also includes a post-processing unit, the feed port of the post-processing unit is connected with the liquid outlet of the steam-water separation unit, and the discharge port of the post-processing unit is connected with the feed port of the brine separation unit.

[0077] The post-treatment unit includes a biological treatment unit and / or an adsorption ...

Embodiment 2

[0084] This embodiment provides a system for resource utilization of high-concentration organic wastewater. The system refers to Embodiment 1, the only difference is that the evaporation unit includes a steam boiler.

[0085] Utilize the method for above-mentioned system to process organic waste water, comprise the steps:

[0086] (1) The organic wastewater to be treated is entered into a steam boiler for evaporation treatment. The treatment temperature is 100-250° C., and the treatment time is 2-8 hours to obtain steam and residual liquid I. The steam pressure is 3-5 MPa, which is used in the production unit ;

[0087] (2) The residual liquid I obtained in step (1) is subjected to wet catalytic oxidation treatment, the treatment temperature is 150-250° C., the pressure is 1-3 MPa, and the residence time is 30-50 minutes to obtain the treated product;

[0088] (3) Separating the treated product obtained in step (2) from steam to water to obtain gas and residual liquid II, the g...

Embodiment 3

[0091] Coal gasification wastewater has complex components and a large amount of water. Pollutants mainly include ammonia, carbon dioxide, hydrogen sulfide, unit phenols, polyphenols, and fatty acids; among them, the content of phenols is as high as 5,000-10,000 mg / L, and the COD is 20,000-50,000 mg / L.

[0092] This embodiment provides a method for resource utilization of coal gasification wastewater. The method is carried out according to the system in Embodiment 1, and its process flow chart is as follows figure 2 As shown, it specifically includes the following steps:

[0093] (1) Set the total amount to 1m 3 , the coal gasification wastewater with a COD content of 30,000-35,000mg / L is passed into a multi-effect evaporator and a steam boiler for evaporation treatment in sequence. The treatment temperatures are 100°C and 200°C respectively, the treatment time is 4h, and the generated steam pressure is 2MPa. Steam and residual liquid I, the steam is passed into the coal gas...

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Abstract

The invention provides a system and a method for recycling high-concentration organic wastewater. The system comprises an evaporation unit, a wet catalytic oxidation treatment unit, a steam-water separation unit and a salt-water separation unit which are connected in sequence. According to the system and the method, the evaporation unit and the wet catalytic oxidation treatment unit are effectively combined, so that the existing technological process of high-concentration organic wastewater treatment is greatly simplified, the treatment amount of wastewater is reduced, the treatment difficultyis reduced, the treatment cost of the wastewater can be remarkably reduced, and the reuse rate of the wastewater is increased; the technological process is simple, compact, efficient and low in operating cost, the applicable range is wide, popularization and application are convenient, and recycling and ultralow emission of the high-concentration organic wastewater are facilitated.

Description

technical field [0001] The invention belongs to the technical field of wastewater treatment, and relates to a treatment system and method for organic wastewater, in particular to a system and method for resource utilization of high-concentration organic wastewater. Background technique [0002] High-concentration organic wastewater refers to COD in water Cr More than 1000mg / L, even as high as tens of thousands to hundreds of thousands, and some wastewater has poor biodegradability and low BOD value, mainly from coal gasification to gas, coal direct liquefaction to oil, coal coking, pharmaceuticals, pesticides and Wastewater produced in the production process of fine chemical industry and other industries. The organic wastewater mainly contains a large amount of refractory organic matter, which has the characteristics of high COD, high toxicity and refractory biodegradation. The treatment and discharge of high-concentration organic wastewater directly affects the future dev...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F9/10C02F1/04C02F1/72C02F101/30C02F103/34C02F103/36
CPCC02F1/04C02F1/048C02F1/725C02F9/00C02F2101/30C02F2101/306C02F2103/34C02F2103/343C02F2103/365C02F2301/066C02F2301/08
Inventor 曹宏斌谢勇冰李玉平石艳春
Owner INST OF PROCESS ENG CHINESE ACAD OF SCI