A kind of phase change material liquid and the solid phase proppant formed by it

A phase change material, solvent technology, applied in drilling compositions, wellbore/well components, chemical instruments and methods, etc., can solve the problem of solid phase proppant (inadequate toughness of solid phase particles, affecting the conductivity of propped fractures) , the slow reaction speed of solid phase proppant, etc., to achieve the effect of shortening the reaction molding time, reducing construction risks and safety hazards, and improving toughness

Active Publication Date: 2020-09-08
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In 2010, Schlumberger proposed that the fracture conductivity of HIWAY high-speed channel flow is not affected by the permeability of proppant. Compared with conventional fracturing technology, this technology also needs to inject solid phase proppant into the formation, and the process implementation is complicated
Although this process solves some major problems in the injection of solid phase proppant in conventional hydraulic fracturing, it also has some defects: on the one hand, the toughness of the solid phase proppant (solid phase particles) obtained by phase transformation is insufficient, and it is easy to occur Broken, blocking the gaps between solid phase particles, affecting the conductivity of propped fractures
On the other hand, the reaction speed of phase change material liquid forming into solid phase proppant is slow, which requires a long construction operation time, and during this period, once the phase change material has not phase change before the fracture is closed, it has a certain pressure. capacity of the proppant, the phase change fracturing process will fail

Method used

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  • A kind of phase change material liquid and the solid phase proppant formed by it
  • A kind of phase change material liquid and the solid phase proppant formed by it
  • A kind of phase change material liquid and the solid phase proppant formed by it

Examples

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Embodiment 1

[0037] This embodiment provides a phase change material solution and a solid phase proppant with melamine substances as supramolecular building blocks.

[0038] Two kinds of phase change material liquid HPP 1 and HPP 2 The preparation process is as follows:

[0039] HPP 1 : first get xylene 50g, then add melamine 40g, dicyclopentadiene resin 30g, hydroxypropyl methylcellulose 0.5g, sodium lauryl sulfate 0.5g, phosphoric acid 0.5g, calcium chloride 0.5g, diperoxide Benzoyl 1g. All placed in a flask, stirred evenly at room temperature to complete the phase change material liquid HPP 1 preparation.

[0040] HPP 2 : First take 50g of xylene, then add 40g of 2,4-diamino-6-diallylamino-1,3,5-triazine, 30g of dicyclopentadiene resin, 0.5g of hydroxypropyl methylcellulose, ten Dialkyl sodium sulfate 0.5g, phosphoric acid 0.5g, calcium chloride 0.5g, dibenzoyl peroxide 1g. All placed in a flask, stirred evenly at room temperature to complete the phase change material liquid HPP...

Embodiment 2

[0048] This embodiment provides a phase change material solution containing a pore-forming agent and a solid-phase proppant.

[0049] Three kinds of phase change material liquid HPP 3 、HPP 4 、HPP 5 The preparation process is as follows:

[0050] HPP 3 : first get xylene 50g, then add propenyl substituted triazine 40g, dicyclopentadiene resin 30g, polyvinyl alcohol 0.7g, sodium dodecylsulfonate 0.3g, phosphoric acid 0.5g, calcium chloride 0.5g, pass Dibenzoyl oxide 1g, ammonium bicarbonate 5g. All placed in a flask, stirred evenly at room temperature to complete the underground phase change material liquid HPP 3 preparation.

[0051] HPP 4 : First get 50g of xylene, then add 40g of acryl-substituted melamine, 30g of dicyclopentadiene resin, 0.5g of hydroxypropyl methylcellulose, 0.5g of sodium dodecylsulfonate, 1g of sodium bicarbonate, dihydrogen peroxide Tert-butyl 1g, solid paraffin 5g. All placed in a flask, stirred evenly at room temperature to complete the underg...

Embodiment 3

[0066] This embodiment provides a phase change material solution and a solid phase proppant with melamine substances as supramolecular building blocks.

[0067] Two kinds of phase change material liquid HPP 1 and HPP 2 The preparation process is as follows:

[0068] HPP 6 : First take 45g of xylene, then add 12g of melamine, 60g of dicyclopentadiene resin, 0.5g of hydroxypropyl methylcellulose, 0.5g of sodium lauryl sulfate, 0.5g of phosphoric acid, 0.5g of calcium chloride, di Benzoyl 1g. All placed in a flask, stirred evenly at room temperature to complete the phase change material liquid HPP 6 preparation.

[0069] HPP 7 : First take 20g of xylene, then add 60g of melamine, 20g of dicyclopentadiene resin, 0.5g of hydroxypropyl methylcellulose, 0.5g of sodium lauryl sulfate, 0.5g of phosphoric acid, 0.5g of calcium chloride, diperoxide Benzoyl 1g. All placed in a flask, stirred evenly at room temperature to complete the phase change material liquid HPP 7 preparation...

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Abstract

The invention provides a phase change material liquid and a solid phase proppant formed therefrom. Wherein, in terms of mass percentage, the components for preparing the phase change material liquid include: supramolecular construction unit 10-60wt%, supramolecular functional unit 20-50wt%, dispersant 0.1-2wt%, inorganic structuring agent 0.1-1wt% %, initiator 0.1‑1wt%, and the rest are solvents; supramolecular building blocks include melamines and / or triazines; supramolecular functional units include dicyclopentadiene resins; dispersants include hydroxylated polysaccharides and surfactants. After the phase-change material liquid enters the reservoir, under the action of supramolecular chemistry and physics, it can form a solid-phase material to support fractures. Because there is no solid phase injection, it can effectively reduce the friction of the pipe string, reduce the requirements for construction equipment, surface pipelines, wellheads and construction pipe strings, effectively reduce construction costs, and reduce construction risks and safety hazards.

Description

technical field [0001] The invention belongs to the technical field of oil reservoir development, and in particular relates to a phase change material liquid and a solid phase proppant formed therefrom. Background technique [0002] Hydraulic fracturing technology has been widely used in the development of oil and gas fields as the main measure for oil and gas well stimulation and water well injection, and has made important contributions to the stable production and injection of oil and gas fields. Hydraulic fracturing is to pump high-viscosity pre-fluid into the target reservoir to form and extend fractures at high pressure, and then pump sand-carrying fluid mixed with proppant. The sand-carrying fluid can continue to extend the fracture and carry proppant deep into the fracture. For fractures, it is best to degrade the fracturing fluid into a low-viscosity fluid and flow back to the bottom of the well, leaving a high-conductivity flow channel formed by the proppant suppor...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L45/00C08L29/04C08L1/28C08K13/02C08K5/3492C08K5/41C08K3/32C08K3/16C08J9/08C08J9/10C08J9/14C08J3/24C09K8/68C09K8/80
CPCC08J3/246C08J9/0028C08J9/0033C08J9/0061C08J9/0066C08J9/08C08J9/102C08J9/141C08J9/142C08J2201/042C08J2201/0502C08J2203/02C08J2203/04C08J2203/12C08J2203/14C08J2345/00C08J2401/28C08J2429/04C08K5/34922C08K5/41C08K13/02C08K2003/162C08K2003/329C09K8/68C09K8/80C09K8/882C08L45/00C08L29/04C09K8/604C09K8/64
Inventor 胡书宝杨勇赵立强刘国华宁萌萌徐昆杜娟李凝张丽娜贾元钊
Owner PETROCHINA CO LTD
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