Modifier for thin-wall and high-strength gray cast iron and melting method thereof

A modifier and high-strength technology, applied in the field of modifier for gray cast iron, modifier of thin-walled high-strength gray cast iron and its melting field, can solve the problem of affecting the mechanical properties and processing properties of castings, the performance of castings fluctuating, Unstable quality of castings and other issues

Active Publication Date: 2018-10-12
FIRST TRACTOR
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to the difference in melting point of the two alloys used, the grain size of the alloy with high melting point is not greater than 1mm. When it is added to the casting ladle, alloys with large grain size and high melting point, such as chromium and zirconium, cannot be completely dissolved and are easy to form in the casting. Hard points, which affect the mechanical properties and processing properties of castings
Even if the particle size of the modifying agent is less than 1mm, hard spots will appear when the furnace temperature is low; secondly, when the particle size of the modifying agent is not greater than 1mm, it is easy to be involved in the molten iron slag along with the molten iron when it is added to the molten iron. Finally, it floats on the surface of molten iron, and is picked up during slag removal, or adheres to the wall or bottom of the pouring

Method used

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  • Modifier for thin-wall and high-strength gray cast iron and melting method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0064] Embodiment one (preparation):

[0065] Modifier chemical composition (by weight): rare earth (RE) 5.2%, silicon (Si) 23.2%, chromium (Cr) 17.0%, zirconium (Zr) 4.0%, manganese (Mn) 8.1%, calcium (Ca) 1.5% %, the balance is iron (Fe) or unavoidable impurities.

[0066] The modifier for melting the above components uses the following raw materials and proportions: rare earth ferrosilicon (FeSiRE) 32.0%, silicon calcium alloy (FeSiCa) 9.0%, ferrosilicon (FeSi) 2.0%, ferrochrome (FeCr) 29.0%, manganese Iron (FeMn) 13.0%, zirconium ferrosilicon (FeSiZr) 14.0%, the rest scrap steel (Fe) 1.0%. According to the above ratio, the raw materials are put into the electric furnace and melted according to the following melting process.

[0067] The melting process is the same as the aforementioned process steps.

Embodiment 2

[0068] Embodiment two (preparation):

[0069] Modifier chemical composition (by weight): rare earth (RE) 5.5%, silicon (Si) 20.2%, chromium (Cr) 14.1%, zirconium (Zr) 2.1%, manganese (Mn) 14.0%6, calcium (Ca) 0.8%, the balance is iron (Fe) or unavoidable impurities.

[0070] The modifier for melting the above components uses the following raw materials and proportions: rare earth ferrosilicon (FeSiRE) 36.0%, silicon calcium alloy (FeSiCa) 5.0%, ferrosilicon (FeSi) 1.5%, ferrochromium (FeCr) 26.0%, manganese Iron (FeMn) 22.0%, zirconium ferrosilicon (FeSiZr) 7.5%, and the rest scrap steel (Fe) 2.0%. According to the above ratio, the raw materials are put into the electric furnace and melted according to the following melting process.

[0071] The melting process is the same as the aforementioned process steps.

Embodiment 3

[0072] Embodiment three (preparation):

[0073] Modifier chemical composition (by weight): rare earth (RE) 8.0%, silicon (Si) 30.0%, chromium (Cr) 10.0%, zirconium (Zr) 1.0%, manganese (Mn) 7.0%, calcium (Ca) 0.4 %, the balance is iron (Fe) or unavoidable impurities.

[0074] The modifier for melting the above components uses the following raw materials and proportions: Rare earth ferrosilicon (FeSiRE) 51.0%, silicon calcium alloy (FeSiCa) 2.5%, ferrosilicon (FeSi) 7.0%, ferrochrome (FeCr) 18.5%, manganese Iron (FeMn) 13.0%, zirconium ferrosilicon (FeSiZr) 4.0%, the rest scrap steel (Fe) 4.0%. According to the above ratio, the raw materials are put into the electric furnace and melted according to the following melting process.

[0075] The melting process is the same as the aforementioned process steps.

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Abstract

The invention discloses a modifier for thin-wall and high-strength gray cast iron and a melting method thereof. The modifier comprises the following components with contents in percentage by weight: 3.0-8.0% of rare earth, 15.0-30.0% of silicon, 10.0-18.0% of chromium, 1.0-4.0% of zirconium, 7.0-14.0% of manganese, 0.2-1.5% of calcium, the balance iron and 24.5-63.8% of inevitable trace elements.The modifier is low in melting point, high in solubility, and not liable to form hard spots; the components are uniform and not liable to generate segregation after being melted, and the casting is stable in quality; the particle sizes of the modifier used in a tapping ladle are 3-5mm, and the modifier is not liable to be involved into molten slag in the ladle or attached onto the wall of the ladle; the amount of graphite in cast iron can be increased, and the sharp corners of the flake graphite are passivated, so that the mechanical property of the casting is improved; and the modifier obtained by the new modifier melting method meets the strength requirement of high-strength gray cast iron, and reduces the shrinkage performance; and meanwhile, the adding amount of molybdenum-chromium alloy can further be replaced or reduced.

Description

Technical field: [0001] The invention belongs to the field of material technology, and relates to a modifier for gray cast iron, in particular to a modifier for thin-walled high-strength gray cast iron and a melting method thereof. Background technique: [0002] As we all know, gray cast iron is a kind of cast iron with flake graphite. Because the fracture is dark gray when it breaks, it is called gray cast iron. The main components are iron, carbon, silicon, manganese, sulfur, and phosphorus. It is the most widely used cast iron. . Its mechanical properties and compactness are lower than that of vermicular iron, especially thin-walled high-strength gray cast iron is widely used in engine cylinder blocks and cylinder heads, but if too much alloy is added, the casting tends to shrink and the casting leakage rate is high . The quality of cylinder block and cylinder head castings directly affects the service life and performance of diesel engines. [0003] Many process facto...

Claims

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Application Information

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IPC IPC(8): C22C33/08C21C1/08
CPCC21C1/08C22C33/08Y02P10/20
Inventor 程俊伟黄胜操吕乐华范随长郭亚辉郭丹丹冯志明许海铎李自君向玲芳
Owner FIRST TRACTOR
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