Modified composite nanofiber membrane of cardanol and preparation method and application of membrane on enzyme immobilization

A technology of composite nanofibers and cardanol, which is applied in the direction of immobilization on/in organic carriers, fiber chemical characteristics, fiber treatment, etc., can solve the problems of low enzyme immobilization efficiency and insufficient membrane toughness, and achieve molecular weight increase, The effect of fixed action enhancement

Active Publication Date: 2018-10-16
ANHUI UNIVERSITY OF TECHNOLOGY AND SCIENCE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Existing the report of simple hordein nanofiber membrane immobilization enzyme at present, but, the pure hordein nanofiber immobilization enzyme exists the defect that t

Method used

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  • Modified composite nanofiber membrane of cardanol and preparation method and application of membrane on enzyme immobilization
  • Modified composite nanofiber membrane of cardanol and preparation method and application of membrane on enzyme immobilization
  • Modified composite nanofiber membrane of cardanol and preparation method and application of membrane on enzyme immobilization

Examples

Experimental program
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Example Embodiment

[0026] Example 1:

[0027] The cardanol-modified composite nanofiber membrane provided in this embodiment is prepared from raw materials in the following weight ratios:

[0028] Β-hydroxyethyl methacrylate 50, methyl acrylate 40, cardanol 160, epichlorohydrin 50, benzyl triethylammonium chloride 12, potassium permanganate 21, toluene 120, hordein 55, Oxidized sodium alginate 100, NN dimethylformamide 100, glacial acetic acid 60, sodium hydroxide 80, water 300.

Example Embodiment

[0029] Example 2:

[0030] The cardanol-modified composite nanofiber membrane provided in this embodiment is prepared from raw materials in the following weight ratios:

[0031] Β-hydroxyethyl methacrylate 100, methyl acrylate 50, cardanol 230, epichlorohydrin 65, benzyl triethylammonium chloride 20, potassium permanganate 32, toluene 250, hordein 100, Oxidized sodium alginate 200, NN dimethylformamide 300, glacial acetic acid 160, sodium hydroxide 150, water 600.

Example Embodiment

[0032] Example 3:

[0033] The cardanol-modified composite nanofiber membrane provided in this embodiment is prepared from raw materials in the following weight ratios:

[0034] Β-hydroxyethyl methacrylate 75, methyl acrylate 45, cardanol 195, epichlorohydrin 58, benzyl triethylammonium chloride 16, potassium permanganate 26, toluene 185, hordein 80, Oxidized sodium alginate 150, NN dimethylformamide 200, glacial acetic acid 110, sodium hydroxide 115, water 450.

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Abstract

The invention discloses a modified composite nanofiber membrane of cardanol. The composite nanofiber membrane is prepared from, by weight, 50-100 parts of hydroxyethyl methacrylate beta, 40-50 parts of methyl acrylate, 160-230 parts of cardanol, 50-65 parts of epoxy chloropropane, 12-20 parts of benzyl triethyl ammonium chloride, 21-32 parts of potassium permanganate, 120-250 parts of methylbenzene, 55-100 parts of hordein, 100-200 parts of oxidized sodium alginate, 100-300 parts of N-N dimethyl formamide, 60-160 parts of glacial acetic acid, 80-150 parts of sodium hydroxide and 300-600 partsof water. By means of modified cardanol and modified hordein, the performance and enzyme immobilization capability of the composite nanofiber membrane are improved.

Description

technical field [0001] The invention belongs to the field of nanofiber membranes, in particular to a cardanol-modified composite nanofiber membrane, a preparation method and its application in enzyme immobilization. Background technique [0002] The nanofibers obtained by electrospinning have excellent properties such as large specific surface area, high uniformity, high porosity and good connectivity between pore diameters. The electrospinning of protein has been reported before, but its application is largely restricted due to the poor tensile strength and water resistance of the prepared nanofibrous membrane. [0003] Hordein is a hydrophobic protein extracted from barley, which is mainly caused by its low solubility in water due to its high content of non-polar amino acid residues. However, these molecular properties make prolamins a naturally water- and oil-resistant material. In addition to good biodegradability and biocompatibility, gliadins also have low hydrophili...

Claims

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Application Information

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IPC IPC(8): D04H1/728D04H1/4382D01D5/00D01F8/10D01F8/02D01F8/18C12N11/10C12N11/08
CPCC12N11/08C12N11/10D01D5/003D01D5/0069D01D5/0092D01F8/02D01F8/10D01F8/18D04H1/4382D04H1/728
Inventor 刘新华宋远丁
Owner ANHUI UNIVERSITY OF TECHNOLOGY AND SCIENCE
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