A kind of alumina-titanium carbonitride composite bulletproof ceramic and its preparation method
A technology of titanium carbonitride composite phase and alumina, which is applied in the field of Al2O3-based composite phase bulletproof ceramics, can solve the problems of limited improvement of ceramic fracture toughness, adverse effects of bullet resistance, reduction of strength and hardness, etc., and achieve excellent mechanical properties performance, improving mechanical properties, and reducing density
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Embodiment 1
[0021] An alumina-titanium carbonitride composite bulletproof ceramic and a preparation method thereof. 95-99 parts by mass of high-titanium bauxite raw meal micropowder and 1-5 parts by mass of carbonaceous materials are used as raw materials; firstly, 0.1-4 parts by mass of soluble salt are dissolved in 4-7 parts by mass of water to obtain salt solution; then put the raw materials and the salt solution in a planetary ball mill, and mix them uniformly to obtain a mixture; press the mixture under the condition of 100-130MPa to obtain a green body; then put the raw The blank is dried at 150-200°C for 12-24 hours, and kept in a nitrogen atmosphere at 1550-1650°C for 4-8 hours to obtain alumina-titanium carbonitride composite bulletproof ceramics.
[0022] The soluble salt is one of aluminum chloride, aluminum nitrate, magnesium chloride, magnesium nitrate, magnesium sulfate, zirconium tetrachloride, zirconium oxychloride, zirconyl nitrate, zirconium sulfate, ammonium zirconium c...
Embodiment 2
[0026] An alumina-titanium carbonitride composite bulletproof ceramic and a preparation method thereof. 95-99 parts by mass of high-titanium bauxite raw meal micropowder and 1-5 parts by mass of carbonaceous materials are used as raw materials; firstly, 0.1-4 parts by mass of soluble salt are dissolved in 4-7 parts by mass of water to obtain salt solution; then put the raw materials and the salt solution in a planetary ball mill, and mix them uniformly to obtain a mixture; press the mixture under the condition of 100-130MPa to obtain a green body; then put the raw The blank is dried at 110-160°C for 24-36 hours, and kept in a nitrogen atmosphere at 1650-1750°C for 1-5 hours to obtain alumina-titanium carbonitride composite bulletproof ceramics.
[0027] The soluble salts are aluminum chloride, aluminum nitrate, magnesium chloride, magnesium nitrate, magnesium sulfate, zirconium tetrachloride, zirconium oxychloride, zirconyl nitrate, zirconium sulfate, ammonium zirconium carbon...
Embodiment 3
[0031] An alumina-titanium carbonitride composite bulletproof ceramic and a preparation method thereof. 95-99 parts by mass of high-titanium bauxite raw meal micropowder and 1-5 parts by mass of carbonaceous materials are used as raw materials; firstly, 0.1-4 parts by mass of soluble salt are dissolved in 4-7 parts by mass of water to obtain salt solution; then put the raw materials and the salt solution in a planetary ball mill, and mix them uniformly to obtain a mixture; press the mixture under the condition of 120-150MPa to obtain a green body; then put the raw The blank is dried at 150-200°C for 12-24 hours, and kept in a nitrogen atmosphere at 1550-1650°C for 4-8 hours to obtain alumina-titanium carbonitride composite bulletproof ceramics.
[0032] The soluble salts are three of aluminum chloride, aluminum nitrate, magnesium chloride, magnesium nitrate, magnesium sulfate, zirconium tetrachloride, zirconium oxychloride, zirconyl nitrate, zirconium sulfate, ammonium zirconi...
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