Antifouling and wear-resistant silicone coating material for ABS surface and preparation method thereof

A coating material, silicone technology, applied in anti-fouling/underwater coatings, fire-retardant coatings, coatings, etc., can solve the problems of rare reports, easy deformation of ABS, poor adhesion, etc., to improve adhesion. Focus, excellent friction resistance, excellent antifouling effect

Active Publication Date: 2021-09-28
常州穗时新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

First of all, most ABS products have a low softening point, and the coating must be screened for more effective curing accelerators; second, ABS is easy to deform, so the silicone wear-resistant and hardened coating coated on the ABS surface must take into account a certain degree of flexibility Third, ordinary silicone hard coatings have poor adhesion on ABS, and new adhesion promotion schemes must be developed
Because of these reasons, there are still few reports on silicone wear-resistant and hardened coating materials for ABS that have real application value.

Method used

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  • Antifouling and wear-resistant silicone coating material for ABS surface and preparation method thereof
  • Antifouling and wear-resistant silicone coating material for ABS surface and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] ① Prepare each component according to the following formula

[0036]Deionized 16g; acetic acid 0.2g; methyltrimethoxysilane 40g; phenyltrimethoxysilane 4g; CHG-101 hydroxy acrylic oligomer 1.5g; hydroxy silicone oil antifouling additive 0.8g; Leveling agent 0.2g; Tetramethylammonium hydroxide 0.2g; Ethylene glycol butyl ether 10g; Butyl acetate 15g;

[0037] ②In a 250mL round-bottomed flask, add deionized water and acetic acid in sequence, and after stirring evenly, slowly add the mixture of methyltrimethoxysilane and phenyltrimethoxysilane into the flask, and stir at 25°C for 2h Complete hydrolytic prepolymerization. Heated and refluxed to continue the reaction for 2.5h;

[0038] ③In the liquid material obtained in step ②, add curing accelerator, antifouling additive, wetting and leveling agent, butyl glycol ether and butyl acetate in sequence, and stir for 3 minutes to obtain antifouling and wear-resistant silicone Material (varnish).

[0039] The material obtaine...

Embodiment 2

[0041] ① Prepare each component according to the following formula

[0042] Deionized 5g; acidic silica sol 20g; acetic acid 0.2g; methyltriethoxysilane 56g; phenyltrimethoxysilane 4g; CHG-104 hydroxyacrylic oligomer 1.5g; BYK-331 wetting and leveling agent 0.2g; Guanidine hydrochloride 0.15g; Ethylene glycol butyl ether 10g; Butyl acetate 15g;

[0043] ②In a 250mL round-bottomed flask, add deionized water and acetic acid in sequence, and after stirring evenly, slowly add the mixture of methyltriethoxysilane and phenyltrimethoxysilane into the flask, and stir the reaction at 25°C 2h to complete the hydrolysis pre-polymerization. Heated and refluxed to continue the reaction for 2.5h;

[0044] ③In the liquid material obtained in step ②, add curing accelerator, antifouling additive, wetting and leveling agent, butyl glycol ether and butyl acetate in sequence, and stir for 3 minutes to obtain antifouling and wear-resistant silicone Material (varnish).

[0045] The material obt...

Embodiment 3

[0047] ① Prepare each component according to the following formula

[0048] 26g of acidic silica sol; 0.2g of acetic acid; 52g of methyltrimethoxysilane; 6g of phenyltrimethoxysilane; 2g of CHG-101 hydroxyl acrylic oligomer; Leveling agent 0.2g; Tetramethylammonium hydroxide 0.2g; Ethylene glycol butyl ether 10g; Butyl acetate 15g; Pearlescent mica 0.4g

[0049] ②In a 250mL round-bottomed flask, add deionized water and acetic acid in sequence, and after stirring evenly, slowly add the mixture of methyltrimethoxysilane and phenyltrimethoxysilane into the flask, and stir at 25°C for 2h Complete hydrolytic prepolymerization. Heated and refluxed to continue the reaction for 2.5h;

[0050] ③In the liquid material obtained in step ②, add curing accelerator, antifouling additive, wetting and leveling agent, ethylene glycol butyl ether and butyl acetate in sequence, and stir for 3 minutes. Add pearlescent mica and stir evenly to obtain a shiny Effect ABS antifouling, wear-resistant...

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Abstract

The invention relates to an anti-fouling and wear-resistant organic silicon coating material for ABS surface, which is prepared by the mixed reaction of the following components, and the dosage of each component is as follows: deionized water 0-30, acid silicon Sol 0‑40, effect pigment 0‑10, methyltrialkoxysilane 20‑60, phenyltrialkoxysilane 1‑8, tetraalkoxysilane 0‑10, acid catalyst 0.1‑3, curing accelerator Agent 0.1-0.4, adhesion promoter 2-5, antifouling additive 0.1-2, other functional additives 0.1-0.6, alcohol ether solvent 5-15, ester solvent 10-15. After the material of the present invention is applied on the ABS surface, it has the advantages of adhesion force 0 grade, hardness 1H, static water contact angle ≥ 105°, etc., and significantly improves the friction resistance, antifouling performance and short-term high temperature resistance and resistance of the ABS substrate. burning ability.

Description

technical field [0001] The invention relates to a new high-performance fluorosilicon material, in particular to an organosilicon coating material capable of imparting good antifouling, friction resistance and certain flame-retardant effects to ABS. Background technique [0002] Acrylonitrile-butadiene-styrene terpolymer, referred to as ABS, is a thermoplastic engineering plastic with easy-to-obtain raw materials, good comprehensive performance and low price. It has a good surface gloss and can be electroplated, hot-pressed and bonded. It has been widely used in machinery, electrical, automobile, aircraft and other manufacturing industries. ABS plastics are also widely used in kitchen ceilings, lampshades and toilet showers. to make. [0003] But ABS also has its own drawbacks. First of all, stains easily penetrate into the interior of the plastic through the surface, and its antifouling performance is not ideal; secondly, ABS has low hardness and is easy to scratch. For th...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08J7/04C08J7/046C08J7/05C09D183/04C09D5/16C09D5/18C09D7/61C09D7/63C09D7/65C08L55/02
CPCC08G77/04C08G77/06C08J2355/02C09D4/00C09D5/1687C09D5/18C09D183/04C08J7/0427
Inventor 陈子辉李林芳
Owner 常州穗时新材料有限公司
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