A kind of micro-nano anti-collapse plugging agent for drilling fluid and preparation method thereof

A plugging agent and micro-nano technology, which are used in the field of micro-nano anti-slump plugging agents for drilling fluids and their preparation, can solve the limitation of wellbore stability, cannot effectively prevent drilling fluid and its filtrate from eroding, and particles cannot effectively Blocking and other problems, to achieve the effect of good compatibility, good temperature resistance, and rheological adjustment

Active Publication Date: 2021-09-10
山东得顺源石油科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The pore size of rocks in different formations is also different. The pore size of the shale formation prone to wellbore instability is mostly micro-nano level. Conventional particles cannot effectively seal and prevent the drilling fluid and its filtrate from affecting The erosion of the formation will cause the shale to hydrate and expand, resulting in complex accidents such as well wall collapse
During the drilling process, effective plugging of micro-fractures on the borehole wall is one of the effective means to avoid the instability of the borehole wall. However, asphalt and emulsified paraffin plugging materials have relatively large particle sizes, so for formations with large fractures and gaps The plugging effect is good, but it cannot form a good size match for nano-micro pores (fractures) such as mudstone mud micro-fractures and beddings, and its wellbore stability is greatly limited

Method used

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  • A kind of micro-nano anti-collapse plugging agent for drilling fluid and preparation method thereof
  • A kind of micro-nano anti-collapse plugging agent for drilling fluid and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] Preparation:

[0024] Epoxy resin 5kg, itaconic acid 5kg, acrylic acid 18kg, 2-acrylamido-2-methylpropanesulfonic acid 15kg, ammonia water 3kg, octylphenol polyoxyethylene ether 2kg, benzoyl peroxide 0.2kg, n-butyl Alcohol 5kg, water 50kg;

[0025] Processing:

[0026] Step 1) dissolving itaconic acid, acrylic acid, and 2-acrylamido-2-methylpropanesulfonic acid in water, and then adjusting the solution to pH=4 with ammonia water to obtain mixed solution 1;

[0027] Step 2) Weighing epoxy resin and n-butanol and dissolving at 60° C. for 1 hour to obtain feed liquid;

[0028] Step 3) At 80°C, pass nitrogen gas into the feed liquid obtained in step 2) for 30 minutes, then add the mixed solution 1 obtained in step 1) dropwise, and at the same time slowly add benzoyl peroxide and octylphenol polyoxyethylene ether, After the reaction time of 6h, mixed solution 2 was obtained;

[0029] Step 4) Send the mixed solution 2 obtained in step 3) into a high-shear emulsifier, add ...

Embodiment 2

[0031] Preparation:

[0032] Epoxy resin 8kg, itaconic acid 12kg, acrylic acid 10kg, 2-acrylamido-2-methylpropanesulfonic acid 25kg, potassium hydroxide 5kg, polyoxyethylene sorbitan trioleate 3kg, potassium persulfate 0.8 kg, toluene 12kg, water 100kg;

[0033] Processing:

[0034] Step 1) dissolving itaconic acid, acrylic acid, and 2-acrylamido-2-methylpropanesulfonic acid in water, and then adjusting the solution to pH=6 with potassium hydroxide to obtain mixed solution 1;

[0035] Step 2) Weighing epoxy resin and toluene and dissolving at 100° C. for 1 hour to obtain a feed solution;

[0036] Step 3) At 60°C, pass nitrogen gas into the feed solution obtained in step 2) for 30 minutes, then add the mixed solution 1 obtained in step 1) dropwise, and slowly add potassium persulfate and polyoxyethylene sorbitan trioleic acid at the same time ester, after the reaction time of 4h, mixed solution 2 was obtained;

[0037] Step 4) Send the mixed solution 2 obtained in step 3) i...

Embodiment 3

[0039] Preparation:

[0040] Epoxy resin 18kg, itaconic acid 7kg, acrylic acid 30kg, 2-acrylamido-2-methylpropanesulfonic acid 9kg, sodium hydroxide 4kg, mixture of sodium lauryl sulfate and sorbitan oleate 4kg, Azobisisobutyronitrile 0.4kg, mixture of xylene and 1,4-butanediol 10kg, water 70kg;

[0041] Processing:

[0042] Step 1) dissolving itaconic acid, acrylic acid, and 2-acrylamido-2-methylpropanesulfonic acid in water, and then adjusting the solution to pH=3 with sodium hydroxide to obtain mixed solution 1;

[0043] Step 2) Weighing the mixture of epoxy resin, xylene and 1,4-butanediol and dissolving it at 80° C. for 1 hour to obtain a feed solution;

[0044] Step 3) At 70°C, after 30 minutes of passing nitrogen gas into the feed solution obtained in step 2), add the mixed solution 1 obtained in step 1) dropwise, and at the same time slowly add azobisisobutyronitrile, sodium lauryl sulfate and The mixture of sorbitan oleic acid ester, after reaction time 8h, obtain ...

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Abstract

The invention discloses a micro-nano anti-collapse plugging agent for drilling fluid and a preparation method thereof. The plugging agent is made of the following raw materials in proportions by weight: 5-20 parts of epoxy resin, 5-15 parts of itaconic acid 10-38 parts of acrylic acid, 15-35 parts of 2-acrylamido-2-methylpropanesulfonic acid, 2-10 parts of pH regulator, 1-6 parts of emulsifier, 0.2-1.0 parts of initiator, solvent 5‑15 parts, water 50‑150 parts. Compared with the prior art, the present invention has nano-scale and micron-scale deformable particles, reduces fluid loss, regulates rheology, has good temperature resistance, no fluorescence, and good compatibility; at the same time, the molecular chain of the plugging agent has A variety of adsorption groups can be adsorbed on the surface of clay particles to repair the filter cake formed by the particle filling in the drilling fluid; through the particle size and deformable characteristics, it can enter the pores and bedding of the shale formation and prevent the filtrate from entering The formation plays a role in stabilizing the well wall; the plugging agent has strong dispersion ability and high stability, and is suitable for hard and brittle mudstone with various micro-fractures.

Description

technical field [0001] The invention relates to the technical field of drilling fluid treatment agents, in particular to a micro-nano anti-collapse plugging agent for drilling fluid and a preparation method thereof. Background technique [0002] Wellbore stability is a common problem in many oilfields in the world, and it has been perplexing the development of the petroleum industry. At present, there are many ways and methods for water-based drilling fluid to protect walls and prevent collapse, which can be generally summarized into three directions, namely: density support, plugging and preventing collapse, and inhibiting hydration. The currently commonly used anti-slump agents such as asphalt, humic acid and other products are limited in application due to reasons such as fluorescence level and environmental protection performance; while the plugging agent emulsified paraffin is commonly used, but its temperature resistance is poor and its softening point Low, the applic...

Claims

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Application Information

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IPC IPC(8): C09K8/03C09K8/506C09K8/508
CPCC09K8/03C09K8/506C09K8/5086
Inventor 郭东荣王树永康乃静
Owner 山东得顺源石油科技有限公司
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