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Preparation method for rubber seal for automobile oil seal

A technology for rubber seals and oil seals, applied in chemical instruments and methods, and other chemical processes, can solve the problems of insufficient sealing effect of nitrile rubber seals, and achieve the effects of improved elasticity, high compressive strength, and stable performance

Inactive Publication Date: 2018-12-11
NINGGUO RUIPUSLS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to the strict performance requirements of rubber seals for automotive oil seals, nitrile rubber has been widely used in various high-temperature and oil-resistant environments, and has become a sealing material for automotive oil seals in recent years. At present, the sealing effect of nitrile rubber seals is Insufficient problems need to be solved urgently

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] A method for preparing a rubber seal for automobile oil seals, comprising the steps of:

[0019] S1. Stir 20kg of humic acid and 120kg of sodium hydroxide solution with a concentration of 0.5mol / L for 4h, the stirring temperature is 70°C, and the adjustment system is neutral. Add 45kg of nano titanium dioxide and 1kg of polyethylene glycol 400 and stir for 20min. at 2000r / min, add 2kg sodium carboxymethylcellulose and 2kg epichlorohydrin and stir for 80min at a stirring temperature of 90°C, filter, wash, and dry to obtain a prefabricated material;

[0020] S2. Mix 160kg of nitrile rubber, 60kg of polyurethane rubber, 2kg of epoxy soybean oil, 1kg of acetyl tributyl citrate, and 4kg of dioctyl terephthalate for 1min. The mixing temperature is 162°C, and the temperature is lowered to 110°C to continue Mixed for 60s to obtain the mixed material;

[0021] S3, add 50kg prefabricated material, 20kg heavy calcium carbonate, 30kg nanometer mica powder, 0.4kg stearic acid, 2kg ...

Embodiment 2

[0023] A method for preparing a rubber seal for automobile oil seals, comprising the steps of:

[0024] S1. Stir 30kg of humic acid and 80kg of sodium hydroxide solution with a concentration of 0.8mol / L for 2h, the stirring temperature is 90°C, and the adjustment system is neutral. Add 25kg of nano titanium dioxide and 3kg of polyethylene glycol 400 and stir for 10min. at 2600r / min, add 1kg sodium carboxymethylcellulose and 4kg epichlorohydrin and stir for 40min at a stirring temperature of 96°C, filter, wash, and dry to obtain a prefabricated material;

[0025] S2. Mix 120kg of nitrile rubber, 100kg of polyurethane rubber, 1kg of epoxy soybean oil, 2kg of acetyl tributyl citrate, and 2kg of dioctyl terephthalate for 4 minutes. The mixing temperature is 145°C, and the temperature is lowered to 118°C to continue Mixed for 30s to obtain the mixed material;

[0026] S3, add 30kg prefabricated material, 30kg heavy calcium carbonate, 20kg nanometer mica powder, 1kg stearic acid, 1...

Embodiment 3

[0028] A method for preparing a rubber seal for automobile oil seals, comprising the steps of:

[0029] S1. 22kg humic acid and 110kg concentration of 0.6mol / L sodium hydroxide solution were stirred for 3.5h, the stirring temperature was 75°C, the adjustment system was neutral, 40kg nanometer titanium dioxide and 1.5kg polyethylene glycol 400 were added and stirred for 18min, The stirring speed is 2200r / min, add 1.8kg sodium carboxymethylcellulose and 2.5kg epichlorohydrin and stir for 70min, the stirring temperature is 92°C, filter, wash and dry to obtain the prefabricated material;

[0030] S2, 150kg nitrile rubber, 70kg polyurethane rubber, 1.8kg epoxy soybean oil, 1.3kg acetyl tributyl citrate, 3.5kg dioctyl terephthalate were mixed for 2min, the mixing temperature was 160°C, and the temperature was lowered to Continue mixing at 112°C for 50s to obtain a mixed material;

[0031] S3, add 45kg prefabricated material, 22kg heavy calcium carbonate, 27kg nano-mica powder, 0.6k...

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Abstract

The invention discloses a preparation method for a rubber seal for an automobile oil seal. The preparation method comprises the following steps that humic acid and a sodium hydroxide solution are stirred, a system is adjusted to be neutral, nano titanium dioxide and polyethylene glycol 400 are added and stirred, sodium carboxymethylcellulose and epoxy chloropropane are added and stirred, and filtering, washing and drying are carried out so as to obtain a prefabricated material; nitrile rubber, polyurethane rubber, epoxidized soybean oil, acetyl tributyl citrate and dioctyl terephthalate are mixed, cooled and continuously mixed so as to obtain a mixed material; and the prefabricated material, heavy calcium carbonate, nano mica powder, stearic acid, an anti-aging agent MBZ and an anti-agingagent BLE are added into the mixed material and are continuously mixed, sulfur, tetramethyl thiuram disulfide, oxy-divinyl benzothiazole sulfenamide and magnesium oxide are added and are continuouslymixed, and vulcanizing is carried out so as to obtain the rubber seal for the automobile oil seal. The rubber seal prepared through the preparation method has the advantages of being good in sealing effect and high in tensile strength and elongation at break.

Description

technical field [0001] The invention relates to the technical field of rubber seals, in particular to a preparation method for rubber seals used in automobile oil seals. Background technique [0002] Rubber seals are the core components of automotive oil seals, and their sealing effect directly depends on the sealing performance of rubber seals. Due to the strict performance requirements of rubber seals for automotive oil seals, nitrile rubber has been widely used in various high-temperature and oil-resistant environments, and has become a sealing material for automotive oil seals in recent years. At present, the sealing effect of nitrile rubber seals is Insufficient problems need to be resolved urgently. Contents of the invention [0003] Based on the technical problems existing in the background technology, the present invention proposes a method for preparing a rubber seal used for automobile oil seals. The obtained seal has good sealing effect, high tensile strength a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L9/02C08L75/04C08L91/00C08L97/00C08K13/02C08K3/22C08K5/11C08K5/12C08K3/34C08K3/26C09K3/10
CPCC08K2003/2241C08K2003/265C08K2201/011C08L9/02C08L2205/035C09K3/10C08L75/04C08L91/00C08L97/005C08K13/02C08K3/22C08K5/11C08K5/12C08K3/34C08K3/26
Inventor 方勇
Owner NINGGUO RUIPUSLS