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Sea salt water desalination and strong brine comprehensive utilization energy-saving process

A technology for desalination of salt water and concentrated brine, applied in general water supply conservation, chemical industry, seawater treatment, etc., can solve the problems of poor process economy and adaptability, and achieve high heat energy utilization rate, high product quality, low production cost and energy consumption Reduced effect

Inactive Publication Date: 2018-12-18
CHINA LIGHT IND INT ENG CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] The purpose of the present invention is to provide an energy-saving process for the comprehensive utilization of salt water desalination and concentrated brine, which uses membrane technology to separate fresh water, monovalent and divalent compounds, and evaporates and separates monovalent and divalent compounds through a reasonable process, which is beneficial to Reduce investment, energy consumption and cost, and can solve the problems of poor economy and adaptability of existing processes

Method used

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  • Sea salt water desalination and strong brine comprehensive utilization energy-saving process

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Experimental program
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Effect test

Embodiment 1

[0037] Embodiment 1: take 900m 3 Seawater (NaCl 30g / l, KCl 0.72g / l, NaBr 0.14g / l, MgSO 4 2.15g / l, MgCl 2 3.28g / l) as raw material, using reverse osmosis to desalinate seawater to produce 600 tons of fresh water and 300m 3 Concentrated brine (NaCl90g / l, KCl 2.16g / l, NaBr 0.42g / l, MgSO 4 6.45g / l, MgCl 2 9.84g / l), the reverse osmosis temperature is 30°C; the 300m 3 Concentrated brine adopts air blowing method to produce 0.29 tons of bromine (Br 2 ) and 300m 3 Debrominated concentrated brine (NaCl 90g / l, KCl2.16g / l, NaBr 0.015g / l, MgSO 4 6.45g / l, MgCl 2 9.84g / l); the 300m 3 Debrominated concentrated brine (NaCl 90g / l, KCl 2.16g / l, NaBr0.015g / l, MgSO 4 6.45g / l, MgCl 2 9.84g / l) and 3.49m 3 Potassium mother liquor (NaCl250g / l, KCl 193g / l, MgSO 4 26.1g / l, MgCl 2 87.2g / l) after mixing 303.49m 3 The mixture was separated by nanofiltration to obtain 278.7m 3 Monovalent compound brine (NaCl 100g / l, KCl 4.7g / l, MgSO 4 0.3g / l, MgCl 2 1.0g / l) and 24.79m 3 Divalent c...

Embodiment 2

[0038] Embodiment 2: take 900m 3 Seawater (NaCl 30g / l, KCl 0.72g / l, NaBr 0.14g / l, MgSO 4 2.15g / l, MgCl 2 3.28g / l) as raw material, using thermal distillation for seawater desalination to produce 600 tons of fresh water and 300m 3 Concentrated brine (NaCl90g / l, KCl 2.16g / l, NaBr 0.42g / l, MgSO 4 6.45g / l, MgCl 2 9.84g / l), thermal distillation temperature 80°C; 300m 3 Concentrated brine adopts air blowing method to produce 0.29 tons of bromine (Br 2 ) and 300m 3 Debrominated concentrated brine (NaCl 90g / l, KCl2.16g / l, NaBr 0.015g / l, MgSO 4 6.45g / l, MgCl 2 9.84g / l); the 300m 3 Debrominated concentrated brine (NaCl 90g / l, KCl 2.16g / l, NaBr0.015g / l, MgSO 4 6.45g / l, MgCl 2 9.84g / l) and 3.49m 3 Potassium mother liquor (NaCl250g / l, KCl 193g / l, MgSO 4 26.1g / l, MgCl 2 87.2g / l) after mixing 303.49m 3 The mixture was separated by nanofiltration to obtain 278.7m 3 Monovalent compound brine (NaCl 100g / l, KCl 4.7g / l, MgSO 4 0.3g / l, MgCl 2 1.0g / l) and 24.79m 3 Divalent...

Embodiment 3

[0039] Embodiment 3: take 900m 3 Seawater (NaCl 30g / l, KCl 0.72g / l, NaBr 0.14g / l, MgSO 4 2.15g / l, MgCl 2 3.28g / l) as raw material, using electrodialysis for seawater desalination to produce 600 tons of fresh water and 300m 3 Concentrated brine (NaCl90g / l, KCl 2.16g / l, NaBr 0.42g / l, MgSO 4 6.45g / l, MgCl 2 9.84g / l), the electrodialysis temperature is 25°C; the 300m 3 Concentrated brine adopts air blowing method to produce 0.29 tons of bromine (Br 2 ) and 300m 3 Debrominated concentrated brine (NaCl 90g / l, KCl2.16g / l, NaBr 0.015g / l, MgSO 4 6.45g / l, MgCl 2 9.84g / l); the 300m 3 Debrominated concentrated brine (NaCl 90g / l, KCl 2.16g / l, NaBr0.015g / l, MgSO 4 6.45g / l, MgCl 2 9.84g / l) and 3.49m 3 Potassium mother liquor (NaCl250g / l, KCl 193g / l, MgSO 4 26.1g / l, MgCl 2 87.2g / l) after mixing 303.49m 3 The mixture was separated by nanofiltration to obtain 278.7m 3 Monovalent compound brine (NaCl 100g / l, KCl 4.7g / l, MgSO 4 0.3g / l, MgCl 2 1.0g / l) and 24.79m 3 Divalen...

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Abstract

The invention relates to a sea salt water desalination and strong brine comprehensive utilization energy-saving process. The process includes: taking sea salt water containing sodium chloride, magnesium sulfate, potassium chloride, sodium bromide and magnesium chloride as the raw material, and conducting sea salt water desalination to obtain fresh water and strong brine; employing air blow-out method to produce bromine and debrominated strong brine with the strong brine; subjecting the debrominated strong brine to nanofiltration separation to obtain monovalent compound strong brine and bivalent compound strong brine, subjecting the monovalent strong brine to high temperature evaporation to obtain sodium chloride and salt-making mother liquor, and subjecting the salt-making mother liquor tolow temperature evaporation to obtain potassium chloride and potassium making mother liquor, circulating the potassium making mother liquor to mixing with the debrominated strong brine, and performing nanofiltration, subjecting the bivalent strong brine to high temperature evaporation to obtain magnesium sulfate monohydrate and magnesium making mother liquor, and conducting evaporation concentration and cooling on the magnesium making mother liquor to obtain a magnesium chloride product. The process provided by the invention has the characteristics of reasonable technological flow, high heatenergy utilization, high product quality, greatly reduced production cost and energy consumption, zero discharge of strong brine, and can adapt to large-scale sea salt water desalination.

Description

technical field [0001] The invention belongs to the technical field of inorganic chemical industry, in particular to an energy-saving process for desalination of sea salt water and comprehensive utilization of concentrated brine. Background technique [0002] Desalination of salt water and comprehensive utilization of concentrated brine, that is, extraction of fresh water, chemical elements, chemicals and deep processing from sea water. Known seawater containing salt, magnesium sulfate, seawater desalination of potassium chloride, bromine, magnesium chloride and other components to produce fresh water and concentrated brine, the production of salt, magnesium sulfate, potassium chloride, bromine And the magnesium chloride process is a comprehensive utilization process of seawater chemical resources. However, this process has the problems of long process flow, unreasonable use of heat energy, high steam consumption, high production cost, and cannot adapt to large-scale seawate...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/10C01D3/06C01F5/40C01F5/30C02F103/08
CPCC01D3/06C01F5/30C01F5/40C02F1/04C02F1/20C02F1/441C02F1/442C02F1/4693C02F9/00C02F2103/08C02F2209/02C02F2301/046C02F2301/08Y02P20/10Y02A20/131
Inventor 彭赛军朱晓峰柴朝晖袁建军唐娜张维胜冯逸仙项振荣周堃
Owner CHINA LIGHT IND INT ENG CO LTD