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Methanol pyrolysis gas pressure swing adsorption agent and preparation method thereof

A technology of methanol cracking gas and pressure swing adsorption, applied in chemical instruments and methods, other chemical processes, alkali metal oxides/hydroxides, etc., can solve the problems of cost increase, large process complexity, high energy consumption, etc., and achieve The effect of improving the purity and accelerating the reaction rate

Inactive Publication Date: 2018-12-21
HEILONGJIANG LAIRUIPUSI ENVIRONMENTAL TECH DEV CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among them, the water electrolysis hydrogen production method has high energy consumption and is not cost-effective and unsuitable for industrialization; natural gas and coal conversion hydrogen production is limited by local resources, and it is necessary to choose areas rich in natural gas or coal resources, and its investment is large and the process is complicated; methanol cracking hydrogen production process It is relatively simple, easy to operate and easy to control, and the raw material methanol is a basic chemical raw material with a wide source and convenient transportation
And now there is an excess capacity of methanol, finding a way to use methanol is also very in line with the current actual needs, but the existing methanol cracking process often produces residues, which often cause impurities and impurities in non-engine oil during the refining process In the case of this method, the cost will increase in the process of using it, and it will also increase the workload. In order to solve the above technical problems, a new technical solution is proposed

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] A methanol cracking gas pressure swing adsorbent, the parts by weight of each component of the adsorbent are 1 part of inorganic alkali, 2 parts of double salt, 1 part of sulfite, 0 part of antioxidant, 1 part of aluminum oxide, diatomaceous earth 2 parts, 1 part of molecular sieve, 1 part of attapulgite and 2 parts of activated carbon. The parts by weight of each component of the sulfite are 0.1 part of sodium persulfate, 0.2 part of sodium chloride and 1 part of ferrous sulfate. Described inorganic base is potassium hydroxide. The double salt is lithium iron phosphate. The parts by weight of each component of the antioxidant are 3 parts of tea polyphenols, 5 parts of bamboo leaf antioxidant and 1 part of ascorbyl palmitate.

Embodiment 2

[0025] A pressure swing adsorbent for methanol cracking gas, the parts by weight of each component of the adsorbent are 5 parts of inorganic alkali, 3 parts of double salt, 3 parts of sulfite, 5 parts of antioxidant, 2 parts of aluminum oxide, diatomaceous earth 3 parts, 3 parts of molecular sieve, 1-3 parts of attapulgite and 2-5 parts of activated carbon. The parts by weight of each component of the sulfite are 0.3 parts of sodium persulfate, 2 parts of sodium chloride and 2 parts of ferrous sulfate. Described inorganic base is sodium hydroxide. The double salt is lithium iron phosphate. The parts by weight of each component of the antioxidant are 3 parts of tea polyphenols, 5 parts of bamboo leaf antioxidant and 1 part of ascorbyl palmitate.

Embodiment 3

[0027] A methanol cracking gas pressure swing adsorbent, the parts by weight of each component of the adsorbent are 10 parts of inorganic alkali, 5 parts of double salt, 5 parts of sulfite, 10 parts of antioxidant, 5 parts of aluminum oxide, diatomaceous earth 5 parts, 5 parts of molecular sieve, 3 parts of attapulgite and 5 parts of activated carbon. The parts by weight of each component of the sulfite are 0.5 parts of sodium persulfate, 3 parts of sodium chloride and 5 parts of ferrous sulfate. Described inorganic base is potassium hydroxide. The double salt is lithium iron phosphate. The parts by weight of each component of the antioxidant are 3 parts of tea polyphenols, 5 parts of bamboo leaf antioxidant and 1 part of ascorbyl palmitate.

[0028] Above three embodiments all adopt following preparation method to prepare:

[0029] A method for preparing a methanol cracking gas pressure swing adsorbent, the method comprising the following steps:

[0030] Step 1. Put the i...

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PUM

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Abstract

The invention discloses a methanol pyrolysis gas pressure swing adsorption agent, which consists of the following ingredients in parts by weight: 1-10 parts of inorganic base, 2-5 parts of double salt, 1-5 parts of sulfite, 0-10 parts of antioxidant, 1-5 parts of aluminium oxide, 2-5 parts of kieselguhr, 1-5 parts of molecular sieve, 1-3 parts of attapulgite and 2-5 parts of activated carbon. Theformula and the preparation method thereof specifically disclose the adsorption agent. The adsorption agent is capable of quickening the reaction rate of waste engine oil in a methanol pyrolysis process, in addition, the purity of non engine oil in a pyrolysis process can be improved, meanwhile, the adsorption agent is nontoxic, does not pollute environment and is harmless for the human body.

Description

technical field [0001] The invention relates to an adsorbent, in particular to a methanol cracking gas pressure swing adsorbent and a preparation method thereof. Background technique [0002] In recent years, the world's oil resources have become increasingly scarce, but with the rapid economic growth, the society's demand for oil products is increasing day by day. However, millions of tons of waste engine oil (including hydraulic oil, waste lubricating oil, residual oil, etc.) Turning waste into treasure is particularly important. [0003] At present, the methods of refining waste engine oil include acid-base refining, vacuum distillation, hydrofining, etc. Among them, hydrofining is recognized as the most effective, thorough and environmentally friendly method, which not only removes the elemental sulfur in the oil , hydrogen sulfide, mercaptan, and sulfide removal, and can also remove difficult-to-remove thiophene sulfur compounds, and hydrofining can significantly impr...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J20/22B01J20/28B01J20/30C10G45/02
CPCB01J20/0229B01J20/0281B01J20/041B01J20/045B01J20/046B01J20/048B01J20/08B01J20/12B01J20/14B01J20/16B01J20/20B01J20/22B01J20/28016C10G45/02C10G2300/1007C10G2300/202C10G2300/80
Inventor 刘潇李云凌
Owner HEILONGJIANG LAIRUIPUSI ENVIRONMENTAL TECH DEV CO LTD