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Fe-Cr-Zr series ferrite heat resistant alloy and preparation method thereof

A fe-cr-zr, heat-resistant alloy technology, applied in the field of heat-resistant alloy materials, can solve problems such as the decrease of high temperature strength, and achieve the effects of high temperature performance improvement, simple preparation method and low cost

Active Publication Date: 2018-12-21
INST OF METAL RESEARCH - CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] In order to solve the problem of high-temperature strength drop caused by carbide coarsening in ferrite / martensitic heat-resistant steel, the purpose of the invention is to develop a Fe-Zr based on Fe—(9~12wt.%)Cr Fe-Cr-Zr based heat-resistant alloys strengthened by intermetallic compounds to improve the high-temperature strength of heat-resistant alloys

Method used

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  • Fe-Cr-Zr series ferrite heat resistant alloy and preparation method thereof
  • Fe-Cr-Zr series ferrite heat resistant alloy and preparation method thereof
  • Fe-Cr-Zr series ferrite heat resistant alloy and preparation method thereof

Examples

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Effect test

Embodiment 1

[0028] A kind of Fe-Cr-Zr series ferritic heat-resistant alloy described in this example, the mass fraction of each element of alloy is as follows: C: 0.0039%, Cr: 8.96%, W: 2.01%, Zr: 9.5%, surplus is Fe.

[0029] The specific production process steps are as follows:

[0030] 1) Melting: Weigh the raw materials according to the alloy composition ratio, put the prepared raw materials into the crucible of the vacuum induction melting furnace, melt them in the vacuum induction furnace, and cast them into ingots. After the ingots are completely solidified, open the mold and take them out ;

[0031] 2) Forging: Heat the ingot to 1200°C, keep it warm for 1 hour, quickly place it on a hammer forging machine to forge into a slab, then air cool to room temperature, and the final forging temperature is above 900°C.

[0032] 3) Rolling: heat the forged plate to 1200°C, keep it warm for 1 hour, roll it into a plate in a two-roll hot rolling mill, then air cool to room temperature, and ...

Embodiment 2

[0040] A kind of Fe-Cr-Zr series ferritic heat-resistant alloy described in this example, the mass fraction of each element of alloy is as follows: C: 0.0045%, Cr: 9.4%, W: 1.8%, Zr: 8.5%, surplus is Fe.

[0041] The preparation process of the alloy is the same as in Example 1.

[0042] After testing, the yield strength of the obtained alloy at 700° C. is 210 MPa, the tensile strength is 258 MPa, and the elongation is 50.8%.

Embodiment 3

[0044] A kind of Fe-Cr-Zr series ferritic heat-resistant alloy described in this example, the mass fraction of each element of alloy is as follows: C: 0.0040%, Cr: 9.5%, W: 1.6%, Zr: 6.5%, surplus is Fe.

[0045] The preparation process of the alloy is the same as in Example 1.

[0046] After testing, the yield strength of the obtained alloy at 700° C. is 205 MPa, the tensile strength is 243 MPa, and the elongation is 52.5%.

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Abstract

The invention discloses a Fe-Cr-Zr series ferrite heat resistant alloy and a preparation method thereof, and belongs to the technical field of heat resistant alloy materials. The alloy comprises the chemical compositions of, by weight, no more than 0.01% of C, 8.0-12.0% of Cr, 0-2.0% of W, 5.0-10.0% of Zr, and the balance Fe. The preparation method of the Fe-Cr-Zr series ferrite heat resistant alloy includes the steps that batching is carried out according to the chemical composition ratio of the Fe-Cr-Zr ferrite heat resistant alloy, after pouring and ingot casting are carried out by adoptingvacuum smelting, forging, rolling and heat treatment are carried out in sequence. According to the Fe-Cr-Zr series ferrite heat resistant alloy, the good high-plasticity is achieved under high temperature, compared with existing ferrite / martensitic heat resistant steel, and without losing the high-temperature plasticity, the high temperature strength is improved remarkably.

Description

Technical field: [0001] The invention relates to the technical field of heat-resistant alloy materials, in particular to an Fe-Cr-Zr series ferritic heat-resistant alloy and a preparation method thereof. Background technique: [0002] Compared with austenitic stainless steel, ferritic / martensitic heat-resistant steel has the characteristics of small thermal expansion coefficient, high thermal conductivity, and low radiation swelling rate, so it is used in ultra (ultra) critical units, steam turbines and fourth-generation High-temperature pressure-bearing components in nuclear power plants. The main alloy composition of the existing ferritic / martensitic heat-resistant steel is Fe-(9~12wt.%)Cr, and its good high-temperature strength mainly depends on the interface formed after quenching+tempering (including the original austenitic grain boundary, martensitic lath boundary and intra-lath subgrain boundary), and M precipitated at the interface 23 C 6 carbide. Carbide is an e...

Claims

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Application Information

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IPC IPC(8): C21D8/02C22C33/04C22C38/22C22C38/28
CPCC21D8/0226C21D2211/005C22C33/04C22C38/004C22C38/22C22C38/28
Inventor 陈胜虎戎利建闫德胜王本贤姜海昌赵明久潘雪新
Owner INST OF METAL RESEARCH - CHINESE ACAD OF SCI