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A microwave-fluidized roasting device for processing complex refractory iron ore

A fluidized roasting and iron ore technology, applied in the field of mineral processing, can solve the problems of easy formation of rings, fine inlaid useful minerals, low iron ore grade, etc., and achieves sufficient gas-solid contact and improved selection index. , the effect of efficient comprehensive utilization

Active Publication Date: 2020-04-21
NORTHEASTERN UNIV LIAONING
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Problems solved by technology

[0002] With the rapid development of China's steel industry, the demand for iron ore has increased rapidly; according to the forecast of the World Iron and Steel Association, the global steel demand will exceed 3.2 billion tons between 2017 and 2018, of which China's steel demand will increase by 3%; in 2017, China imported 1.075 billion tons of iron ore, an increase of 7.5%, and its dependence on foreign countries exceeded 86%. Although China's total iron ore output is large, it generally presents the characteristics of "poor, fine, and miscellaneous", that is, iron ore is of low grade and useful. Mineral distribution is fine, ore composition is complex, and the proportion of refractory iron ore is relatively high; specifically, the overall mine iron grade is only 25-40%, and only 1.6% of mines are high-grade, and the average grade is only 34.29%, which is 10.45% lower than the global average grade. A large number of poor, impurity and weak magnetic iron ore resources have not been effectively developed and utilized; Shaped hematite is a typical iron ore resource that is difficult to use, with a total reserve of more than 20 billion tons, and is widely distributed in Liaoning, Hebei, Shanxi, Shaanxi, Hubei, Xinjiang, Guangxi and other provinces; Conventional mineral processing technology is difficult to obtain better technical and economic indicators, some resources have not yet been developed and utilized industrially, and although some resources have been developed, the utilization efficiency is extremely low; Comprehensive development and utilization is of great significance to reduce China's iron ore dependence on foreign countries and promote the healthy development of China's iron and steel industry
[0003] In recent years, around the high-efficiency development and utilization of complex refractory iron ores, many research institutes at home and abroad have carried out a lot of basic research and technological development work, among which the combination of dressing and metallurgy, that is, magnetization roasting-magnetic separation process, has the most outstanding effect, and magnetization roasting-magnetic separation process has the most outstanding effect. Magnetic separation refers to transforming weak magnetic iron minerals such as hematite, siderite, limonite, etc. into strong magnetic magnetite or maghemite through chemical reaction, and then using the magnetic difference between minerals for magnetic separation ;Magnetization roasting methods include shaft furnace roasting, rotary kiln roasting, fluidized roasting, etc.; the shaft furnace magnetization roasting process is mainly suitable for processing lump ore with a particle size of 25-75mm, and this process has the disadvantages of low single-machine processing capacity, high energy consumption, and roasting Problems such as long time and uneven product quality; the magnetization roasting process of the rotary kiln is suitable for processing ores with a particle size below 25mm. problems such as instability, low operating rate and high energy consumption; fluidization refers to the fluid state of solid material particles under the action of a fluid medium, and the fluidization process has characteristics similar to liquid; in recent years, some domestic research teams have focused on fluid state A lot of research has been carried out on chemical roasting technology and equipment. For example, the research team of Academician Yu Yongfu of Wuhan University of Technology proposed a circulating fluidized flash magnetization roasting process, and the Institute of Process Engineering, Chinese Academy of Sciences proposed a low-temperature fluidized magnetization roasting process. Good separation indicators; Among them, the pre-enrichment suspension roasting magnetic separation technology independently developed by Northeastern University is used for Wufeng-shaped hematite in Hubei, typical sedimentary hematite in eastern Chongqing, tailings in eastern Anshan Iron and Steel, and iron ore in eastern Anshan and JISCO powder ore as raw materials, carried out systematic PSRM laboratory and pilot test, all obtained good separation indicators

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  • A microwave-fluidized roasting device for processing complex refractory iron ore

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Effect test

Embodiment 1

[0043] The structure of the microwave-fluidized roasting device for processing complex refractory iron ore is as follows: figure 1 As shown, it includes a reaction chamber (2) and a microwave cavity (3) that is enclosed within it. The reaction chamber (2) is a cylindrical shape with upper and lower ends closed, and a quartz mesh (15) is provided inside; a thermocouple (10) Insert from the top of the reaction chamber (2), there is a gap between the bottom of the thermocouple (10) and the quartz mesh (15); the bottom of the reaction chamber (2) is provided with a protective gas inlet and a reducing gas inlet , the top is provided with an exhaust port (12); the microwave cavity (3) is equipped with a microwave generating device outside, and the microwave generating device is composed of a waveguide (5), a magnetron (8) and an antenna cap (6), and the waveguide (5 ) is connected to the power supply, the waveguide (5) is located below the magnetron (8), the microwave power meter (9...

Embodiment 2

[0054] Device structure is the same as embodiment 1;

[0055] Method is with embodiment 1, and difference is:

[0056] (1) The raw material of complex refractory iron ore is ore from a certain place in Yunnan, which belongs to hematite-limonite type complex refractory iron ore. The grade of TFe in this ore is 35.25%, containing FeO 9.24% by mass percentage, SiO 2 49.41%, harmful element phosphorus 0.88%;

[0057] (2) The part that is ground to a particle size of ≤0.074mm accounts for 75% of the total mass;

[0058] (3) The protective gas is CO 2 ; The reducing gas is H 2 ; The volume flow rate of the reducing gas accounts for 20% of the total volume flow rate of the reducing gas and the protective gas; the reaction temperature is 560°C, and the microwave-fluidized roasting reaction time is 4 minutes; the heating time is 5 minutes;

[0059] (4); Microwave roasting ore grinding to a particle size of ≤0.038mm accounts for 70% of the total mass, and weak magnetic separation ...

Embodiment 3

[0061] Device structure is the same as embodiment 1;

[0062] Method is with embodiment 1, and difference is:

[0063] (1) The complex refractory iron ore raw material used is hematite-siderite mixed ore in a certain place in Anshan, with a TFe grade of 34.43%, containing 9.24% FeO and SiO by mass percentage 2 49.41%, the harmful elements phosphorus and sulfur are 0.07% and 0.05% respectively;

[0064] (2) The part that is ground to a particle size of ≤0.074mm accounts for 80% of the total mass;

[0065] (3) The protective gas is CO 2 ; The reducing gas is CH 4 ; The volume flow rate of the reducing gas accounts for 30% of the total volume flow rate of the reducing gas and the protective gas; the reaction temperature is 570°C, and the microwave-fluidized roasting reaction time is 8 minutes; the heating time is 4 minutes;

[0066] (4) Microwave roasting ore grinding until particle size ≤ 0.038mm accounts for 80% of the total mass, and weak magnetic separation is carried ou...

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Abstract

A microwave-fluidized roasting device for processing complex and refractory iron ore, including a reaction chamber and a microwave cavity set outside it. A quartz mesh is installed inside the reaction chamber; a thermocouple is inserted from the top of the reaction chamber, and the bottom end is connected to There are gaps between the quartz meshes; a protective gas inlet and a reducing gas inlet are provided at the bottom of the reaction chamber, and an exhaust port is provided at the top; a microwave generating device is installed outside the microwave cavity. The device of the present invention can realize efficient and comprehensive utilization of complex and difficult-to-select weakly magnetic iron ore, concentrates the advantages of fluidized roasting and microwave heating, and makes up for each other's shortcomings in their current applications.

Description

technical field [0001] The invention belongs to the technical field of mineral processing, and in particular relates to a microwave-fluidized roasting device for processing complex refractory iron ore. Background technique [0002] With the rapid development of China's steel industry, the demand for iron ore has increased rapidly; according to the forecast of the World Iron and Steel Association, the global steel demand will exceed 3.2 billion tons between 2017 and 2018, of which China's steel demand will increase by 3%; in 2017, China imported 1.075 billion tons of iron ore, an increase of 7.5%, and its dependence on foreign countries exceeded 86%. Although China's total iron ore output is large, it generally presents the characteristics of "poor, fine, and miscellaneous", that is, iron ore is of low grade and useful. Mineral distribution is fine, ore composition is complex, and the proportion of refractory iron ore is relatively high; specifically, the overall mine iron gr...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22B1/10
CPCC22B1/10
Inventor 韩跃新周文涛孙永升李艳军高鹏
Owner NORTHEASTERN UNIV LIAONING
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