Toughened antistatic dual-functional plastic master batch for direct injection molding and preparation method thereof

A technology of injection molding and plastic masterbatch, applied in the field of toughening and antistatic bifunctional plastic masterbatch and its preparation, can solve the problems of difficult toughening modification, decreased toughening effect, low elastic ionomer melt strength, etc. , to achieve the effect of being beneficial to the toughening effect, enhancing the toughening effect and reducing the deformation of the dispersed phase

Active Publication Date: 2019-02-22
江苏万纳普新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, it is difficult to directly apply elastic ionomers to the toughening modification in the plastic injection molding process. The “sea-island” phase structure with regular shape can be obtained by cutting action, which leads to the decrease of toughening effect.

Method used

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  • Toughened antistatic dual-functional plastic master batch for direct injection molding and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] A toughened and antistatic dual-functional plastic masterbatch for direct injection molding and a preparation method thereof, the mass ratio of its raw materials is as follows:

[0031] Calcium ion cross-linked ethylene-methacrylic acid copolymer elastic ionomer 83.0kg

[0032] Zinc ion cross-linked sulfonated three-arm telechelic polybutadiene ionomer 5.12kg

[0033] K30 polyvinylpyrrolidone 6.0kg

[0034] LDPE 5.0kg

[0035] Dicumyl peroxide 0.08kg

[0036] Calcium stearate 0.3kg

[0037] Polyethylene wax 0.5kg

[0038] Calcium ion cross-linked ethylene-methacrylic acid copolymerized elastic ionomer, zinc ion cross-linked sulfonated three-arm telechelic polybutadiene ionomer, K30 polyvinylpyrrolidone, low density Put polyethylene, dicumyl peroxide, calcium stearate and polyethylene wax into the high-speed mixer and mix evenly, then transfer to the internal mixer for thermal mixing, the mixing temperature is set at 135°C, and the mixing time is 16 minutes; then t...

Embodiment 2

[0040] A toughened and antistatic dual-functional plastic masterbatch for direct injection molding and a preparation method thereof, the mass ratio of its raw materials is as follows:

[0041] Zinc ion cross-linked ethylene-octene-acrylic acid copolymer elastic ionomer 76.15kg

[0042] Calcium ion cross-linked sulfonated three-arm telechelic polybutadiene ionomer 10.0kg

[0043] K25 Polyvinylpyrrolidone 3.0kg

[0044] Atactic polypropylene 10.0kg

[0045] Dicumyl peroxide 0.05kg

[0046] Stearic acid 0.5kg

[0047] Oxidized polyethylene wax 0.3kg

[0048] Zinc ion cross-linked ethylene-octene-acrylic acid copolymerized elastic ionomer, calcium ion cross-linked sulfonated three-arm telechelic polybutadiene ionomer, K25 polyvinylpyrrolidone, no Standard polypropylene, dicumyl peroxide, stearic acid and oxidized polyethylene wax were put into a high-speed mixer and mixed evenly, then transferred to an internal mixer for thermal mixing, and the mixing temperature was set at 1...

Embodiment 3

[0050] A toughened and antistatic dual-functional plastic masterbatch for direct injection molding and a preparation method thereof, the mass ratio of its raw materials is as follows:

[0051] Barium ion cross-linked ethylene-methacrylic acid copolymer elastic ionomer 75.0kg

[0052] Magnesium ion cross-linked sulfonated three-arm telechelic isoprene ionomer 10.0kg

[0053] K60 polyvinylpyrrolidone 5.62kg

[0054] LDPE 8.5kg

[0055] Dilauroyl peroxide 0.03kg

[0056] Zinc stearate 0.4kg

[0057] Oxidized polyethylene wax 0.45kg

[0058] Barium ion cross-linked ethylene-methacrylic acid copolymer elastic ionomer, magnesium ion cross-linked sulfonated three-arm telechelic isoprene ionomer, K60 polyvinylpyrrolidone, low density Polyethylene, dilauroyl peroxide, zinc stearate and oxidized polyethylene wax were put into a high-speed mixer and mixed evenly, then transferred to an internal mixer for thermal mixing, and the mixing temperature was set at 138°C. The time is 20 mi...

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Abstract

The invention belongs to the technical field of plastic modification and processing and in particular relates to toughened antistatic dual-functional plastic master batch capable of being directly used for injection molding of a plastic product and a preparation method of the toughened antistatic dual-functional plastic master batch. The dual-functional plastic master batch is prepared from the following components in percentage by mass: 75.0 to 83.0 weight percent of a vinyl elastic ionomer, 5.0 to 10.0 weight percent of a three-arm telechelic ionomer, 3.0 to 6.0 weight percent of polyvinylpyrrolidone, 5.0 to 10.0 weight percent of carrier resin, 0.03 to 0.08 weight percent of a micro-crosslinking initiator, 0.3 to 0.5 weight percent of dispersant and 0.3 to 0.5 weight percent of a lubricant, wherein the polyvinylpyrrolidone is medium and low molecular weight N-polyvinylpyrrolidone with the K value of 25 to 60. Compared with traditional plastic master batch, the plastic master batch prepared by the invention not only has good toughening and antistatic dual-functional modification effects, but also has the properties of easiness for dispersion and easiness for processing; the toughened antistatic dual-functional plastic master batch can be simply mixed with modified plastic according to a ratio and then a mixture is directly used for injection molding processing of the plasticproduct; and a good modification effect is obtained.

Description

technical field [0001] The invention belongs to the technical field of plastic modification and processing, and in particular relates to a toughened and antistatic dual-functional plastic masterbatch which can be directly applied to injection molding of plastic products and a preparation method thereof. Background technique [0002] Using twin-screw extruder to implement melt blending extrusion method is an important technical development direction in the field of high-performance and multi-functional modification processing of thermoplastics. The high-efficiency and excellent mixing performance of twin-screw extruder can be used for general and Continuous melt blending of engineering plastics and various plastic modification additives and extrusion granulation, the modified special materials prepared are then used in injection or extrusion molding processing, which can not only effectively improve the strength, toughness, Mechanical properties such as stiffness can also end...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/08C08L47/00C08L39/06C08L23/06C08L23/12C08L23/28C08L25/06C08K5/14C08K5/09C08K5/098C08J3/22C08J3/24
CPCC08J3/226C08J3/246C08J2423/08C08J2423/12C08J2423/28C08J2425/06C08J2439/00C08J2447/00C08K5/09C08K5/098C08K5/14
Inventor 李翰卿
Owner 江苏万纳普新材料科技有限公司
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