Environment-friendly PVC eraser with high finish and antibacterial function, and preparation process thereof
A preparation process, eraser technology, applied in the direction of eraser, printing, office supplies, etc., to achieve the effect of low wear, reduced wear loss, excellent hardness and puncture strength
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Embodiment 1
[0046] A kind of preparation technology of the environment-friendly PVC eraser with high light antibacterial function, concrete steps are as follows:
[0047] (1) dissolving polyvinyl alcohol with a degree of alcoholysis of 70 mol% in deionized water, then adding initiator and vinyl chloride monomer, uniformly dispersing and transferring to a polymerization kettle;
[0048] (2) Add a crosslinking agent and heat to 50°C for polymerization;
[0049] (3) When the conversion rate of vinyl chloride monomer reaches 42%, add silane coupling agent, hydroxypropyl methylcellulose, and sucrose polyester, and heat up to 75°C at a heating rate of 12°C / min for polymerization until chlorine The ethylene monomer conversion rate reaches 85%, the polymerization reaction is completed, the unreacted monomer is recovered, the obtained slurry is centrifuged and dried to obtain a modified polyvinyl chloride resin, which is used for future use;
[0050] (4) Add dioctyl terephthalate, paraffin oil, z...
Embodiment 2
[0066] A kind of preparation technology of the environment-friendly PVC eraser with high light antibacterial function, concrete steps are as follows:
[0067] (1) dissolving polyvinyl alcohol with a degree of alcoholysis of 72mol% in deionized water, then adding initiator and vinyl chloride monomer, uniformly dispersed and transferred to a polymerization kettle;
[0068] (2) Add a crosslinking agent and heat to 60°C for polymerization;
[0069] (3) When the conversion rate of vinyl chloride monomer reaches 46%, add silane coupling agent, hydroxypropyl methylcellulose, and sucrose polyester, and heat up to 75-80°C at a heating rate of 15°C / min for polymerization. Until the conversion rate of vinyl chloride monomer reaches 85%, the polymerization reaction is terminated, the unreacted monomer is recovered, and the obtained slurry is centrifuged and dried to obtain a modified polyvinyl chloride resin for future use;
[0070] (4) Add dioctyl terephthalate, paraffin oil, zinc stear...
Embodiment 3
[0086] A kind of preparation technology of the environment-friendly PVC eraser with high light antibacterial function, concrete steps are as follows:
[0087] (1) Dissolving polyvinyl alcohol with a degree of alcoholysis of 71mol% in deionized water, then adding initiator and vinyl chloride monomer, uniformly dispersed and transferred to a polymerization kettle;
[0088] (2) Add a crosslinking agent and heat to 55°C for polymerization;
[0089] (3) When the conversion rate of vinyl chloride monomer reaches 44%, add silane coupling agent, hydroxypropyl methylcellulose, and sucrose polyester, and heat up to 78°C at a heating rate of 13°C / min for polymerization until chlorine The ethylene monomer conversion rate reaches 85%, the polymerization reaction is completed, the unreacted monomer is recovered, the obtained slurry is centrifuged and dried to obtain a modified polyvinyl chloride resin, which is used for future use;
[0090] (4) Add dioctyl terephthalate, paraffin oil, zinc...
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