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Environment-friendly single liquid aqueous mixed coating and double liquid aqueous mixed coating

A water-based, coating technology, used in epoxy resin coatings, polyurea/polyurethane coatings, coatings, etc., can solve problems such as poor film hardness, material processing methods that limit the peeling of protective films, and difficult handling.

Inactive Publication Date: 2019-03-15
SUNNY GENERAL INT
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0024] Disadvantages: When applied to a large area with a curved or 3D surface, the film cannot achieve full protection; the film only relies on static electricity or the adhesion of the pressure-sensitive adhesive to the surface of the material is not good; the hardness of the film is not good; there may be residual glue (sensitive) Lamination); poor resistance to processing chemicals
[0027] Disadvantages: In the process of manufacturing, transportation and coating processing and drying, a large amount of organic solvents (usually >75% solvent) will volatilize, which is not only flammable but also causes air pollution; the final coating film is not easy to peel off, and it needs to rely on a large amount of organic solvents, so cleaning The final coating film contains a large amount of solvent and is difficult to handle
[0030] Disadvantages: During the coating process, there are volatile organic substances (including plasticizers), which cause concerns about industrial safety and hygiene; and it is not easy to remove the film after processing, and it needs to be destructively treated with strong alkali
[0033] Disadvantages: the existence of organic solvents that cause VOC troubles; the emulsifier added to the surface of the protective material is displaced, causing surface contamination; emulsions, additives, and additives often cause paint instability (emulsions are subject to critical cell concentration (CMC, critical micelle concentration), temperature and mechanical stirring will cause the emulsion to be unstable); the final protective film is not easy to peel off, and more organic solvents need to be used for cleaning
[0034] In view of the above, the traditional method of material surface protection not only causes environmental protection, sanitation, and safety problems and hidden worries, but also has the limitation of material processing methods and the difficulty of peeling off the final protective film that needs to be overcome; It is becoming more and more stringent, so it is imperative to seek products that meet environmental protection requirements, especially for the industry to respond to the social responsibility of protecting the earth

Method used

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  • Environment-friendly single liquid aqueous mixed coating and double liquid aqueous mixed coating
  • Environment-friendly single liquid aqueous mixed coating and double liquid aqueous mixed coating
  • Environment-friendly single liquid aqueous mixed coating and double liquid aqueous mixed coating

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0109] Embodiment one: the water-based mixed coating of protecting plastic material

[0110] Select the hybrid resin of water-based PU resin dispersion (emulsion) (PU-1) and water-based acrylic resin (AC-2), PU-1 / AC-2=4 / 1, bridging agent, polyaziridines, PICASSIAN XL-706) accounts for 2.0% (2.0phr) of the solid content of the resin coating, and is prepared into a "single-component" water-based hybrid coating; sprayed on the surface of a clean polymethyl methacrylate (PMMA) transparent sheet, Then place it in a 50°C oven and dry it with hot air to form a transparent protective film with a thickness of about 35mm, a hardness of 1H pencil hardness, and an adhesion of 4-5B; after immersing the transparent sheet in a 60°C aqueous solution for 15 minutes, the coating film is smooth and automatic Shedding, no paint residue on PMMA surface.

Embodiment 2

[0111] Embodiment 2: Water-based hybrid paint for protecting aluminum materials:

[0112] Select the hybrid resin of water-based epoxy resin emulsion (EP-1), water-based PU resin dispersion (emulsion) (PU-1) and water-based acrylic resin (AC-1), EP-1 / PU-1 / AC-2= 2 / 3 / 1, bridging agent, polyaziridines (PICASSIAN XL-706) and polycarbodiimides (polycarbodiimides, PICASSIAN XL-701) are respectively 2.0% (2.0phr) of the solid content of the resin coating, Prepare a "single-component" water-based hybrid coating; before construction, add 20phr of fillers such as barium sulfate to increase the consistency of the water-based coating, increase the thickness of the coating film, and increase the wear resistance of the dry film. Before coating construction, use a mechanical mixer to stir the coating formula evenly, spray it on the cleaned aluminum surface, and then put it in a 90°C oven to dry with hot air to form a protective film with a thickness of about 50mm and a hardness of 2H pencil ...

Embodiment 3

[0113] Embodiment three: the water-based coating that protects stainless steel:

[0114] Select the mixed resin (EP-2 / PU-3 / AC-1= 2 / 3 / 1), when A agent; mixed bridging agent, polyaziridines (polyaziridines, PICASSIAN XL-706) and polyisocyanate (polyisocyanates, CORONATE AQ130) are 2.0% (2.0phr) of resin coating solid content when B agent, prepared into a "two-component" water-based hybrid coating; this two-component formulation (A / B agent) is mixed uniformly before spraying, and before construction, add barium sulfate and aluminum oxide 30phr (to increase the consistency of the water-based coating ), and increase the thickness of the coating film, as well as the abrasion resistance of the dry film. Before spraying, mix the paint formula evenly with three rollers, spray it on the surface of stainless steel, and then put it in an oven at 80°C to dry it with hot air to form a protective film with a thickness of about 55 mm and a hardness of 2-3H pencil hardness. (Baiger test) is ...

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Abstract

The invention discloses an environment-friendly single liquid aqueous mixed coating which comprises an agent A: an aqueous resin dispersion liquid and a selected bridging agent as an agent B, whereinthe aqueous resin dispersion liquid comprises a group composed of tertiary amine (for example aqueous resin neutralized by triethylamine) and at least one aqueous resin which is selected from water-borne epoxy resin, water-borne polyurethane and water-borne acrylic-based resin, wherein the at least one aqueous solution contains carboxyl and other reactive functional groups; when the agents A and Bare mixed to form the single liquid aqueous mixed coating, sprayed and dried, the bridging agent is bridged with the at least one aqueous resin to form a reciprocal crossed netty structure. The single liquid aqueous mixed coating can be coated to various materials to form non-permanent material protecting films. After the materials are processed, the materials are only soaked in water, and the protecting films can be peeled, recovered and centrally processed from the surfaces of the materials easily without using any organic solvents in the full course. The invention also discloses a double liquid aqueous mixed coating.

Description

technical field [0001] The invention relates to an environment-friendly one-component water-based hybrid coating, more particularly to a one-component water-based hybrid coating comprising a hybrid resin and a bridging agent. The invention also relates to a two-component water-based hybrid paint. Background technique [0002] Whether it is the processing or reprocessing of organic or inorganic materials, it is often exposed to dusty environments with a hardness of 7.0 Mohs scale; generally, inorganic materials (metals and non-metals) have higher hardness than organic materials , but the hardness of inorganic materials is still less than 7.0; inorganic materials include metals and non-metals, such as: [0003] 1. Metal: iron, steel, aluminum, copper, metal alloy, metal plated (nickel, chromium) film, etc.; [0004] 2. Non-metal: wafers, glass (optics, solar panels, ITO, lenses, mirrors), stone. [0005] During the polishing surface, material transportation and processing o...

Claims

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Application Information

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IPC IPC(8): C09D175/08C09D175/06C09D175/04C09D163/00C09D133/00C09D5/20
CPCC08K2003/2227C08K2003/2241C08K2003/265C08K2003/3045C08L2205/03C09D5/20C09D133/00C09D163/00C09D175/04C09D175/06C09D175/08C08L75/06C08L75/04C08L63/00C08L33/00C08K5/3412C08K5/29C08K3/30C08K3/26C08K3/22C08K3/34
Inventor 张娟娟张建龙
Owner SUNNY GENERAL INT
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