Method for preparing synthetic gas from C1 chemical fuel in multivariate conjugation manner

A synthesis gas and multi-component technology, applied in the direction of granular/powdered fuel gasification, gasification process, and production of combustible gas, can solve the problems of complex structure, waste of coal resources, shortage, etc., and achieve the effect of improving the conversion rate

Active Publication Date: 2019-03-19
THE NORTHWEST RES INST OF CHEM IND
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  • Claims
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Problems solved by technology

As the three major non-renewable fossil energy sources, kerosene and gas play an important role in safeguarding the national economy, national defense industry and national defense security. Oil and gas resources flow in the body of the national economy like blood due to their excellent physical and chemical properties. The characteristics of the first operation have led to rapid and high consumption of oil and gas resources and even serious shortages, which directly affect the healthy operation of the national economy. Therefore, in recent years, industry personnel have put forward two innovative scientific propositions of coal-to-gas and coal-to-oil Putting it into industrialized operation has greatly alleviated the contradiction between energy supply and demand caused by the shortage of oil and gas resources. However, due to the complex structure and different physical and chemical properties of coal resources, the mass transfer effect of useful components in the process of coal-to-gas-to-oil conversion is not good, resulting in The waste of coal resources is serious. In response to this secondary problem caused by it, scientific researchers have devoted themselves to research, put forward new ideas one after another, and developed targeted new technologies one after another, in order to solve the technical problem of maximizing and effectively utilizing coal resources.

Method used

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  • Method for preparing synthetic gas from C1 chemical fuel in multivariate conjugation manner
  • Method for preparing synthetic gas from C1 chemical fuel in multivariate conjugation manner
  • Method for preparing synthetic gas from C1 chemical fuel in multivariate conjugation manner

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0055] This embodiment includes the following steps:

[0056] Step 1. Embed the oven burner 11 in the gaseous fuel nozzle 6 installed on the top of the gasifier 1, and then use gaseous methanol as fuel to bake the oven until the gasifier 1 is preheated to above 1000°C;

[0057] Step 2: Disassemble the oven burner 11 from the gaseous fuel nozzle 6, and make the first oxidant pipeline 14-1, the gaseous fuel pipeline 12 and the second oxidant pipeline 14-2 coaxial from the inside to the outside in sequence according to the sleeve method Assembled in the gaseous fuel nozzle 6, then pass the carbon-gaseous fuel into the gasification furnace 1 through the gaseous fuel pipeline 12, and simultaneously pass the carbon-solid fuel and oxidant through the slurry nozzle 7 located above the gasification furnace 1 side In the gasifier 1, after carbon-gaseous fuel and high-concentration slurry enter the gasification section 2 of the gasifier 1, the oxidant is passed into the gasifier through ...

Embodiment 2

[0076] The difference between this embodiment and Example 1 is that in step one, natural gas is used as raw material for oven; the carbon-solid fuel used in step two is Inner Mongolia coal, and the carbon-gaseous fuel is CH 4 Natural gas with a content of 96.63%, the physical parameters of carbon-solid fuel and carbon-gaseous fuel are shown in Table 6 and Table 7 below, the oxidant is oxygen with a volume purity of 99.6%, and the reaction distribution parameters of the oxidant are shown in Table 8 below. Carbon- The furnace parameters of the water-based slurry made from solid fuel grinding are shown in Table 9 below. The temperature of the multi-component conjugation reaction is 1250° C., and the pressure is 1.0 MPa. The pressure of the multi-component conjugation reaction is gauge pressure (G) The dry gas volume composition of the crude syngas produced in step 3 is as shown in Table 10 below, and the carbon element content in the dry matter of the unreacted solid residue slag ...

Embodiment 3

[0089] The difference between this embodiment and Example 1 is that in step one, natural gas is used as a raw material for drying, the carbon-solid fuel used in step two is Xinjiang coal, and the carbon-gaseous fuel is natural gas with a CH4 content of 96.63%. The physical parameters of the solid fuel and the carbon-gaseous fuel are shown in Table 11 and Table 12 respectively. The oxidant is oxygen with a volume purity of 99.6%. The reaction distribution parameters of the oxidant are shown in Table 13. The furnace parameters of the base slurry are shown in Table 14 below. The pressure of the multi-component conjugation reaction is 9.0 MPa, and the temperature is 1350 ° C. The pressure of the multi-component conjugation reaction is gauge pressure (G); the crude The composition of the dry gas volume of the synthesis gas is shown in Table 15 below. The carbon element content in the dry mass of the unreacted solid residue slag discharged from the gasifier after heat exchange is 2.3...

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Abstract

The invention discloses a method for preparing synthetic gas from C1 chemical fuel in a multivariate conjugation manner. The method comprises the following steps: 1, baking in an oven; 2, introducingC1 gas-state fuel and C1 solid-state fuel slurry into a gasification furnace respectively to be mixed with an oxidant, and reacting to generate crude synthetic gas, wherein a reaction cavity is of a flat and long gourd shape, a relation between the diameter d of a fine neck part of the reaction cavity and the diameter D of the thickest part of a web part is as follows: d=0.382D, and the ratio of axial heights of upper and lower sections of chambers of the reaction cavity taking the fine neck part as the boundary is 1 to 3; and 3, quenching the crude synthetic gas and unreacted solid residues,and discharging the crude synthetic gas with overheated gas. According to the method disclosed by the invention, the reaction cavity of the gasification furnace and a spraying nozzle are designed andan actual reaction space of the reaction cavity of the gasification furnace is matched with a flow field for reaction of raw materials, so that C1 raw materials are mixed in the reaction cavity in a high-strength manner and are in sufficient contact; the mass transfer effect is improved, and the high-concentration crude synthetic gas taking CO and H2 as main raw materials is obtained; and the utilization efficiency of a C1 fuel resource is improved.

Description

technical field [0001] The invention belongs to the technical field of energy and chemical production, and in particular relates to a method for producing synthesis gas by reacting carbon-chemical fuels in a multiple-conjugation manner. Background technique [0002] The carbon-chemical industry is a chemical process that studies the synthesis of industrial products from substances containing one carbon atom. The substances with one carbon atom mainly include CO, CO 2 、CH 4 、CH 3 OH, HCHO, carbon-chemical fuel is a set of raw materials containing one carbon atom collected for the carbon-chemical industry. Gas-liquid-solid raw materials for producing synthesis gas. Because of its abundant reserves, wide distribution, and easy acquisition and transportation, coal will always be the leading role in the selection of raw materials in the field of energy and chemical production technology. As a non-renewable fossil energy, the solid utilization of coal resources is an innovatio...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10J3/48C10J3/50C10J3/82C10J3/72
CPCC10J3/48C10J3/50C10J3/72C10J3/82C10J2200/152C10J2300/0913
Inventor 徐红东朱春鹏杨云龙刘军赵蒙曾梅邹涛林益安徐宏伟贺根良韦孙昌
Owner THE NORTHWEST RES INST OF CHEM IND
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