70results about How to "Easy to phase" patented technology

The liquid-liquid-liquid three-phase continuous lifting and stirring extractor includes one horizontal reactor with two stuffing-holding isolating board cases in its two ends; one upper shaft and onelower shaft penetrating the reactor side walls and installed parallelly to the isolating board cases; upper baffle and lower baffle with horizontal arc lift tank in between; light phase outlet, middle phase inlet and heavy phase outlet successively arranged on one side wall of the reactor; light phase inlet, middle phase outlet and heavy phase inlet successively arranged on the opposite side wallof the reactor; and motor driven wheels installed in the ends of the two shafts. With simple structure, low power consumption, flexible operation, no emulsification and less back mixing, the presentinvention is suitable for separating and purifying high-value biochemical product from relevant fermented liquid.

The invention provides an aqueous two-phase extraction system formed by anion/cation mixed surfactant which is induced by fluoroalcohol, a preparation method and an application thereof. The aqueous two-phase extraction system comprises anion surfactant sodium dodecyl sulfate, cation surfactant hexadecyl trimethyl ammonium bromide, hexafluoroisopropanol and water. The extraction system has short phase forming time, wide phase forming range, gentle and simple phase forming condition, low consumption and high efficiency, so the extraction system is a novel extraction system. The invention can extract and separate different types of compounds through the phase forming conditions of the system, so the application prospect is good.

The invention discloses a process for preparing nuclear-grade hafnium oxide and zirconium oxide through solvent extractive separation of zirconium and hafnium. The process comprises the following steps: (1) mixing tributyl phosphate or tributyl phosphate and ionic liquid, which serve as extractants, and kerosene, which serves as a diluent, so as to prepare an organic phase; and then, mixing the organic phase with nitric acid, and carrying out countercurrent acidification in a centrifugal extractor; (2) adding zirconium oxychloride, which serves as a raw material, into deionized water, carryingout dissolving, and then, adding hydrochloric acid and nitric acid into the solution, so as to prepare a feed solution containing zirconium and hafnium; (3) carrying out countercurrent extraction onthe acidified organic phase and the feed solution containing zirconium and hafnium, prepared in the step (2), in a centrifugal extractor; (4) carrying out back-extraction on a zirconium-containing organic phase with water, then, carrying out hydrolysis, and carrying out calcination, so as to obtain nuclear-grade zirconium oxide; and (5) enriching hafnium-containing raffinate with P204, then, carrying out back-extraction, carrying out hydrolysis, and carrying out calcination, so as to obtain nuclear-grade hafnium oxide. According to the process, the problems, i.e., complicated process, much waste liquid and environmental pollution in the prior art are solved, and the production efficiency is increased.

The invention discloses a method for treating a chemical nickel plating concentrated waste liquid by a solvent extraction method and an ion exchange method. The method comprises adjusting a chemical nickel plating concentrated waste liquid concentration to 6-7 by NaOH, fully mixing the waste liquid subjected to pH adjustment and an extractant, carrying out standing for two phase layering, separating the two phases to obtain organic and water phases, wherein the water phase is a nickel-free solution and the organic phase is a loading organic phase, fully mixing sulfuric acid and the above organic phase, carrying out standing for two phase layering, separating the two phases to obtain a water phase and an organic phase, wherein the water phase is a nickel sulfate solution and the organic phase is an extractant, treating the nickel-free solution by an alkalescent anion exchange resin column to remove hypophosphite, carrying out cooling to precipitate sodium sulfate crystals, and adding nickel sulfate and hypophosphite into the sodium sulfate crystals to obtain a regenerated chemical nickel plating liquid for direct chemical nickel plating. The method has the advantages of high extraction efficiency, environmental friendliness, simple operation, low cost and high economic value.

The invention discloses an extraction device comprising an emulsifying machine (1) and a phase-splitting apparatus (2). The emulsifying machine (1) is provided with an emulsifying machine inlet (3) and an emulsifying machine outlet (4), the phase-splitting apparatus (2) is provided with a mixed phase inlet (5), a heavy phase outlet (6) and a light phase outlet (7), the emulsifying machine inlet (3) is connected with an extracted object inlet (8) and a solvent inlet (9), and the emulsifying machine outlet (4) is connected with the mixed phase inlet (5) of the phase-splitting apparatus. When multistage extraction devices are combined, the light phase outlet of the phase-splitting apparatus in the extraction device at the current level is connected with the solvent inlet of the extraction device at the next level through a pipeline provided with a pump, and the heavy phase outlet of the phase-splitting apparatus in the extraction device at the next level is connected with the extracted object inlet of the extraction device at the current level through the pipeline provided with the pump. The invention has high extraction efficiency, small size, less occupied area, simple operation and capability of saving apparatus investment and running cost.

The invention relates to the technical field of new ceramic materials, and particularly discloses a roller kiln low-temperature sintered colorful halo crystal glaze which comprises a ground glaze anda cover glaze, and the ground glaze comprises the following components in parts by weight: 80 to 90 parts of lead-zinc frit and 10 to 20 parts of pigment; the cover glaze is prepared from the following components in parts by weight: 50 to 70 parts of high-boron frit, 5 to 10 parts of titanium dioxide, 10 to 20 parts of zinc oxide, 5 to 15 parts of talc, 0 to 10 parts of calcite and 17 to 30 partsof seeding colorant, wherein the seeding colorant is prepared from manganese dioxide, vanadium pentoxide and copper oxide. The preparation method of the roller kiln low-temperature sintered colorful halo crystal glaze comprises the steps of preparing the ground glaze and cover glaze, glazing and sintering, wherein the highest sintering temperature is 1125 to 1135 DEG C, and the sintering period is190 to 210 min. The crystal glaze suitable for roller kiln low-temperature sintering is prepared, the glaze surface can show a circle of colorful halo under the sun, and the process effect of metal and crystal glaze is achieved.

The invention relates to an improvement of a method for preparing dimer acid and dimer acid methyl ester by using unsaturated fatty acid and corresponding fatty acid methyl ester thereof, which is characterized in that a catalyst for reaction is sulfonate ionic liquid which contains SO3H functional groups and accounts for not less than 0.5% in parts by weight, the reaction is carried out at the temperature of 150-300 DEG C, the iodine value of products are controlled to be 65-80%, and the products and the catalyst are stratified by standing after the reaction is complete. The method has the advantages of high polymerization reaction activity, fast reaction speed and relatively mild reaction conditions, and the reaction can be carried out at atmospheric pressure and relatively low temperature, thereby not only reducing the reaction energy consumption and having low requirements on equipment, but also greatly reducing the preparation cost. The catalyst has good stability and small usingquantity, only 0.5% by weight of the catalyst can carry out full reaction, the catalyst is difficult to hydrolyze and easy to realize the phase separation with the products, the catalyst can be separated from the products only through ordinary standing or centrifugation without entrainment of the products, the catalyst can be repeatedly recycled, and the production process is environment-friendly.

The invention discloses an extraction and boron removal method for lithium-containing brine. The extraction and boron removal method comprises the following steps that 1, acidification is performed, wherein the pH value of a lithium chloride water solution containing boron is acidized to 1-3 by using hydrochloric acid; 2, mixing and extraction are performed, wherein isooctyl alcohol and 2-octanol are mixed according to the ratio of 10-18 to 1 to obtain an octanol mixed solution; the octanol mixed solution is mixed with kerosene to prepare a mixed extracting agent, the kerosene accounts for 30-70% of the total volume of the mixed extracting agent, and standing is performed for 1-3 hours after the acidized lithium chloride water solution containing boron and the mixed extracting agent are fully mixed; 3, phase splitting is performed, wherein a mixed liquid phase of the lithium chloride water solution containing boron and the mixed extracting agent is divided into an oil phase and a first water phase after standing; 4, recovery is performed, wherein the first water phase is guided out, the boron content is detected, the first water phase is re-guided back to the step 2 under the situation that the boron content exceeds the standard and serves as lithium chloride water containing boron to perform extraction, the operation is repeated till the boron content of the water phase is up to the standard. The lithium-containing brine can be extracted in a low-cost and efficient mode, treated waste water can be secondarily utilized, and environmental pollution can be reduced.

The invention discloses an extractive organic phase and application thereof. The extractive organic phase comprises a diluting agent, a modifying agent and a compound expressed as a formula (I); the concentration of the compound expressed as the formula (I) (as described in the description) in the extractive organic phase is 0.05-2 mol/L; and the concentration of the modifying agent in the extractive organic phase is 0.05-2 mol/L. The application can comprise the following steps: the extractive organic phase is used for extracting water phase extractives containing lithium ions; and the layering is performed to collect organic phases. The extractive organic phase and the extracting method for extracting lithium have the advantages of high extracting efficiency of the lithium ions, easy phase separation and convenient operation method, meanwhile, achieve excellent lithium-sodium and lithium-potassium separation coefficients, and can realize high-selectivity separation of lithium from other alkali metal.

The invention relates to the technical field of ceramic preparation, and concretely relates to a dark green transmutation glaze ceramic product and a preparation method thereof. The dark green transmutation glaze ceramic product is prepared from, by weight, 64-72 parts of kaolin, 40-45 parts of glass powder, 6-10 parts of talc, 10-12 parts of quartz, 4-9 parts of calcium carbonate, 3-5 parts of ferric oxide, 3-8 parts of copper oxide, 1-3 parts of chrome green and 1-2 parts of phosphorus pentoxide. The preparation method comprises the following steps: S1, glaze preparation; S2, slurry preparation; S3, glazing; and S4, sintering. The ceramic product has the characteristics of bright color, uniform and clear texture, wear resistance and scratch resistance.

The invention provides a method for separating uranium, molybdenum and iron from a vanadium extraction agent by utilizing organic phase regeneration. (2) filter the regeneration solution to obtain uranium-containing, iron-containing precipitates and molybdenum-containing solutions; (3) adopt Na CO to the gained uranium-containing and iron-containing precipitates for leaching of solution, filter to obtain uranium-containing Na CO leaching solution and iron slag, and transfer the leaching solution and iron slag to the uranium-containing and iron-containing precipitates. NaOH was added to the Na2CO3 leaching solution of uranium, and Na2U2O7 was prepared by NaOH alkaline uranium precipitation process; for the obtained molybdenum-containing solution, when the molybdenum concentration was greater than 30g/L~40g/L, it was evaporated to dryness and then calcined; the calcined product was leached with NaOH Take, add sulfuric acid to the obtained molybdenum solution, and pyrolyze molybdic acid to prepare molybdenum trioxide. The method effectively regenerates the organic phase, avoids the reduction of the capacity of the extractant due to the accumulation of uranium, molybdenum and iron in the organic phase, recovers the uranium and molybdenum and obtains qualified products, and comprehensively recycles the resources. .

The invention discloses a stripping device which comprises an emulsifying machine (1) and phase splitting equipment (2), wherein an emulsifying machine inlet (3) and an emulsifying machine outlet (4) are arranged on the emulsifying machine (1), a mixed-phase inlet (5), a heavy-phase outlet (6) and a light-phase outlet (7) are arranged on the phase splitting equipment (2), the emulsifying machine inlet (3) is connected with a stripping agent inlet (8) and a solvent inlet (9), and the emulsifying machine outlet (4) is connected with the mixed-phase inlet (5) of the phase splitting equipment. When multiple stages of stripping devices are combined, the light-phase outlet of the phase splitting equipment in the stage of stripping device is connected with the solvent inlet in the next stage of stripping device through a pipeline provided with a pump; and the heavy-phase outlet of the phase splitting equipment in the next stage of stripping device is connected with the stripping agent inlet in the stage of stripping device through the pipeline provided with the pump. The invention can strengthen the mass transfer performance, improve the stripping efficiency and lower the stripping equipment investment and the operating cost.

The invention discloses an energy converter to launch two different frequency sound sources, which comprises the following parts: broad-band energy converter, controller, feeding power, D-type power amplifier, waveshape data list storage and address generator, wherein the controller coordinates each part to work simultaneously, which controls the pulse breadth and repeating times per second of sound signal and outputs the order to the address generator and D-type power amplifier; the address generator outputs the data address to the waveshape data list storage, which outputs the data to the D-type power amplifier; the D-type power amplifier connects the broad-band energy converter, which supplies enough power to drive the electric power; the broad-band energy converter transmits the electric power into sound power to launch out.

The invention relates to a method for extracting copper from chrysocolla type copper oxide ores through a wet process, and belongs to the field of non-ferrous metal hydrometallurgy. The method comprises the following technological steps: 1) curing ores by adding sulfuric acid and performing desiliconization; 2) performing heaping and dipping to leach copper; 3) precipitating silicon in leaching feed liquid by utilizing ox glue; and 4) continuously inhibiting the volume of interphase dirt by selecting an organic phase component and a controlled phase. According to the method disclosed by the invention, after the chrysocolla type copper oxide ores are subjected to acid mixing, curing and desiliconization and the silicon of the leaching copper-containing feed liquid is precipitated by using the ox glue, the situation that the copper-containing feed liquid SiO2 is less than 500mg/L can be maintained, an extraction requirement is met, and the leaching time of the ores can be shortened; an extracting agent adopts M5640 and a diluent adopts SX-80, and extraction and back extraction are continuously carried out by adopting an organic phase, so that the emulsification volume and the compression volume of the interphase dirt can be reduced, and therefore, the chrysocolla type copper oxide ores can realize industrial application.

The invention provides film scratching type rotary micro-channel enhanced extraction equipment and application thereof. The extraction equipment comprises an inner barrel and an outer barrel which sleeves the outer part of the inner barrel, wherein a gap between the inner barrel and the outer barrel is 0.15 to 0.35mm; a plurality of vertical strips are engraved on an inner wall of the inner barrel; the top of the inner barrel is connected with a rotary shaft; the rotary shaft is connected with a motor; and the outer barrel is provided with an upper feeding opening, a lower feeding opening anda discharging opening. The equipment is applied to an enhancement method of solvent extraction; the enhancement method comprises the following steps: conveying a solution to be extracted and an extracting agent into the gap between the inner barrel and the outer barrel through the upper feeding opening and the lower feeding opening respectively under the pushing of an injection pump at the same time; and after the gap between the inner barrel and the outer barrel is fully filled with liquid, a motor is started and the inner barrel is rotated, so that a two-phase flow is formed in the gap and the two-phase flow is discharged from the discharging opening through movement. By adopting the film scratching type rotary micro-channel enhanced extraction equipment, the time that extraction is balanced can be greatly shortened and the extraction energy consumption is reduced.