Fluorescent glass, preparation method thereof and light emitting device
A fluorescent glass and glass technology, applied in the field of fluorescent materials, can solve the problems of heat resistance, poor anti-aging performance, carbonization and yellowing of encapsulation glue, affecting the luminous efficiency and service life of LED devices, etc., to achieve good aging resistance and use Long life and high luminous efficiency
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Embodiment 1
[0018] A kind of fluorescent glass, its raw material comprises glass substrate and fluorescent powder, and fluorescent powder is Lu 3 Al 5 o 12 : Ce 3+ and CaAlSiN 3 : a combination of Eu; the components of the glass matrix include: aluminum oxide, silicon oxide, boron oxide, flux, magnesium oxide, zinc oxide, calcium oxide and lead oxide, and the flux is specifically selected from sodium oxide and potassium oxide; and aluminum oxide, The molar ratio of silicon oxide, boron oxide, sodium oxide, potassium oxide, magnesium oxide, zinc oxide, calcium oxide and lead oxide is 0.2:2.2:0.5:0.3:0.05:0.03:0.2:0.3:0.2.
[0019] The specific preparation method includes the following steps: taking each component of the glass matrix according to the above molar ratio, taking the glass matrix, phosphor powder Y 3 Al 5 o 12 : Ce 3+ and CaAlSiN 3 : Eu, mix the raw materials for 48 hours to fully mix the raw materials; then put them into a clean crucible container, heat to about 1000 °...
Embodiment 2
[0027] The difference between this embodiment and embodiment 1 is that the fluorescent powder is Y 3 Al 5 o 12 : Ce 3+ and K 3 SiF 6 :Mn 4+ The composition of the glass matrix is: aluminum oxide, silicon oxide, boron oxide, sodium oxide, potassium oxide, magnesium oxide, zinc oxide, calcium oxide and lead oxide in a molar ratio of 0.1:2.5:0.6:0.2:0.02: 0.01:0.25:0.23:0.1; the specific preparation method is the same as in Example 1.
Embodiment 3
[0029] The difference between this embodiment and embodiment 1 is: the phosphor is (CaSrBa) 2 SiO 4 ;The composition of the glass matrix is: aluminum oxide, silicon oxide, boron oxide, sodium oxide, potassium oxide, magnesium oxide, zinc oxide, calcium oxide and lead oxide in a molar ratio of 0.3:2:0.2:0.1:0.07:0.05: 0.3:0.2:0.15; the specific preparation method is the same as in Example 1.
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