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Method for jointly gasifying coal and heavy oil for preparing synthesis gas

A synthesis gas and co-gasification technology, applied in chemical instruments and methods, gasification process, granular/powdered fuel gasification, etc., can solve the problems of energy consumption and production cost reduction, large raw material consumption, synthesis gas output and energy efficiency Increased utilization etc.

Active Publication Date: 2019-04-05
THE NORTHWEST RES INST OF CHEM IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The technical problem to be solved by the present invention is to provide a method for producing synthesis gas by co-gasification of coal and heavy oil, which has simple steps, reasonable design, convenient implementation, good use effect, and effective synthesis gas. Increased output and energy efficiency utilization rate, reduced energy consumption and production cost, not only solved the problem of high-efficiency and economical utilization of heavy oil, but also solved the problem of large raw material consumption of pure coal gasification to produce syngas, with strong practicability

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  • Method for jointly gasifying coal and heavy oil for preparing synthesis gas
  • Method for jointly gasifying coal and heavy oil for preparing synthesis gas
  • Method for jointly gasifying coal and heavy oil for preparing synthesis gas

Examples

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Embodiment 1

[0082] Step 1. Storage and transportation of heavy oil and preparation and transportation of coal slurry

[0083] The heavy oil from the Weiqiang coal and residual oil cracking olefins plant is sent to the heavy oil storage tank 1 for storage, and the heavy oil in the heavy oil storage tank is then pressurized to 1.5MPa by the high-pressure heavy oil pump 2, and sent to the gasifier through the heavy oil pipeline 4 The outer material channel 37 in the four-channel nozzle 13 at the top;

[0084] In this embodiment, the high-pressure heavy oil pump 2 is a piston-type diaphragm pump, such as a product sold by Shanghai Huishang Engineering Equipment Co., Ltd. under the trade name of Feluwa pumpen.

[0085] Weiqiang bituminous coal is crushed to obtain coal particles with a particle size of ≤20mm, and the coal particles, water, sodium hydroxide, and sodium lignosulfonate are respectively sent to the mill 5 for mixing and grinding to obtain coal slurry, and The coal slurry is sent ...

Embodiment 2

[0149] In this embodiment, the difference from Example 1 is that the mass percentages of coal particles, water, dispersant and pH regulator in the coal slurry are respectively: 59% of coal particles, 40.66% of water, 0.3% of dispersant, and PH Regulator 0.04%, the dispersant is calcium lignosulfonate, and the raw coal is gas coal.

[0150] In step 1, the heavy oil is pressurized to 7.0 MPa by the high-pressure heavy oil pump 2, and is sent to the central material channel 35 in the four-channel nozzle 13 on the top of the gasifier through the heavy oil pipeline 4; the coal slurry is pressurized by the high-pressure coal slurry pump 7 to 7.0 MPa is sent into the outer material channel 37 in the four-channel nozzle 13 .

[0151] In step 2, coal slurry, heavy oil and oxygen are subjected to partial oxidation reaction at a temperature of 1320° C. and a pressure of 4.0 MPa; the temperature of the heavy oil is maintained at 70° C.

[0152] In the present embodiment, further, the den...

Embodiment 3

[0157] In this embodiment, the difference from Example 1 is that the mass percentages of coal particles, water, dispersant and pH regulator in the coal slurry are respectively: 64% of coal particles, 35.5% of water, 0.45% of dispersant, and PH Regulator 0.05%, the dispersant is naphthalenesulfonic acid sodium salt formaldehyde condensate, and the raw coal is long-flame coal.

[0158] In step 1, the heavy oil is pressurized to 9.5MPa by the high-pressure heavy oil pump 2, and is sent to the central material channel 35 in the four-channel nozzle 13 on the top of the gasifier through the heavy oil pipeline 4; the coal slurry is pressurized by the high-pressure coal slurry pump 7 to 9.5 MPa is sent into the outer material channel 37 in the four-channel nozzle 13 .

[0159] In step 2, coal slurry, heavy oil and oxygen are subjected to partial oxidation reaction at a temperature of 1350° C. and a pressure of 6.5 MPa; the temperature of the heavy oil is maintained at 80° C.

[0160]...

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Abstract

The invention discloses a method for jointly gasifying coal and heavy oil for preparing synthesis gas. The method includes steps of firstly, storing and delivering the heavy oil and preparing and delivering coal slurry; secondly, gasifying the coal and the heavy oil at the high temperatures; thirdly, cooling high-temperature crude synthesis gas and molten ash residues; fourthly, purifying the crude synthesis gas; fifthly, collecting and discharging crude residues; sixthly, treating ash water. The method has the advantages that the method includes the simple steps and is reasonable in design and convenient to implement, and good use effects can be realized; reaction is carried out on the heavy oil and the coal slurry in a gasification reactor for preparing the synthesis gas, accordingly, the effective synthesis gas yield and the utilization rate can be increased, the energy efficiency can be improved, and energy consumption and the production cost can be reduced; the heavy oil can be efficiently and economically utilized, the problem of high raw material consumption due to the fact that existing synthesis gas is prepared from pure coal by means of gasification can be solved by the aid of the method, and the method is high in practicality.

Description

technical field [0001] The invention belongs to the technical field of co-gasification of coal and heavy oil to produce synthesis gas, in particular to a method for co-gasification of coal and heavy oil to produce synthesis gas. Background technique [0002] my country's oil resources are relatively scarce, and the content of heavy oil components is high, so the deep processing and efficient utilization of oil resources have become a major issue in the development of oil refining and petrochemical industries. In the process of crude oil deep processing, the residual oil produced by distillation of crude oil accounts for more than 1 / 3 of the crude oil, and the residual oil must be further processed to produce oil products and chemicals. When residual oil is catalytically cracked to produce olefins, the by-product of cracked heavy oil is mostly sold as a product by enterprises. Due to the high consumption tax of heavy oil, the by-product of cracked heavy oil has been in a stat...

Claims

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Application Information

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IPC IPC(8): C10J3/50C10J3/52C10J3/72C10J3/84C02F9/10C10J3/46C10J3/48C02F103/18
CPCC02F1/001C02F1/04C02F1/06C02F1/5281C02F9/00C02F2001/007C02F2103/18C10J3/46C10J3/48C10J3/50C10J3/52C10J3/723C10J3/84C10J2300/0906C10J2300/0913C10J2300/0936C10J2300/0959C10J2300/0983C10J2300/1615C10J2300/1628Y02P20/10
Inventor 徐宏伟郑亚兰韦孙昌门长贵罗进成林益安朱春鹏袁善录贺根良王晓娟戴爱军杨云龙杜彦学曹德全吕春成孙晓伟陈昱郗小明王军龙柳春张明
Owner THE NORTHWEST RES INST OF CHEM IND
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