Porous substrate-based flexible exhaled ammonia gas sensor and preparation method thereof
An ammonia gas sensor and substrate technology, which is applied in the direction of instruments, scientific instruments, measuring devices, etc., can solve the problems of wearable ammonia gas sensors such as difficulty, poor sensitivity, poor air permeability and softness, etc., to improve wearability, Low production cost and improved air permeability
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preparation example Construction
[0045] A preparation method of an exhaled ammonia sensor as claimed in claim 1, comprising the steps of:
[0046] Step 1: cleaning the porous flexible sheet substrate or fibrous substrate;
[0047] Step 2: performing oxygen plasma treatment on the porous flexible sheet substrate or fibrous substrate;
[0048] Step 3: Deposit a highly moisture-resistant sensitive film on a porous flexible sheet substrate or a fibrous substrate by in-situ chemical polymerization or suction filtration, soaking, spraying sensitive material dispersion or a combination of the two methods ;
[0049] Step 4: cutting the sheet substrate with the sensitive film deposited or weaving the fibrous substrate with the sensitive film deposited;
[0050] Step 5: Prepare electrodes on both sides of the sensitive film by evaporation or printing or spraying process.
[0051] If the porous flexible sheet substrate in step 1 uses a microporous filter membrane or a battery separator, use deionized water to ultraso...
Embodiment 1
[0057] A flexible exhaled ammonia sensor based on a porous substrate, including a substrate 1, a sensitive film 2 covering the substrate 1, and electrodes 3 arranged on both sides of the sensitive film 2, and the substrate 1 is in the form of a porous flexible organic sheet material or fibrous material, the sensitive film 2 is a flexible ammonia sensitive film with strong moisture resistance; the substrate 1 is a water-based microporous filter membrane made of polyethersulfone; the sensitive film 2 is made of a conductive organic polymer material, and the material is polyaniline PANI; Electrode 3 is made of conductive silver paste.
[0058] The preparation method is as follows:
[0059] A water-based microporous filter membrane with a diameter of 50 mm and a pore size of 0.2 μm, made of polyethersulfone, was used as the substrate; first, the substrate was ultrasonically cleaned with deionized water, and dried in a vacuum oven at 60 °C . Secondly, the substrate is treated wit...
Embodiment 2
[0063] Compared with Example 1, this example differs in that: before preparing the hydrochloric acid-doped polyaniline film, a layer of WS was prepared on the substrate by vacuum filtration. 2 film. The specific method is as follows, configure 0.2mg / ml small-diameter few-layer WS 2 Solution 10ml (sheet size: 20-500nm; layer number: 1-10 layers), and then prepare WS on the microporous membrane by vacuum filtration 2 film. Subsequently, according to the method in Example 1 in WS 2 Polyaniline film was prepared on the film. Finally, cut the substrate, prepare the electrode, and obtain the polyaniline / WS 2 Composite film flexible and breathable breath ammonia sensor;
[0064] Graphene-like materials and conductive organic polymer materials are used for compounding. Due to the synergistic effect, the sensitivity of the sensor in high-humidity environments is improved. Graphene-like materials can also be made of molybdenum disulfide MoS 2 Or tungsten diselenide WSe 2 Or molyb...
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