Formula for novel auxiliary agent capable of improving TPV
A technology of additives and formulations, applied in the field of TPV, can solve the problems of difficult processing and modulus, poor compression deformation resistance, and poor compression deformation resistance of TPV, and achieve good flame retardant effect, easy adsorption, and enhanced flame retardant effect. Effect
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[0038] During the preparation of chitosan antibacterial microspheres, Span 80 was added. This non-ionic surfactant was dispersed in paraffin oil to form latex bundles, and chitosan and glutaraldehyde reacted in the latex bundles to form Spherical cross-linked chitosan matrix, the ZnO nanoparticles and polyhexamethylene monoguanidine hydrochloride in the system are coated in the formed matrix; at the same time, the hydroxyl and amino groups on the chitosan molecular chain and the hydroxyl groups on the ZnO surface Hydrogen bonds are formed between them to form chitosan antibacterial microspheres with a particle size of 2-10um; the antibacterial particles have a large specific surface area and surface energy, making it easier to adsorb on the surface of bacterial cells and directly contact the bacterial cell wall And affect its permeability, indirectly increase the contact area between chitosan antibacterial microspheres and bacteria, and then doped nano-ZnO particles and polyhex...
Embodiment 1
[0044] The new additive formula for improving TPV includes the following raw materials in parts by weight: 60 parts of EPDM rubber, 14 parts of ethylene-vinyl acetate copolymer, 11 parts of polyethylene, 10 parts of chlorinated polyvinyl chloride, 7 parts of polypropylene, 5 parts of chitosan antibacterial microspheres, 1 part of flame retardant, 2 parts of bis-tert-butylperoxycumene (BIPB), 0.3 parts of sulfur, 0.5 parts of naphthenic oil, 2-hydroxy-4-methoxy 0.2 parts of benzophenone, 0.3 parts of PE wax;
[0045] The flame retardant is obtained by compounding melamine salt of 2-carboxyethyl (phenyl) phosphinic acid and antimony trioxide in a mass ratio of 6:1.
Embodiment 2
[0047] The new additive formula for improving TPV includes the following raw materials in parts by weight: 65 parts of EPDM rubber, 15 parts of ethylene-vinyl acetate copolymer, 12 parts of polyethylene, 11 parts of chlorinated polyvinyl chloride, 8 parts of polypropylene, 6 parts of chitosan antibacterial microspheres, 1.5 parts of flame retardant, 2.5 parts of dicumyl peroxide (DCP), 0.4 parts of sulfur, 0.8 parts of naphthenic oil, 2,2'-dihydroxy-4-methoxy 0.3 part of benzophenone, 0.4 part of stearic acid;
[0048] The flame retardant is obtained by compounding 2-carboxyethyl (phenyl) phosphinic acid melamine salt and antimony trioxide in a mass ratio of 6.5:1.
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