A preparation method of pim-1@mofs/polymer composite pervaporation membrane
A PIM-1, pervaporation membrane technology, applied in the field of preparation of PIM-1@MOFs/polymer composite pervaporation membrane, can solve the problems of limited application, not MOF agglomeration, etc., achieve increased separation performance, simple preparation method, The effect of increasing hydrophobic properties
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
example 1
[0028](1) Weigh 0.75g of zinc nitrate hexahydrate and 1.65g of 2-methylimidazole and dissolve them in 35mL of methanol respectively, and ultrasonicate for 30min; quickly pour the resulting solution into a 100mL polytetrafluoroethylene reactor, and react at 150°C for 5h, Then cool to room temperature, centrifuge, wash off the white solid surface obtained by the reaction with methanol, which is the ligand of the reaction, wash it three times, centrifuge, and then stir it in methanol at 80°C for 12h, and replace it every 4 hours Methanol was separated by centrifugation, and the resulting solid was vacuum-dried at 80°C for 24 hours.
[0029] (2) Weigh 0.15g of PIM-1 and dissolve it in 5mL of chloroform, and ultrasonicate for 1 hour; weigh 0.0382g of the solid obtained in step 1 and soak in the above solution for 10min, centrifuge to separate ZIF-8, and dry it at room temperature. Wash the soaked ZIF-8 with chloroform for 3 times, then wash with methanol for 3 times, and dry it for...
example 2
[0033] (1) Weigh 0.75g of zinc nitrate hexahydrate and 1.65g of 2-methylimidazole and dissolve them in 35mL of methanol respectively, and ultrasonicate for 30min; quickly pour the resulting solution into a 100mL polytetrafluoroethylene reactor, and react at 150°C for 5h, Then cool to room temperature, centrifuge, wash off the white solid surface obtained by the reaction with methanol, which is the ligand of the reaction, wash it three times, centrifuge, and then stir it in methanol at 80°C for 12h, and replace it every 4 hours Methanol was separated by centrifugation, and the resulting solid was vacuum-dried at 80°C for 24 hours.
[0034] (2) Weigh 0.15g of PIM-1 and dissolve it in 5mL of chloroform, and ultrasonicate for 1 hour; weigh 0.0764g of the solid obtained in step 1 and soak in the above solution for 10min, centrifuge to separate ZIF-8, and dry it at room temperature. Wash the soaked ZIF-8 with chloroform for 3 times, then wash with methanol for 3 times, and dry it fo...
example 3
[0038] (1) Weigh 0.75g of zinc nitrate hexahydrate and 1.65g of 2-methylimidazole and dissolve them in 35mL of methanol respectively, and ultrasonicate for 30min; quickly pour the resulting solution into a 100mL polytetrafluoroethylene reactor, and react at 150°C for 5h, Then cool to room temperature, centrifuge, wash off the white solid surface obtained by the reaction with methanol, which is the ligand of the reaction, wash it three times, centrifuge, and then stir it in methanol at 80°C for 12h, and replace it every 4 hours Methanol was separated by centrifugation, and the resulting solid was vacuum-dried at 80°C for 24 hours.
[0039] (2) Weigh 0.15g of PIM-1 and dissolve it in 5mL of chloroform, and ultrasonicate for 1 hour; weigh 0.0115g of the solid obtained in step 1 and soak in the above solution for 10min, centrifuge to separate ZIF-8, and dry it at room temperature. Wash the soaked ZIF-8 with chloroform for 3 times, then wash with methanol for 3 times, and dry it fo...
PUM
| Property | Measurement | Unit |
|---|---|---|
| pore size | aaaaa | aaaaa |
| diameter | aaaaa | aaaaa |
| pore size | aaaaa | aaaaa |
Abstract
Description
Claims
Application Information
Login to View More