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Humic acid and urea-formaldehyde sustained-release chelated fertilizer, and preparation method and application thereof

A humic acid urea-formaldehyde and humic acid technology, applied in the field of agricultural fertilizers, can solve problems such as inapplicability and harsh conditions, and achieve the effects of improving compressive strength, anti-pulverization ability, good viscosity and increasing crop yield.

Inactive Publication Date: 2019-10-29
吉林澳佳农业科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the conditions are relatively harsh, and it is not suitable for the steam drum granulation and ammonia drum granulation equipment commonly used in compound fertilizer enterprises.

Method used

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  • Humic acid and urea-formaldehyde sustained-release chelated fertilizer, and preparation method and application thereof
  • Humic acid and urea-formaldehyde sustained-release chelated fertilizer, and preparation method and application thereof
  • Humic acid and urea-formaldehyde sustained-release chelated fertilizer, and preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0040] Present embodiment provides a kind of humic acid urea-formaldehyde slow-release fertilizer, and its formula is as follows:

[0041] Humic acid urea formaldehyde slurry 500kg, urea 2120kg, ammonium chloride 200kg, monoammonium phosphate 3409kg, potassium chloride 2483kg, superfine weathered coal 600kg, calcium magnesium phosphate fertilizer 200kg, attapulgite powder 488kg.

[0042] Wherein the preparation method of humic acid urea formaldehyde slurry is as follows:

[0043] Taking 1000 kg of feeding each time as an example, add 900 kg of water to the reactor, add 18 kg of potassium hydroxide under continuous stirring, raise the temperature to 70-80°C, and then add 100 kg of lignite (pre-crushed 80-100 mesh), keep The temperature is 80°C, the reaction time is 2.5 hours, the obtained slurry is left to stand for 24 hours, and the supernatant is taken, which is the humic acid-base extract;

[0044]Taking each production of 1000 kg as an example, add 320 kg of 37% formaldehy...

Embodiment 2

[0046] This embodiment provides a kind of humic acid urea-formaldehyde slow-release fertilizer and preparation method thereof:

[0047] Specific steps are as follows:

[0048] 1) Preparation of humic acid-alkaline extract: taking 1000 kg of feeding each time as an example, add 900 kg of water into the reaction kettle, add 18 kg of potassium hydroxide under continuous stirring, raise the temperature to 70-80 °C, and then add lignite (pre-crushed 80-100 mesh) 100 kg, keep the temperature at 80° C., and the reaction time is 2.5 hours. The obtained slurry is left to stand for 24 hours, and the supernatant is taken, which is the humic acid-base extract.

[0049] 2) Preparation of humic acid urea-formaldehyde slurry: taking 1000 kg per production as an example, add 320 kg of 37% formaldehyde (industrial grade) to the reaction kettle, add 240 kg of the first batch of urea under continuous stirring, and heat up to 50°C. React for 20-30 minutes, add the second batch of urea 240 kg, th...

Embodiment 3

[0054] Present embodiment provides a kind of humic acid urea-formaldehyde slow-release fertilizer, and its formula is as follows:

[0055] Humic acid urea formaldehyde slurry 400kg, urea 5043kg, monoammonium phosphate 1818kg, potassium chloride 1987kg, superfine weathered coal 400kg, calcium magnesium phosphate fertilizer 150kg, attapulgite powder 202kg.

[0056] Wherein, the preparation method of described humic acid urea formaldehyde slurry is as follows:

[0057] Taking 1000 kg of feeding each time as an example, add 900 kg of water to the reactor, add 18 kg of potassium hydroxide under continuous stirring, raise the temperature to 70-80°C, and then add 100 kg of lignite (pre-crushed 80-100 mesh), keep The temperature is 80°C, the reaction time is 2.5 hours, the obtained slurry is left standing for 24 hours, and the supernatant is taken, which is the humic acid-base extract.

[0058] Taking each production of 1000 kg as an example, add 343 kg of 37% formaldehyde (industria...

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Abstract

The invention relates to the field of agricultural fertilizers, specifically to a humic acid and urea-formaldehyde sustained-release chelated fertilizer and a preparation method. The sustained-releasechelated fertilizer comprises a humic acid and urea-formaldehyde slurry which is prepared from urea, formaldehyde and a humic acid alkali extract, wherein the molar ratio of the urea to the formaldehyde is (1.5-2.0): 1. According to the invention, through the humic acid and urea-formaldehyde slurry, the speed of a urea-formaldehyde condensation reaction can be effectively delayed, and slurry stability and low free formaldehyde content can be maintained for a long period of time; meanwhile, after the humic acid and urea-formaldehyde slurry and basic fertilizers like nitrogen, phosphorus and potassium are mixed and granulated, the urea-formaldehyde condensation reaction is accelerated to form a long-chain molecule, so good viscosity is achieved; a more stable particle structure skeleton canbe easily formed; and compressive strength and powdering resistance of a fertilizer are improved. The humic acid and urea-formaldehyde sustained-release chelated fertilizer provided by the inventionis applied in agriculture, contains nitrogen nutrients with cold-water insolubility, has the function of sustained release, and can significantly increase the yield of crops.

Description

technical field [0001] The invention relates to the field of agricultural fertilizers, in particular to a humic acid urea-formaldehyde slow-release chelated fertilizer and a preparation method thereof. Background technique [0002] Humic acid is the remains of animals and plants, mainly plant remains, a type of natural macromolecular organic polymer with complex structure containing active groups such as carboxyl and phenolic hydroxyl groups, which is caused and accumulated through microbial decomposition and transformation, as well as a series of geochemical processes. . [0003] In terms of agricultural applications, humic acid has the functions of improving soil, synergizing fertilizers, stimulating crop growth, enhancing crop resistance, and improving the quality of agricultural products. In recent years, humic acid, as an important product of biostimulants, has been researched and applied in maintaining the balance of plant auxins, inducing plants to enhance their resi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C05G3/04C05G3/08C05G3/80C05G3/90
CPCC05B7/00A01G22/22A01G22/20A01G22/35C05G3/90C05G3/80
Inventor 冯广祥赵红光乔新健田原宇乔生
Owner 吉林澳佳农业科技有限公司