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Cadmium sulfide quantum dot loaded carbon fibers prepared by utilizing waste cigarette ends, and preparation method and application of cadmium sulfide quantum dot loaded carbon fibers

A carbon fiber and cadmium sulfide technology, applied in the field of carbon fiber loaded with cadmium sulfide particles and its preparation, can solve the problems of photogenerated electron-hole instability, reducing the photo-generated electron-hole pair recombination rate, shortening the carrier migration path, etc. , to achieve the effect of improving life, improving performance, simple equipment and preparation process

Inactive Publication Date: 2019-11-15
GUANGDONG UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, the photogenerated electron-hole pairs, which play a key role in the photocatalysis process, are unstable and easy to recombine, which also limits the photocatalytic effect of cadmium sulfide.
Therefore, in order to better play the role of tin dioxide in the field of photocatalysis, two problems must be solved: (1) shorten the migration path of carriers; (2) reduce the recombination rate of photogenerated electron-hole pairs

Method used

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  • Cadmium sulfide quantum dot loaded carbon fibers prepared by utilizing waste cigarette ends, and preparation method and application of cadmium sulfide quantum dot loaded carbon fibers
  • Cadmium sulfide quantum dot loaded carbon fibers prepared by utilizing waste cigarette ends, and preparation method and application of cadmium sulfide quantum dot loaded carbon fibers

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Experimental program
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Effect test

Embodiment 1

[0026] 1. Dry the discarded cigarette butts at 40°C for 12 hours;

[0027] 2. Put the dried cigarette butts into the tube furnace, feed nitrogen gas for 10 minutes, set the temperature of the tube furnace to 500°C, and anneal for 2 hours to obtain carbon fibers;

[0028] 3. Soak the carbon fiber obtained above in cadmium acetate aqueous solution for 30 seconds, then soak it in sodium sulfide aqueous solution for another 30 seconds after natural air drying, put it in a tube furnace after air drying, and calcinate at 400°C under a nitrogen atmosphere, and then cool to room temperature to obtain Carbon fibers loaded with cadmium sulfide particles.

[0029] figure 1 Surface SEM photographs of carbon fibers loaded with cadmium sulfide particles prepared for this example. From figure 1 It can be seen that the complete carbon fiber observed under the scanning electron microscope at 800 times. figure 2 Surface SEM photographs of carbon fibers loaded with cadmium sulfide particles...

Embodiment 2

[0031] 1. Dry the waste cigarette butts at 50°C for 12 hours;

[0032] 2. Put the dried cigarette butts into the tube furnace, feed nitrogen gas for 10 minutes, set the temperature of the tube furnace to 500°C, and anneal for 3 hours to obtain carbon fibers;

[0033] 3. Soak the carbon fiber obtained above in cadmium acetate aqueous solution for 30 seconds, then soak it in sodium sulfide aqueous solution for another 30 seconds after natural air drying, put it in a tube furnace after air drying, and calcinate at 400°C under a nitrogen atmosphere, and then cool to room temperature to obtain Carbon fibers loaded with cadmium sulfide particles.

Embodiment 3

[0035] 1. Dry the discarded cigarette butts at 60°C for 12 hours;

[0036] 2. Put the dried cigarette butts into the tube furnace, feed nitrogen gas for 10 minutes, set the temperature of the tube furnace to 450°C, and anneal for 3 hours to obtain carbon fibers;

[0037] 3. Soak the carbon fiber obtained above in cadmium acetate aqueous solution for 30 seconds, then soak it in sodium sulfide aqueous solution for another 30 seconds after natural air drying, put it in a tube furnace after air drying, and calcinate at 400°C under a nitrogen atmosphere, and then cool to room temperature to obtain Carbon fibers loaded with cadmium sulfide particles.

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Abstract

The invention belongs to the technical field of carbon fiber preparation, and discloses a method for preparing cadmium sulfide quantum dot loaded carbon fibers by utilizing waste cigarette ends, and an application of the cadmium sulfide quantum dot loaded carbon fibers. The method comprises the following steps: putting waste cigarette ends into a tubular furnace, and carrying out annealing under anitrogen atmosphere at a temperature of 450-500 DEG C to obtain carbon fibers; and then soaking the carbon fibers in a cadmium acetate aqueous solution and a sodium sulfide aqueous solution in sequence, carrying out natural drying in the air, and then carrying out calcination under a nitrogen environment at 370-450 DEG C to prepare the cadmium sulfide quantum dot loaded carbon fibers. According to the method, annealing synthesis is adopted to convert the waste cigarette ends into the carbon fibers, and then cadmium sulfide particles are loaded by an in-situ synthesis method to prepare the cadmium sulfide quantum loaded carbon fibers. The product can be used in the application field of degrading waste pollutants.

Description

technical field [0001] The invention belongs to the technical field of carbon fiber preparation, in particular to a carbon fiber loaded with cadmium sulfide particles made from waste cigarette butts, a preparation method and application thereof. Background technique [0002] In recent years, environmental pollution has become an important problem that people urgently need to solve. Due to the unique performance of semiconductor materials, it has injected new vitality into the catalytic degradation of pollutants. Especially in the face of the severe challenge of water pollution treatment, semiconductor catalysts can absorb and utilize sunlight, a green energy source, to catalyze and degrade organic matter in wastewater. They have high photocatalytic efficiency and good safety, and can degrade almost all organic pollutants. The development of photocatalytic materials with large specific surface area, high photocatalytic activity and wide photoresponse range and economical, ef...

Claims

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Application Information

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IPC IPC(8): B01J27/04B01J35/06B01J35/02
CPCB01J27/04B01J35/50B01J35/39B01J35/58
Inventor 陈梦诗张梦龙肖也
Owner GUANGDONG UNIV OF TECH