Catalyst for synthesizing cyclohexylamine by aniline hydrogenation and preparation method thereof
A catalyst, cobalt catalyst technology, applied in catalyst activation/preparation, preparation of organic compounds, preparation of amino compounds, etc., can solve the problems of low conversion rate and low selectivity of non-precious metal catalysts, and achieve improved stability and service life, The effect of improving reaction efficiency and improving conversion rate
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Embodiment 1
[0046] Preparation of modified hydrotalcite-like precursor:
[0047] First, 72.8g of cobalt nitrate (Co(NO 3 ) 2 ·6H 2 O, 291), 128.2g magnesium nitrate (Mg(NO 3 ) 2 ·6H 2 O, 256), 92.9g aluminum nitrate (Al(NO 3 ) 3 9H 2 O, 375), 1.1g lanthanum nitrate (La(NO 3 ) 3 ·6H 2 (2,433) and 600.1g urea (60) were dissolved in 1000mL deionized water to obtain a transparent solution; then the solution was transferred to an autoclave and crystallized at 110°C for 12h; , Methanol each washed 3 times; Then, the solid sample after separation was dispersed in Methanol (the consumption of Methanol is 55ml / g 固体 ), ultrasonicated at 25°C for 1h; then the sample was filtered and dried at 60°C for 12h to obtain a modified hydrotalcite-like precursor.
[0048] Preparation of modified hydrotalcite-like cobalt catalysts:
[0049] The above-mentioned hydrotalcite-like precursor was placed in a muffle furnace, and the temperature was raised to 550° C. at a rate of 3° C. / min, and kept for ...
Embodiment 2
[0053] Preparation of modified hydrotalcite-like precursor:
[0054] First, 131.0g of cobalt nitrate (Co(NO 3 ) 2 ·6H 2 O, 291), 38.5g magnesium nitrate (Mg(NO 3 ) 2 ·6H 2 O, 256), 35.4g calcium nitrate (Ca(NO 3 ) 2 4H 2 O, 236), 91.1g aluminum nitrate (Al(NO3) 3 9H 2 O, 375), 3.2g lanthanum nitrate (La(NO 3 ) 3 ·6H 2 O, 433) and 600.1g (60) urea were dissolved in 1000mL deionized water to obtain a transparent solution; then the solution was transferred to an autoclave, and crystallized at 120°C for 10h; , Methanol each washed 3 times; Then, the solid sample after separation was dispersed in Methanol (the consumption of Methanol is 55ml / g 固体 ), ultrasonicated at 25°C for 1h; then the sample was filtered and dried at 62°C for 10h to obtain a modified hydrotalcite-like precursor.
[0055] Preparation of modified hydrotalcite-like cobalt catalysts:
[0056] The above-mentioned hydrotalcite-like precursor was placed in a muffle furnace, and the temperature was raise...
Embodiment 3
[0060] Preparation of modified hydrotalcite-like precursor:
[0061] First, 109.1g of cobalt nitrate (Co(NO 3 ) 2 ·6H 2 O, 291), 88.6g calcium nitrate (Ca(NO 3 ) 2 4H 2 O, 236), 89.3g aluminum nitrate (Al(NO3) 3 9H 2 O, 375), 5.2g cerium nitrate (Ce(NO 3 ) 3 ·6H 2 (2,434) and 600.1g urea were dissolved in 1000mL deionized water to obtain a transparent solution. Then the solution was transferred to an autoclave and crystallized at 100°C for 18h. After the solid-liquid mixture of gained is filtered, respectively wash with water, acetone 3 times; Then, the solid sample after separation is dispersed in acetone (the consumption of acetone is 55ml / g 固体 ), ultrasonicated at 25°C for 1h; then the sample was filtered and dried at 55°C for 8h to obtain a modified hydrotalcite-like precursor.
[0062] Preparation of modified hydrotalcite-like cobalt catalysts:
[0063] The above-mentioned modified hydrotalcite-like precursor was placed in a muffle furnace, the temperature wa...
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