Organic compound and organic electroluminescent device containing same

A compound and unsubstituted technology, applied in the field of organic compounds, can solve problems such as efficiency roll-off, high device turn-on voltage, and restrictive development, and achieve the effects of reducing efficiency roll-off, reducing driving voltage, and improving luminous efficiency

Pending Publication Date: 2019-12-27
TSINGHUA UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to the wide band gap and hole-biased unipolar transport properties of common host materials, the exciton injection energy barrier is high and will lead to the deviation of the exciton recombination region under high voltage, resulting in unstable electroluminescence spectrum and efficiency roll-off serious
In order to solve the shortcomings of host unipolar transport, two materials with hole transport ability and electron trans

Method used

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  • Organic compound and organic electroluminescent device containing same
  • Organic compound and organic electroluminescent device containing same
  • Organic compound and organic electroluminescent device containing same

Examples

Experimental program
Comparison scheme
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Synthetic example 1

[0109] Synthesis Example 1: Synthesis of M1-1

[0110]

[0111] Synthesis of M1-1:

[0112] Add 600mg of sodium hydride (60%, 15mmol) into a 250mL dry two-necked flask, then add 20mL of dry N,N-dimethylformamide (DMF), and stir for 5min. After that, 20 mL of DMF solution in which 4.11 g of 3-(3,6-diphenyl-9H-carbazole)phenol (10 mmol) was dissolved was added dropwise, and stirring was continued for 1 h after the addition was completed. 2.67 g of 2-chloro-4,6-diphenyl-1,3,5-triazine (10 mmol) was dissolved in 20 mL of dry DMF, and then added dropwise to the reaction system. After the dropwise addition was completed, the temperature was raised to 100° C. and stirring was continued for 12 h. After the reaction system dropped to room temperature, it was poured into 200 mL of ice water, and the precipitate was collected by filtration and dried in vacuum. The crude product was separated by column chromatography to obtain 5.9 g with a yield of 92%. The molecular ion mass deter...

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Abstract

A compound has a structural formula shown as a formula (1): D-L1-Y-L2-A (1), wherein D is a substituted or unsubstituted donor group; the L1 and L2 are each independently a single bond, a substitutedor unsubstituted C6-C30 arylene group, or a substituted or unsubstituted C3-C30 heteroarylene group; the A is a substituted or unsubstituted receptor group; the Y has a structural formula shown as a formula (2) or (3); the X1 and X2 are the same or different and are independently selected from O, S or Se respectively; X3 is selected from C or Si; the R1 and R2 are respectively and independently selected from halogen, alkyl, substituted or unsubstituted alkoxy, substituted or unsubstituted C6-C30 arylamino or heteroarylamino, substituted or unsubstituted C6-C30 aryl or substituted or unsubstituted C3-C30 heteroaryl; the n1 is any integer from 0 to 5; and the n2 is any integer from 1 to 5.

Description

technical field [0001] The invention relates to an organic compound, which can be used as a light-emitting layer host material of an organic electroluminescent device; the invention also relates to the application of the compound in the organic electroluminescent device. Background technique [0002] Due to many advantages such as self-luminescence, high contrast ratio, low power consumption, etc., organic light-emitting diodes (OLEDs), as a new generation of display and lighting technology, have attracted widespread attention from academia and industry. At present, the industry uses blue fluorescent materials with green and red fluorescent phosphorescent materials to achieve full-color display. However, blue dyes are cheap but inefficient, and phosphorescent dyes are efficient but expensive due to heavy metal content. In 2012, Professor Adachi of Kyushu University in Japan reported a series of thermally activated delayed fluorescence (TADF) materials in Nature, which made ...

Claims

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Application Information

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IPC IPC(8): C07D401/12C07D401/14C07D498/04C07D513/04C07D471/04C07D491/107C07D495/10C07D487/04C07D487/14C07D491/147C07D495/14C07D405/14C07D409/14C07F7/08C07F9/6558C09K11/06H01L51/50H01L51/54
CPCC07D401/12C07D401/14C07D498/04C07D513/04C07D471/04C07D491/107C07D495/10C07D487/04C07D487/14C07D491/147C07D495/14C07D405/14C07D409/14C07F7/0816C07F9/65583C07F9/65586C09K11/06C09K2211/1029C09K2211/1007C09K2211/1011C09K2211/1044C09K2211/1059C09K2211/1088C09K2211/1092C09K2211/1096H10K85/6576H10K85/6574H10K85/6572H10K85/657H10K85/40H10K50/11
Inventor 段炼蔡明瀚宋晓增魏金贝高文正
Owner TSINGHUA UNIV
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