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Glass fiber composite cement and preparation method thereof

A technology of glass fiber and composite cement, which is applied in cement production, etc., can solve the problems of limited range of use of glass fiber reinforced cement, deterioration of mechanical properties of glass fiber, unsuitability for construction waste, etc., and achieve high early strength and fast hydration reaction , Improve the effect of cement strength

Inactive Publication Date: 2020-01-17
衡阳县海华水泥有限责任公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, glass fiber reinforced cement itself also has defects, that is, the high alkaline environment of the cement mortar matrix will corrode the glass fiber, making its mechanical properties gradually deteriorate over time, and eventually aging and becoming a brittle material
However, even if alkali-resistant glass fibers are used to prepare glass fiber reinforced cement, aging problems still occur, which limits the scope of use of glass fiber reinforced cement, and it is very unsuitable to use construction waste as raw materials under the existing technological conditions. preparation

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] In embodiment one, glass fiber composite cement is prepared by the raw materials of following components:

[0026] Cement clinker 800kg, industrial waste slag 400kg, fly ash 300kg, slag 100kg, alkali-resistant glass fiber 20kg, additives 20kg.

[0027] Among them: cement clinker is low alkalinity sulfoaluminate cement; raw material of alkali-resistant glass fiber is ZrO 2 The alkali-resistant glass fiber of 14wt%, wherein, alkali-resistant glass fiber is according to 60:5 with m-phenylene neopentyl glycol type unsaturated polyester resin, dehydroacetic acid, 1-3 propanediol when carrying out surface modification treatment: The ratio of 5:1 is mixed evenly in the container and then kept for 40 minutes, then the mixture is added to the silane coupling agent KH570, mixed and stirred for 90 minutes, and then the modified alkali-resistant glass fiber is obtained after hot air drying; the industrial waste is A mixture of cement kiln bottom material and abandoned building was...

Embodiment 2

[0031] In embodiment two, glass fiber composite cement is prepared by the raw materials of following components:

[0032] 700kg of cement clinker, 320kg of industrial waste residue, 380kg of fly ash, 12kg of slag, 35kg of alkali-resistant glass fiber, and 20kg of additives.

[0033] Among them: cement clinker is a mixture of low-alkalinity sulfoaluminate cement and magnesium phosphate cement prepared in a mass ratio of 7:1; the raw material of alkali-resistant glass fiber is ZrO 2 13.6wt% alkali-resistant glass fiber, wherein the alkali-resistant glass fiber is mixed with m-phenylene neopentyl glycol type unsaturated polyester resin, dehydroacetic acid, 1-3 propylene glycol according to 60:5 when carrying out surface modification treatment : The ratio of 5:1 is mixed evenly in the container and then kept standing for 35 minutes, then add the mixture into the silane coupling agent KH570, mix and stir for 70 minutes, and then dry with hot air to obtain modified alkali-resistant ...

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Abstract

The invention discloses glass fiber composite cement and a preparation method thereof. The glass fiber composite cement uses alkali-resistant glass fibers containing 12.5 wt% to 14 wt% of ZrO2 as rawmaterials, the alkali-resistant glass fibers containing 12.5 wt% to 14 wt% of ZrO2 as raw materials is prepared by modifying isophthalene neopentyl glycol type unsaturated polyester resin, dehydroacetic acid and 1-3 propylene glycol in silane coupling agent KH 570, and the glass fiber composite cement is prepared from the obtained alkali-resistant glass fibers as the raw materials and cement clinker, industrial waste residue, fly ash, slag and related auxiliary agents. The preparation method comprises the following steps of: firstly, calcining the industrial waste residue, slag and fly ash athigh temperature, then adding the cement clinker under the condition of medium temperature, and continuously calcining to obtain semi-finished cement; and then, mixing the semi-finished cement with the alkali-resistant glass fiber, the auxiliary agent and water at high speed, drying by hot air, and pulverizing into powder to obtain the finished cement. The cement prepared by the invention has lowalkalinity, high mechanical strength and strong stability and weatherability.

Description

technical field [0001] The invention relates to the technical field of cement preparation technology, in particular to a glass fiber composite cement and a preparation method thereof. Background technique [0002] As one of the three basic materials in the construction industry, cement is the most used building material. It is widely used and used in a large amount. As a powdery hydraulic inorganic cementitious material, cement is usually made by adding water and stirring. Mortar or Concrete is widely used in infrastructure projects such as construction engineering, traffic engineering, and offshore platforms. However, ordinary concrete has defects such as high brittleness, low compressive strength, and cement hydration is often accompanied by volume shrinkage, which is very likely to cause concrete cracks, freeze-thaw effects, chlorine-sulfur erosion, or other types of corrosion, which significantly reduces In addition, the cement manufacturing industry, as a high-pollut...

Claims

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Application Information

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IPC IPC(8): C04B7/36C04B7/26C04B7/153
CPCC04B7/153C04B7/243C04B7/246C04B7/36Y02P40/10
Inventor 刘品
Owner 衡阳县海华水泥有限责任公司
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